Microstructures and quartz crystallographic fabrics of conglomerate lenses from the Tyson Formation, which composes the basal portion of the authochthonous Paleozoic cover sequence in central Vermont, were analyzed to investigate the complex deformational history associated with a polydefonned area. Microstructural observations and crystallographic fabric techniques were used for kinematic analysis, and to relate the development of microstructures and lattice preferred orientations to the local and regional structural settings. Additionally, the study compares the development of microstructures and lattice preferred orientations, and investigates strain heterogeneity that develops within deformed conglomerate. Recrystallization textures within quartz-rich pebbles suggest dynamic recrystallization via subgrain rotation and grain boundary migration. Dynamically recrystallized quartz grains have a grain shape preferred orientation, which is parallel to a series of intracrystalline strain features including undulatory extinction, deformation bands, and subgrains. These features are believed to be a manifestation of shearing along a conjugate set of intracrystalline shear planes that appear as deformation lamellae (Brace, 1955). Plastic deformation along these shear planes has developed a grain shape preferred orientation that forms at high angles (45° to 60°) to the foliation plane, rather than parallel to the XY plane of the incremental strain ellipsoid. Although the Tyson Formation contains more than one tectonic fabric, lattice preferred orientations within quartz-rich domains appear to have formed in response to the second Taconian deformational event of Stanley and Ratcliffe (1985). The crystallographic fabrics show considerable variation on many scales. The distribution of the fabrics relative to local structures show no consistent or predictable relationship. Fabric variation between the matrix and pebbles is believed to be a manifestation of strain heterogeneity. Shear strain within the matrix is accommodated by grain boundary sliding, therefore only coaxial portions of the strain are recorded by the matrix quartz lattice preferred orientation. Furthermore, strain partitioning, and possibly the lack of extensive recrystallization, has precluded the development of strong lattice preferred orientations in the matrix. Within quartz pebbles, conflicting kinematic indicators, microstructures, and c-axis fabrics indicate strain path partitioning due to rheological variability within a flowing rock mass, which deformed under predominantly coaxial conditions. The asymmetric crystal fabrics in this study are approximately 50% top-to-the- west and 50% top-to-the-east. Additionally, porphyroclasts and mica fish locally suggest either non-coaxial or coaxial deformation, as well as conflicting shear senses. Deformation probably occurred within the constrictional field, and was locally accommodated by shearing. Kinematic indicators such as mica fish, asymmetric porphyroclast tails, and c-axis fabrics suggest that partitioning occurred not only between pebbles, but within individual pebbles as well. / Master of Science

A técnica da Distribuição do Tamanho de Cristais - DTC (Crystal Size Distribution - CSD), que relaciona a densidade de cristais com a distribuição do tamanho, foi aplicada à população de plagioclásio de diques máficos do Enxame de Cabo Frio - Búzios (RJ). Os diques possuem larguras variáveis, de alguns centímetros a 20 metros, e orientação em torno de N45E. A textura dos diques é geralmente fina, localmente microporfirítica e intergranular no centro dos diques mais largos. Bordas resfriadas de alguns centímetros de largura são frequentes nos contatos com as rochas metamórficas encaixantes. Foram estudados dois diques na Praia das Conchas com espessura de 0,8m e 8,2m e, um outro na Praia da Lagoinha, com 2m de largura. As amostras foram coletadas junto às margens (~10 cm do contato) e no centro dos diques. O tamanho médio dos cristais de plagioclásio varia de 0,07 a 0,13 mm na borda dos diques mais finos (<= 2 m de largura) e de 0,09 a 0,20 mm na borda do dique mais largo. No centro do dique de Lagoinha e no dique largo de Praia das Conchas o tamanho de plagioclásio é da ordem de 0,19 ± 0,02 mm e 0,60 ± 0,07 mm, respectivamente. As DTCs nas bordas dos diques, independentemente de sua largura, mostraram um padrão tipicamente encurvado, e que tem sido atribuído na literatura como evidência para misturas de magmas com populações de cristais de tamanhos distintos. No entanto, no centro do dique largo (8,2m) de Praia das Conchas, a DTC é log-linear consistente com uma cristalização magmática simples. A química mineral mostrou que os cristais maiores (precoces) de plagioclásio apresentam um teor mais elevado em An (bytownita-labradorita) que os cristais menores (tardios) da matriz (labradorita-andesina). Além disso, a olivina