Submitted in fulfilment of the requirements for a Master of Science degree in Geology, in the Department of Geosciences, University of the Witwatersrand, Johannesburg, South Africa. 2015 / This study undertook to re-evaluate the conventional historic interpretation that accepted the Marginal Zone as representative of the chill phase to the earliest emplacement of Lower Zone magmas. The Clapham Trough preserves a thick sequence of the Marginal Zone rocks, at least 220 m thick. Poor exposures and incomplete stratigraphy of the rock succession that occurs between the floor and the Marginal Zone rocks presented great limitations to earlier studies, and led earlier workers to accepting that the base of the Bushveld Complex is the Marginal Zone norite. This study presents results from the 692 m CH6 drilled core, which intersects the Marginal-Lower Zone boundary in the Clapham Trough. The base of the CH6 drill core consists of melanorite (with less than 40 % cumulus plagioclase), which is conformable with the underlying, thick Basal Ultramafic Sequence (BUS, described in Wilson and Chunnett, 2010; and Wilson, 2012) separating the Marginal Zone rocks with the floor rocks of the Magaliesberg Formation. The amount of cumulus plagioclase in the Marginal Zone increases with increasing stratigraphic height such that the top units of the Marginal Zone are norite-leuconorites (typically 45-65 % cumulus plagioclase), bordering on anorthosite. The progressive changes in the modal variations led to the subdivision of the Marginal Zone norite to a basal Mafic Norite and a xenolith-bearing Shelter Norite. The latter is deemed a correlative of the Xenolithic Norite described at Olifants River Trough. Coupled with the increasing amount of cumulus plagioclase, the An# increases with stratigraphic height. The An# fractionation trend is reversed from that of the co-existing orthopyroxene observed in the same interval (An63-74 vs. En81-70). The reversed An# compositions are an abnormal differentiation trend. The compositional disequilibrium between co-existing orthopyroxene and plagioclase formed from in-situ crystallization with floatation of plagioclase, through convection, separating the cotectic phases. All the data in the Marginal Zone show that these rocks have continuous fractionation trends with no interruptions. The Marginal Zone rocks are cumulus rocks that formed through fractional crystallization in a temporarily closed magma chamber. The present work showed unequivocally that the Marginal Zone is a product of differentiation of earlier emplacement of B1-magma, and cannot be representative of either a chill zone or composite sills. The appropriate (parental) liquid composition of the Marginal Zone formed after 30 % crystallization of the B1-magma. The postulated liquid composition is 6 wt. % MgO and 56.7 wt. % SiO2. The entire Marginal Zone succession would have formed from about 30-54 % crystallization of the B1-magma. The crystallization of the Marginal Zone was ended abruptly by the emplacement of a new batch of B1-magma, which must have mixed with the residual magma that must have ponded atop Marginal Zone cumulates after 54 % crystallization. The mixing of the evolved residual magma and the primitive B1-magma formed the liquid postulated to be parental to the Lower Zone A (10.59 wt. % MgO and 57.10 wt. % SiO2). The Transitional Pyroxenite bears all the evidence of mixing between magmas of contrasting compositions, forming the 10-30 m gradational boundary unit between the Marginal Zone and Lower Zone A (correlative of the Lower Orthopyroxenite Subzone described at Olifants River Trough). The Lower Orthopyroxenite Subzone at the Clapham Trough is almost a mono-mineralic rock succession with generally constant orthopyroxene composition (En87-86), with the exceptions at marker norite horizons (En84-82; An83-81). The constant compositions observed in Lower Zone A are attributed to contemporaneous emplacement of new magma and differentiation, which maintained the composition of the parental magma.

