The application of substantial quantities of phosphorus (P) has been required to increase productivity on many Australian soils. Unfortunately, these applications have often resulted in increased concentrations of P in surface runoff that contributes to excessive algal growth in surface waters and consequently a decline in their quality. The concentrations of P in runoff from intensively managed pastures are often high (1-5 mg/L) and typically at least an order of magnitude higher than water quality targets. Although a substantial amount of research has been devoted to the problem of P accumulation and mobilisation in arable systems ( in which P is typically mobilised by the action of raindrop impact and subsequently transported in particulate form ), there has been substantially less research in intensively managed pasture systems. Consequently, there is a paucity of knowledge concerning the fundamental processes and factors responsible for P in runoff from these systems and a dearth of truly effective remedial strategies. In this thesis, the accumulation of P in soil under intensively managed pastures used for dairying and the processes responsible for its mobilisation in surface runoff were investigated. This research was undertaken at two research sites in South - east Australia, i.e. Camden in New South Wales and Flaxley in South Australia. A number of factors relating to scale and hydrology may influence the processes of P mobilisation and its concentration in runoff. A comparison was made of the forms and concentrations of P in runoff between a typical rainfall simulation methodology and large runoff plots. The effect of rainfall intensity on the forms and concentrations of P was also investigated. The concentrations of P in runoff from small - scale, high - intensity rainfall simulations were on average 33 % lower than those from large plots ( approximating hillslopes ) although the processes of mobilisation ( as evidenced by runoff P forms ) were similar. Increasing rainfall intensity resulted in decreasing P concentrations, but similar forms of P. It was hypothesised that changes in hydrological characteristics ( residence time and depth of runoff ) were responsible for the differences in the P concentrations. A model of P mobilisation ( incorporating hydrological and P - release characteristics ) was developed and shown to successfully predict runoff P concentrations under a range of rainfall intensities. These findings and the subsequent model were used in the successful modelling of landscape scale nutrient exports based on rainfall simulation data as part of a separate, but complementary project. There is anecdotal evidence to suggest that Australian soils are relatively ' leaky ' in terms of P in runoff compared to soils overseas. Consequently, comparisons of the labile soil P characteristics and soil P - runoff P relationships were made between Australian soils and soils of similar fertility from the USA, UK and New Zealand ( using both experimental data and data sourced from the literature ). It was concluded that Australian soils leak more P than soils of similar fertility in the USA, UK and New Zealand, although it was beyond the scope of the thesis to make more detailed comparisons between Australian and overseas soils. The accumulation and mobilisation of P in two soils used for intensive pasture production in Australia were investigated. In intensive pasture systems P accumulated in the shallowest zones of the soil and principally as inorganic P. The concentrations of labile P were 3 - 5 times higher in the top 0.01 m than in the top 0.1 m. Using a simple model, it was estimated that only the top several mm of soil influence runoff P concentrations. The dominant form of P in runoff was shown to be orthophosphate although in low to moderate fertility soils, dissolved organic P can constitute a substantial proportion of the P in runoff. These results confirm the need to reduce the pool of P available for mobilisation in the immediate topsoil in order to reduce runoff P concentrations. Because P is stratified, it was hypothesised that one method to reduce the pool of P available for mobilisation is to de - stratify the soil ( i.e. mix the topsoil ). The effect of this technique on runoff P concentrations was investigated in laboratory and rainfall simulation experiments. These experiments revealed that reductions in runoff P concentrations between 45 and 70 % can be achieved by de - stratification of soils under permanent pastures. It was hypothesised that the benefits of de - stratification could be maximised using a combination of information relating to catchment hydrology and the spatial distribution of soil P and that this would result in large reductions in P exports with a relatively small degree of inconvenience to land managers. Given the limited opportunities identified in previous research to reduce P exports in runoff, the strategic utilisation of de - stratification is a potentially important option in water quality management for the dairy industry and warrants further investigation. / Thesis (Ph.D.)--School of Earth and Environmental Sciences, 2006.

Thermal desorption (TD), a remediation method used to remove hydrocarbons from contaminated soils, may cause changes in soil properties that threaten soil function and plant productivity. The goal of this research is to better understand the effect that TD treatment has on soils intended for agricultural use. A series of soil phosphorus (P) sorption and desorption experiments were conducted on soils before and after TD treatment to determine P availability for plant uptake and risk for run-off. TD-treated soils retained more P, likely due to mineral transformations of Fe- and Al-oxides. In addition, a three-year field study using mixtures of topsoil (A), crude-contaminated soil (SP), and TD-treated soils (TDU) was conducted. Yields were significantly greater in plots that included A in the mixture compared to SP and TDU soils alone. TD-treated soils can be a replacement for topsoil, but the addition of topsoil will reduce the time to successful reclamation.

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Accelerated eutrophication is becoming a major problem in relation to surface waters. Controversy has arisen as to its causes in different types of natural systems. Investigations were made of the stimulatory and limiting effects of phosphate on the bacterium E. coli in synthetic media. Growth was measured in batch and continuous flow cultures using both turbidimetric and respirometric techniques. The results obtained were used to formulate a hypothesis concerning the stimulation of algae by inorganic carbon produced by bacteria and the role this relationship plays in the eutrophic processes that occur in natural systems where organic carbon is not limiting to bacterial populations. / Master of Science

A study of phosphorus loading and water quality implications was conducted for the Oregon coastal lakes. The study was based on existing data for lake total phosphorus concentrations and for watershed land uses. A phosphorus mass-balance model was developed to predict lake total phosphorus concentrations from estimated phosphorus loading from land uses within the lake's watershed. Uncertainty in total phosphorus concentration estimates are included in the model, and model predictions are considered to be moderately to highly reliable. The Oregon coastal lake phosphorus mass-balance model was calibrated from data for 12 Oregon coastal lakes. Land use phosphorus loading coefficients for forestry, the coastal dunal aquifer, and precipitation were derived from data specific to the Oregon coastal region, while other phosphorus loading coefficients were estimated based on correlations between literature values and Oregon coastal conditions. The model may be used as an aid for land use management decisions by estimating water quality effects of projected land use changes. A case study of Mercer Lake was used to illustrate the model application. / Graduation date: 1994