é mais rica em Fo na borda que no centro do dique e, respectivamente, o piroxênio mais enriquecido em Ca. Esses resultados indicam que as margens resfriadas são mais máficas que o centro sugerindo uma evolução química normal com o resfriamento do magma. Portanto, as DTCs encurvadas provavelmente refletem taxas de cristalização heterogêneas possivelmente induzidas pela despressurização durante a ascensão do magma basáltico seguida de rápido resfriamento. O padrão da DTC log-linear no centro do dique de 8,2m de largura é atribuído ao maior tempo de residência do magma que favoreceria os processos de difusão química e re-equilíbrio textural. Os cálculos da taxa de resfriamento utilizando a inclinação da DTC permitiram estimar que o centro do dique largo da Praia das Conchas estaria completamente cristalizado (~ 900 °C) em torno de 73 dias. O estudo da Orientação Preferencial de Forma (OPF) de plagioclásio mostrou que a petrotrama tende a isotrópica nas margens dos diques com largura menor que 2 metros, o que poderia refletir uma rápida cristalização de plagioclásio por despressurização. Quando a trama é localmente definida, como no dique largo da Praia das Conchas, a lineação de plagioclásio é subhorizontal sugerindo que o fluxo magmático moveu-se predominantemente na lateral do dique. / The method of Crystal Size Distribution (CSD), which relates crystal density with size distribution, has been applied on the plagioclase population of the Mafic Dyke Swarm of Cabo Frio-Búzios (RJ). The dykes are NE-trending with widths from a few centimetres to 20m. The texture is generally fine grained and locally microporphyritic and intergranular at the center of the larger dykes. Chilled margins of a few centimetres in width are common at contacts with the metamorphic basement. Two dykes of 0.8m and 8.2m in width of the Conchas Beach and another of 2m in width at the Lagoinha Beach have been studied. Samples were collected at the margins (~10cm from the contact) and at the center of the dykes. The average characteristic size of the plagioclase crystals varies from 0.07 to 0.13mm at the margins of the narrow dykes (<=2m of width) and from 0.09 to 0.20mm at the margins of the large dyke. At the center of the Lagoinha and Conchas dykes the plagioclase size varies from 0.19 ±0.02mm and 0.60±0.07mm respectively. The CSDs at the dyke margins, irrespective of the dyke width, are typically concave-up, and in literature such patterns have been attributed as evidence of magma mixing with distinct crystal populations. However, at the center of the largest dyke (8.2m) of Conchas Beach, the CSD is log-linear, consistent with simple steady-state crystallization pattern. The mineral chemistry shows that the plagioclase phenocrysts have a high An content (bytownite-labradorite) than the groundmass grains (labradorite-andesine). At the margins olivine is richer in Fo than at the center, and respectively, pyroxene is richer in Ca. These results indicate that the chilled margin is more mafic than the center suggesting a normal chemical evolution in a cooling magma. Nevertheless, the concave-up CSDs probably depict heterogeneous crystallization rates possibly induced by depressurization during the ascent of the basaltic magma followed by rapid cooling. The log-linear CSD pattern at the center of the Conchas dyke (8.2m width) is attributed to a higher residence time of the magma which favors the processes of chemical diffusion and textural re-equilibration. The calculated cooling rates using the CSD slope enables us to estimate that the larger dyke of Conchas would be completely crystallized (at ~900oC) in 73 days. The study of the Shape Preferred Orientation (SPO) in plagioclase shows an isotropic petrofabric at the margins of the dykes <=2m, which could reflect a rapid crystallization of plagioclase by depressurization. When the fabric is defined, as in the larger Conchas Beach dyke, the plagioclase lineation is subhorizontal, suggesting that the magma flow was predominantly lateral to the dyke plane.

A técnica da Distribuição do Tamanho de Cristais - DTC (Crystal Size Distribution - CSD), que relaciona a densidade de cristais com a distribuição do tamanho, foi aplicada à população de plagioclásio de diques máficos do Enxame de Cabo Frio - Búzios (RJ). Os diques possuem larguras variáveis, de alguns centímetros a 20 metros, e orientação em torno de N45E. A textura dos diques é geralmente fina, localmente microporfirítica e intergranular no centro dos diques mais largos. Bordas resfriadas de alguns centímetros de largura são frequentes nos contatos com as rochas metamórficas encaixantes. Foram estudados dois diques na Praia das Conchas com espessura de 0,8m e 8,2m e, um outro na Praia da Lagoinha, com 2m de largura. As amostras foram coletadas junto às margens (~10 cm do contato) e no centro dos diques. O tamanho médio dos cristais de plagioclásio varia de 0,07 