Union Section of Rustenburg Patinum Mines is situated in the northwestern part of the Bushveld Complex, some twenty kilometres north of the Pilanesberg Alkaline Complex. The mining lease area covers a roughly triangular segment of Lower, Critical and Main Zone rocks, transgressed to the north and south by magnetite-bearing ferrogabbro of the Upper Zone. The Main Zone at Union Section is the focus of this study. The prime source of sample material for the study is the deep exploration borehole SK2, but additional, supplementary samples were collected on surface and underground, as well as from a second surface exploration borehole, SK4. In line with the recommendations of SACS (1980), the top of the Critical Zone, and therefore the base of the Main Zone, is taken to be the top of the Bastard Cyclic Unit. Sharpe (1985) suggested that the succession from the base of the Main is an isotopically separate entity Zone up to the Pyroxenite Marker from the rest of the Bushveld layered succession. This is not strictly true, as there is evidence that more than one parental magma was involved in the formation of this interval. It is, however, true that there are fundamental differences, particularly in isotopic makeup, between the Main Zone rocks below the pyroxenite Marker and those above (the latter having been assigned by Molyneux (1970) to subzone C of the Main Zone). Kruger et al. (1986, in press) suggested that the Pyroxenite Marker marks the base of the Upper Zone, and this convention is adhered to here. The implication of this is that the rocks which formerly constituted subzone C of the Main Zone are now considered part of the Upper Zone. The Main Zone rocks below the pyroxenite Marker were originally subdivided by Molyneux (1970) into two subzones, A and B. The results of the present study indicate that this subdivision is not justified. Instead, eight units have been distinguished in the Main Zone on geochemical, petrological and mineralogical bases. Each of these units is characterized by a coherent set, or progression, of chemical and petrological characteristics. The specific assignment of genetic connotations to these units has been deliberately avoided , at least until further studies of the Main Zone prove this to be justified. The demarcation of the eight units is illustrated in the composite diagram (Fig. 34) in the back pocket of this work, and the reasons for the subdivisions are listed in Table 6 (at the end of chapter 7 of this thesis). Until the late 1970's, it was thought that most layered cumulates formed by crystal settling (Wager and Brown, 1968). More recently, there has been a fundamental conceptual change, and many workers now believe that most cumulate rocks formed by in situ crystallization at the floor and walls of the magma chamber (McBirney and Noyes, 1979, Irvine, 1980a; Campbell, 1987). There is, however, some evidence for the physical separation of phases undergoing cotectic crystallization, particularly in the Upper Critical Zone and lower part of the Main Zone (Eales et al., 1986). This process, which has been alluded to in the past by various authors (Ferguson and Botha, 1963; Vermaak, 1976) involves the flotation of early-formed plagioclase crystals due to their positive bouyancy in tholeiitic liquids. The result is an apparent decoupling of the chemistry of pyroxene and plagioclase, as in unit IV of the Main Zone, where plagioclase becomes more anorthitic upwards, whilst pyroxene becomes more iron-rich. There is some substantial evidence, particularly in reversals in the strontium isotope initial ratio and the orthopyroxene Mg/(Mg+Fe) ratio , for multiple intrusion in the Main Zone. Although the largest and most important magma influx in the Main Zone was a high-R₀ aluminous tholeiite, as suggested by Sharpe (1985), the intrusive history of the Main Zone is believed to be far more complex than Sharpe (op. cit.) suggested. Significantly, there is strong evidence for small influxes of Upper Zone-type (Fe-rich tholeiite) magma in the upper reaches of the Main Zone. These are believed to be precursors to the major influx of Upper Zone-type magma at the pyroxenite Marker (Kruger et al, 1986, in press). The fate of intercumulus liquids in cumulate rocks has recently recieved substantial attention (Sparks et al., 1985; Morse, 1986; Barnes, 1986: Campbell, 1987). It is believed that the migration, or at least redistribution, of intercumulus liquids has played a vital role in modifying fractionation trends in the Main Zone. More importantly, the accumulation of late-stage intercumulus liquids is believed to be responsible for the formation of the Fe-rich ultramafic pegmatite bodies that interrupt the layered cumulates in borehole SK2 / Adobe Acrobat 9.53 Paper Capture Plug-in

D.Phil. (Geology) / A specific geological event has been characterized with the aid of an integrated metamorphic and fluid inclusion study of data obtained from syn-tectonic vein-quartz associated with thrusting and bedding-parallel shear along the northern margin of the Witwatersrand Basin. The vein-quartz associated with this event occurs as boudin-shaped bodies with their long and intermediate axes orientated within the foliation-, bedding- or fault-planes. The length of the quartz lenses which are spatially confined to shear zones often exceeds the thickness of the shear zones. These phenomena and the fact that quartz-fibres are orientated parallel to and not at right angles to the foliation confirms the syn-tectonic nature of the quartz veins. Heterogeneous P-T condition is indicative of imbrication, i.e. crustal thickening which is also substantiated by the random growth of pyrophylite and kyanite in shear zone assemblages, indicating that metamorphism outlasted deformation. Metamorphic studies of aluminous schists and vein-quartz with pyrophylliteand pyrophyllite - kyanite selvages established the development of two critical mineral assemblages: 1 Kaolinite + 2 Quartz = 1 Pyrophyllite + 1 H20 ... (1) and at higher P-T conditions 1 Pyrophyllite = 1 Kyanite + 3 Quartz + 1 H20 ... (2). The schists and quartz vein assemblages are quartz-oversaturated in contrast to the study material of Wallmach and Meyer (1990) which is quartz-undersaturated. Peak metamorphic conditions, therefore, are closely constrained by the position of the reaction curve (2) in P-T space, as is also substantiated by the presence of coexisting kyanite and pyrophyllite which are closely associated with syn-tectonic vein-quartz at the Florida Lake, Monarch Shaft and Krugersdorp localities. The nature of and circumstances under which the equilibrium aSsemblage pyrophyllite + kyanite + quartz has formed support an univariant situation, i.e. this assemblage can only coexist along the pyrophyllite kyanite isograd. The mineral assemblages that equilibrated during peak metamorphism are still present in the rocks of the shear zones, and show only incipient rehydration. The quartz-oversaturated nature of the rocks in the shear zones and the fact that kyanite formation is ascribed to reaction (2), cannot explain the abundance of quartz veins. Accordingly it is concluded that there must have been an external source from which Si02 was imported into shear zone to give rise to the formation of the large quantities of vein-quartz.

M.Sc. / The study site for this project is New Clydesdale Colliery situated in the Witbank Coalfield, South Africa. The Witbank Coalfield is located within the northern part of the Karoo Basin where the major coal deposits in South Africa are located. Optimum ash fusion temperatures derived from coal in this region are approximately 1400°C, and higher, although temperatures above 1300°C are also acceptable. In certain coal seams the ash fusion temperatures drop well below this optimum temperature, leading at times to problems in the user industry. Ash fusion temperature which is the temperature at which the mineral matter in coal begins to soften, flow and fuse, is an important aspect relating to coal utilization but is little understood and under-studied in South Africa. The objective of this thesis is to attempt to determine what factors, mineralogical or inorganic chemical, influence variations in the ash fusion temperatures in certain coal samples. An understanding of this problem will have a bearing on the ultimate assessment of a coal for utilization purposes, in general, and ash deposition prediction in future boiler plants in particular. This study is somewhat pioneering as no detailed studies have been undertaken or published previously. Samples were collected at four sites from New Clydesdale Colliery. The sample sites were selected based on pre-existing knowledge of the ash fusion temperatures obtained from company analytical sheets. The sites were therefore representative of low and high ash fusion temperature coal. The first two sites were located in the opencast area where the No. 2 seam is actively being mined. The other two sites were located underground where mining has ceased. Conventional analyses conducted on the samples include proximate analyses, calorific values, percentage sulphur, and ash fusion temperatures. Further analyses performed included ash analyses (composition of ash), X-ray diffraction, scanning electron microscopy and petrographic studies. It was found that although complex relationships exist between ash fusion temperature and the various geological and coal parameters, positive results were obtained. These indicate a possible relationship between low ash fusion temperatures and i) finer size fractions, ii) an increase in iron content present in the form of pyrite and iii) the form in which pyrite is present, namely cleats. High ash fusion temperatures tend to correlate with i) the absence of pyrite or ii) pyrite present as framboids.