a 0,13 mm na borda dos diques mais finos (<= 2 m de largura) e de 0,09 a 0,20 mm na borda do dique mais largo. No centro do dique de Lagoinha e no dique largo de Praia das Conchas o tamanho de plagioclásio é da ordem de 0,19 ± 0,02 mm e 0,60 ± 0,07 mm, respectivamente. As DTCs nas bordas dos diques, independentemente de sua largura, mostraram um padrão tipicamente encurvado, e que tem sido atribuído na literatura como evidência para misturas de magmas com populações de cristais de tamanhos distintos. No entanto, no centro do dique largo (8,2m) de Praia das Conchas, a DTC é log-linear consistente com uma cristalização magmática simples. A química mineral mostrou que os cristais maiores (precoces) de plagioclásio apresentam um teor mais elevado em An (bytownita-labradorita) que os cristais menores (tardios) da matriz (labradorita-andesina). Além disso, a olivina é mais rica em Fo na borda que no centro do dique e, respectivamente, o piroxênio mais enriquecido em Ca. Esses resultados indicam que as margens resfriadas são mais máficas que o centro sugerindo uma evolução química normal com o resfriamento do magma. Portanto, as DTCs encurvadas provavelmente refletem taxas de cristalização heterogêneas possivelmente induzidas pela despressurização durante a ascensão do magma basáltico seguida de rápido resfriamento. O padrão da DTC log-linear no centro do dique de 8,2m de largura é atribuído ao maior tempo de residência do magma que favoreceria os processos de difusão química e re-equilíbrio textural. Os cálculos da taxa de resfriamento utilizando a inclinação da DTC permitiram estimar que o centro do dique largo da Praia das Conchas estaria completamente cristalizado (~ 900 °C) em torno de 73 dias. O estudo da Orientação Preferencial de Forma (OPF) de plagioclásio mostrou que a petrotrama tende a isotrópica nas margens dos diques com largura menor que 2 metros, o que poderia refletir uma rápida cristalização de plagioclásio por despressurização. Quando a trama é localmente definida, como no dique largo da Praia das Conchas, a lineação de plagioclásio é subhorizontal sugerindo que o fluxo magmático moveu-se predominantemente na lateral do dique. / The method of Crystal Size Distribution (CSD), which relates crystal density with size distribution, has been applied on the plagioclase population of the Mafic Dyke Swarm of Cabo Frio-Búzios (RJ). The dykes are NE-trending with widths from a few centimetres to 20m. The texture is generally fine grained and locally microporphyritic and intergranular at the center of the larger dykes. Chilled margins of a few centimetres in width are common at contacts with the metamorphic basement. Two dykes of 0.8m and 8.2m in width of the Conchas Beach and another of 2m in width at the Lagoinha Beach have been studied. Samples were collected at the margins (~10cm from the contact) and at the center of the dykes. The average characteristic size of the plagioclase crystals varies from 0.07 to 0.13mm at the margins of the narrow dykes (<=2m of width) and from 0.09 to 0.20mm at the margins of the large dyke. At the center of the Lagoinha and Conchas dykes the plagioclase size varies from 0.19 ±0.02mm and 0.60±0.07mm respectively. The CSDs at the dyke margins, irrespective of the dyke width, are typically concave-up, and in literature such patterns have been attributed as evidence of magma mixing with distinct crystal populations. However, at the center of the largest dyke (8.2m) of Conchas Beach, the CSD is log-linear, consistent with simple steady-state crystallization pattern. The mineral chemistry shows that the plagioclase phenocrysts have a high An content (bytownite-labradorite) than the groundmass grains (labradorite-andesine). At the margins olivine is richer in Fo than at the center, and respectively, pyroxene is richer in Ca. These results indicate that the chilled margin is more mafic than the center suggesting a normal chemical evolution in a cooling magma. Nevertheless, the concave-up CSDs probably depict heterogeneous crystallization rates possibly induced by depressurization during the ascent of the basaltic magma followed by rapid cooling. The log-linear CSD pattern at the center of the Conchas dyke (8.2m width) is attributed to a higher residence time of the magma which favors the processes of chemical diffusion and textural re-equilibration. The calculated cooling rates using the CSD slope enables us to estimate that the larger dyke of Conchas would be completely crystallized (at ~900oC) in 73 days. The study of the Shape Preferred Orientation (SPO) in plagioclase shows an isotropic petrofabric at the margins of the dykes <=2m, which could reflect a rapid crystallization of plagioclase by depressurization. When the fabric is defined, as in the larger Conchas Beach dyke, the plagioclase lineation is subhorizontal, suggesting that the magma flow was predominantly lateral to the dyke plane.