The mineralogy and petrology of two kimberlites, a peripheral monticellite kimberlite, and its core of phlogopite kimberlite, from the West Auxiliary Pipe at Dutoitspan Mine are described. The mineralogy of the two kimberlites differs mainly in the presence of phlogopite macrocrysts, greater abundance of angular crustal inclusions, more heavy minerals and higher diamond grade in the phlogopite type. Microprobe analyses of olivine, phlogopite, monticellite, oxide minerals and garnet are presented. Silicate compositions are comparable in both kimberlites and zoning of olivine grains is typically towards a rim of Fo₈₉₋₉₀ʻ irrespective of whether cores are more Fe-rich or more Mg-rich. This is caused by re-equilibration after fluidised emplacement in the earth's crust of macrocryst-bearing kimberlite magma. Olivine aggregates were derived from sheared mantle lherzolite and single-crystal macrocrysts were formed at higher mantle levels from a kimberlitic crystal-mush magma. This was emplaced in the crust by rapid gas streaming. The post-fluidisation phenocrysts of olivine and phlogopite which formed then are in general more Fe-rich than macrocrysts. Re-equilibration of ilmenite results in the formation of complex perovskite and titanomagnetite mantles. Phlogopite macrocrysts are preserved in the monticellite contact rock where rapid quenching prevented their resorption and allowed separation of an immiscible carbonate melt, giving the abundant groundmass calcite. Atoll-textured spinels are found in the contact rock. Major and minor trace-element analyses of whole rock samples are presented and discussed, bringing into account the problem of contamination by crustal inclusions. Whole rock chemistry supports derivation of the kimberlites as partial melts of mantle material in the presence of a lithophile-element-enriched fluid. The monticellite contact rock is highly enriched in REE, Nb, and Sr due to rapid freezing of this perovskite-enriched phase. The monticellite type is more enriched in lithophile elements than the phlogopite type, which supports derivation of the monticellite type by a small degree of partial melting, further melting reducing the relative concentrations of lithophile elements to give the phlogopite kimberlite chemistry.

Field work and mapping with the aid of aerial photographs have shown the north Gap Dyke to be a vertical intrusion 93½ miles long . It extends from a point about 4½ miles south of Cathcart to the coast where it enters the sea about 100 yards north of the Ngadla R lver mouth. It is composed of several rock types including dolerite pegmatite, granophyric dolerite, subophitic dolerite, and it has a more or less central core of mobilized sediment at the western end. The essential minerals of the dolerite types include zoned plagioclase, which is described in some detail, and augite. Less important are hornblende and micropegmatite. Accessories include apatite, ilmenite, magnetite, quartz, actinolite, prehnite, calcite and epidote. Iddingsite (?), saussurite and chlorite occur as alteration products. The mode of origin of the Gap Dyke magma remains an open question: it may have arisen as a result of normal crystal fractionation or as the result of hybridization in depth followed by differentiation.

A study of petrological and geochemical variations through the upper Critical Zone of the Bushveld Complex at Amandelbult section of R.P,M. was undertaken. The sequence at this locality may be divided into seven "units" two of which appear to be complete, possessing the sequence harzburgite-pyroxenite-norite-anorthosite. The other five Units lack basal, intermediate or upper members. Considerable lateral variations are apparent in this sequence, but these are restricted to the Lower Pseudo Reef-Merensky Reef interval, tne same portion of the succession which is affected by pothole structures. The single most important petrographic feature of genetic significance is the occurrence of annealed, recrystallized anorthosite immediately underlying ulstramafic layers. This, together with the undulatory nature of the contact between the two rock layers, suggests that the ultramafic layer was emplaced as a hot liquid over a pre-existing, crystalline anorthosite floor, and that some remelting of this layer occurred. Variations in the chemical make-up of constituent silicate minerals reveal a number of significant processes which may have been operative in the magma chamber prior to crystallization, Olivine grains, for instance, exhibit extremely wide chemical variations both within single layers and from one layer to the next. These variations are best explained by re-equilibration processes with spinel and base metal sulphides, rather than by wide variations in original liquidus compositions. It appears that the compositions of the initial liquids from which each basal olivine-bearing layer crystallized, were approximately similar. Variations in the iron-magnesium ratio of ortho-pyroxenes indicate well defined continuous fractionation trends in units which are considered to be complete. Magnesian compositions are recorded in ultramfic members, while increasingly iron-enriched values are recorded upwards through the sequence pyroxenite-norite-antorthosite. Plagioclase grains exhibit less well defined fractionation trends, but it is clear that an upward increase in An is encountered through indivitual Units. This is in direct contrast to the trend exhibited by orthopyroxene. A further feature of plagioclase grains is the considerable degree of chemical zonation exhibited by them. In cumulus grains this is commonly manifested as strongly reversed rims, while in intercululus grains normal zoning is ubiquitous. Whole-rock chemical variations through the succession indicate that cyclical variations occur through successive Units, but that these merely reflect changes in modal mineralogy and not liquid fractionation trends. Such trends can be shown for selected element ratios, where these elements are known to partition into a single mineral phase. Rations of pyroxene components such as the nickel/scandium ratio, exhibit a saw tooth pattern through successive Units, while ratios of plagioclase components such as the strontium/alumina ratio have unique, fairly constant values for each individual Unit but different values for successive Units. The latter type of cyclicity is not always strictly confined to lithologically recognized boundaries between Units, and a slight overlap into overlying ultramafic layers is apparent. An investigation of variations in trace element levels in a single layer in five widely separated boreholes revealed that there is some evidence for a lateral fractionation trend from the southwest (more primitive) to the northeast (more evolved), although the small number of data points available preclude definite conclusions. There exists in the data some evidence that the Giant Mottled Anorthosite differs chemically from the other anorthosites in the study section, and that it more closely resembles rocks of the Main Zone. This evidence is particularly apparent in variations of the chromium/aluminium ratio of orthoyroxene grains, and in the An content of plagioclase grains, both of whose trends exhibit distinct inflections at the base of this member. The features of the succession at Amandelbult are best explained by the model of Eales et al. (in press, a), which visualizes the input of a number of pulses of new, hot liquid into a magma chamber containing the fractionated residua of previous influxes. At a critical point in time, just prior to the mafic Merensky Reef input, a large input of gabboic liquid was intruded at high levels in the chamber. The lower portions of this liquid mixed with the residua of earlier mafic inputs, which in turn mixed with new inputs of mafic, typical Critical Zone liquids. Thus the lower portions of the study section represent mixtures of new Critical Zone liquids with the residua of previous such influxes, while the upper portions have the added complication of mixture with a Main Zone-type liquid. The unique chemical character of the Giant Mottled Anorthosite appears to be a direct manifestation of the influence of the Main Zone liquid. / KMBT_363 / Adobe Acrobat 9.54 Paper Capture Plug-in

Sixty one basalt samples from the Drakensberg Subgroup in the Barkly East area were analysed for major elements and fourteen trace elements viz. Sr, Rb, Zr, Y, Nb, Zn, Cu, Ni, Co, V, Cr, La, Ce and Nd . These data confirm the tholeiitic nature of the Drakensberg Subgroup. Geochemical differences in the major element compositions are small within the different units of the Drakensberg Subgroup. Small differences are also evident between these units. The trace element variation between the units and within the Lesotho Formation are more pronounced than the variation of the major elements. The Lesotho Formation samples show a minor vertical increase in value for the top half of the Naudes Nek section in Fe, Ti, P, Zr, Nb, Y, La, Ce and Nd . A decrease in value from the same position in Mg, Ni and Co was observed. These patterns of variation are interpreted as representing low-pressure fractionation of plagioclase, olivine and clinopyroxene. Differences between the units of the Drakensberg Subgroup are examined by using absolute trace element contents and interelement ratios. Ratios of incompatible elements differ for the different units leading to the suggestion that a heterogeneous mantle is the most likely explanation for these differences. A unique unit of flows designated the Omega Formation is examined. The basal massive unit displays an unusual pattern of variation with height which suggests an origin through two different differentiation mechanisms. The data from this thesis are compared with those of Cox and Hornung (1966) on the central Lesotho basalts, Bristow (1976) on the southern Lebombo basalts and Robey (1976) on the Karroo dolerites of the Eastern Cape. The geochemical comparison between the lavas of the Lesotho Formation in the Barkly East area, central Lesotho and the Karroo dolerites show no major differences. However the southern Lebombo basalts show an enrichment in Sr and depletion in Cr.