Ce travail retrace l’évolution varisque des Massifs d’Almǎj (Roumanie), de Deli Jovan (Serbie) et de la Stara Planina Occidentale (Bulgarie), à travers une étude pétrostructurale effectuée sur les différentes unités lithologiques de la Nappe alpine du Danubien supérieur. Cette nappe possède la particularité de contenir un marqueur de convergence de toute première importance sous la forme de 4 massifs ophiolitiques démembrés lors de l’orogenèse alpine :Tisoviţa Iuţi (TI, Roumanie), Deli Jovan (DJ, Serbie), Zaglavak (Z, Serbie) et Tcherni Vrah (TV, Bulgarie). Les études pétrologiques de terrain effectuées dans ces trois pays ont permis de confirmer la continuité entre ces 4 massifs, qui, séparément, comprennent chacun une portion de croûte océanique différente (TI :section mantélique et cumulats inférieurs, DJ :cumulats inférieurs et supérieurs, Z :cumulats supérieurs, TV :cumulats supérieurs et section effusive), mais considérés ensemble, forment une pile ophiolitique classique complète. De nouvelles datations par la méthode 147Sm-143Nd confirment un âge d’accrétion pour cette croûte océanique au Dévonien inférieur (~ 400 Ma). Cependant, l’essentiel de ce mémoire concerne les Monts Almǎj, notamment les roches encaissantes du massif de Tisoviţa Iuţi. La partie sud de ce massif ophiolitique représente la section inférieure d’une croûte océanique classique, alors que sa partie orientale est caractérisée par des roches de la croûte océanique supérieure, fortement déformées et transformées (métagabbros à zoïsite et fuchsite). Ces roches font partie de la Zone Mylonitique de Corbu (CMZ), qui comporte également des métasédiments à Gt ± St ± And et des serpentinites. Les conditions PT de formation de ces métagabbros, datés à 380-360 Ma par la méthode 40Ar-39Ar, ont été estimées à des températures comprises entre 450°C et 300°C. Leur contexte de formation peut être assimilé à une semelle ophiolitique ‘froide’, développée lors d’une obduction intra-océanique initiée probablement le long d’une faille transformante. Si le pic de métamorphisme des roches de Corbu a été estimé à 585°C/ 5.5 kbar, leur exhumation pourrait s’effectuer au sein d’un anticlinal en régime transpressif sénestre, en relation avec la formation de la CMZ, interprétée comme une ancienne zone plissée qui évolue en zone de cisaillement sénestre. Au Carbonifère, le granite syntectonique de Cherbelezu se met en place le long de la CMZ et enregistre les dernières phases de cette déformation lors de son refroidissement. Les études préliminaires sur les roches encaissantes des massifs ophiolitiques en Serbie et Bulgarie permettent de préciser une vergence d’obduction du lambeau ophiolitique vers le paléo-NW et d’établir un modèle de reconstitution paléogéodynamique au Varisque pour l’ensemble de la région étudiée./ This study provides new information on the Variscan evolution of the Almǎj Mountains (Romania), Deli Jovan Massif (Serbia) and Western Stara Planina (Bulgaria), throughout a petrostructural investigation conducted on the various lithological units of the Upper Danubian Alpine Nappe. This nappe displays an important convergence tectonic marker in the form of four ophiolitic massifs dismembered during the Alpine orogeny: Tisoviţa Iuţi (TI, Romania), Deli Jovan (DJ, Serbia), Zaglavak (Z, Serbia) and Tcherni Vrah (TV, Bulgaria). Our petrological studies in these three countries have confirmed the continuity between these four massifs, each of which showing, separately, a different portion of the oceanic crust (TI: mantle section and lower cumulates, DJ: lower and upper cumulates, Z: upper cumulates, TV: upper cumulates and effusive section), but taken together, forming a complete classical ophiolitic pile. New dating using the 147Sm-143Nd method has confirmed an accretion age for this oceanic crust at around 400 Ma (Early Devonian). However, the main part of this study has been focused in the Almǎj Mountains, particularly the Tisoviţa Iuţi ophiolitic massif and its enclosing rocks. The Southern part of this ophiolitic massif represents the lower section of a classical oceanic crust whereas its eastern part is characterized by upper crustal oceanic rocks that are highly deformed and transformed (zoïsite and fuchsite-bearing metagabbros). These rocks belong to the Corbu Mylonitic zone (CMZ), which also comprises Gt ± St ± And metasediments and serpentinites. Temperature estimates for the formation of the metagabbros are bracketed between 450°C and 300°C and these rocks have been dated at 380-360 Ma using the 40Ar-39Ar method on fuchiste. The geodynamic context for their formation can be viewed as a ‘cold’ ophiolitic sole, developed during an intra-oceanic obduction probably initiated along transform fault. If the metamorphic peak for the Corbu rocks has been estimated at 585°C/5.5kbar, their rapid exhumation could be realized via an anticline under a transpressive sinistral regime, connected with the formation of the CMZ that is interpreted as an ancient fold zone evolving in a sinistral shear zone. Finally, the Carboniferous syntectonic Cherbelezu granite intrudes along the CMZ and records the final stages of this deformation during its cooling. Preliminary investigations on the enclosing rocks of the ophiolitic massifs in Serbia and Bulgaria allow us to define a top to the NW obduction vergence for the ophiolite and to propose a paleogeodynamic reconstitution model for the Carpathian/Balkans terrains in the Variscan times. / Doctorat en Sciences / info:eu-repo/semantics/nonPublished