One of the most remarkable features of the layered sequence of the Bushveld Complex is its lateral consistency in lithology. This work has established a geochemical and lithological correlation along 170 km of strike of the interval between the UG2 chromitite and the Merensky Reef within the Upper Critical zone of the western limb of the Bushveld Complex. The correlation is based on geochemical investigations of 10 borehole intersections and lithological comparisons of more than 20 borehole intersections around the western lobe of the complex. The basic data presented include 123 whole-rock analyses for major and 12 trace elements, 97 analyses for ' 12 trace elements, and ca. 5500 microprobe analyses of all major phases. Patterns of cryptic variation are established. Some layers (the UG2 chromitite and pyroxenite) show considerable consistency with regard to geochemistry and lithology. Others can be traced along most of the investigated strike length, such as the Lone Chrome Seam, the Footwall Marker anorthosite and the immediate anorthosite footwall to the Merensky Unit. Most of the distinguishable members within the study section, however, show great variation along strike (i.e., the Lower and Upper Pseudoreef Markers, the central noritic sequence in the southern arm of the western limb and parts of the immediate Merensky Reef footwall succession). Several models have been evaluated to interpret the geochemical and lithological data. The author comes to the conclusion that the degree of lithological consistency depends on the variability of magmatic parameters within different parts of the chamber. The most important of these parameters are: (i) the size of fresh primitive influxes and consequently the heat flux, (ii) the composition of the residual liquid, and (iii) the frequency of the influxes. Fresh influxes of more or less similar composition thus spread out along the floor if the residual liquid was less dense than the fresh primitive liquid, but intruded the chamber as a plume where plagioclase had crystallized for some time and the residual liquid had become relatively dense. The size of the influx may be regarded as a measure of the amount of heat flux from the feeder into the chamber. A large influx created uniform physicochemical conditions in the chamber whereas a smaller influx created a strong lateral gradient of physicochemical parameters in the chamber, with subsequent differences in viscosity, density, convection currents, yield strength and thus different mixing behaviour of different liquids. Furthermore, a persistent heat flux from the feeder may have delayed crystallization of successive phases in those parts of the chamber proximal to the feeder . Therefore, new influxes would have been deposited on a footwall of varying thickness and lithology in response to different degrees of crystallization and accumulation along strike. The development of a normal cyclic unit (chromititeharzburgite-pyroxenite-norite (+anorthosite?)) may thus have been interrupted at various stages in different parts of the chamber. The ability to correlate anorthosites over great strike distances implies that their formation did not follow entirely random processes but was dependent on specific magmatic conditions which prevailed over laterally extensive portions of the chamber at certain stages during the evolution of the crystallizing liquid.

The Cu/(Cu+Ni) ratios associated with the Basal Gabbro also display the vertical reverse fractionation trend, supporting the supercooled margin model. The disseminated sulphides in the lowermost units, are regarded as being the result of sulphur saturation induced by contamination from the dolomitic and quartzitic xenoliths. This is supported by isotope data which indicate the high degree of contamination in the lowermost units of the Complex. The results of this study are used to propose a model for the petrogenesis and metallogenesis of the Uitkomst Complex, whereby the Complex is closely related to the Bushveld Complex. The Basal Gabbro, as supported by its chemistry and style of mineralisation (Cu-rich), represents a supercooled margin to the lowermost units of the Uitkomst Complex, which stoped upwards into the surrounding sediments, assimilating the country rock xenoliths, and precipitating sulphides. Following this was a period in which large quantities of magma moved laterally through the system before the magma flow waned, and closed system crystallisation ensued. As the body cooled, the primarily magmatic water was superceded by the hydrothermal magmatic water released from the xenoliths, and later by geothermally driven circulating meteoric water, producing the extensive alteration. This alteration was accompanied by considerable stress and the development of fractures and shears. Finally the Complex was itself intruded by diabase sills and later dolerite dykes.