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Studies in the halogen substituted pinacols and the possible formation of ketyl radicals, R2=C-OMgI ...Bailar, John C. January 1929 (has links)
Thesis (Ph. D.)--University of Michigan, 1928.
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The molecular rearrangement of 2-dimethylaminotetramethylethanol hydrochloride ...Alderman, Van Vernon, January 1942 (has links)
Thesis (Ph. D.)--University of Chicago, 1939. / Lithoprinted. Includes bibliographical references.
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Studies in the halogen substituted pinacols and the possible formation of ketyl radicals, R2=C-OMgI ...Bailar, John C. January 1929 (has links)
Thesis (Ph. D.)--University of Michigan, 1928.
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The pinacol-pinacolone rearrangement.Sternberger, Helen Ruth, Bachmann, Werner Emmanuel, January 1900 (has links)
Thesis (Ph. D.)--University of Michigan, 1934. / "By W.E. Bachmann and Helen R. Sternberger." "Reprint from the Journal of the American chemical society, 55 ... (1933); 56 ... (1934)."
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The pinacol-pinacolone molecular rearrangement The rearrangement of pinacol dibromide ...Roberts, Frederick H., January 1937 (has links)
Thesis (Ph. D.)--University of Chicago, 1934. / Lithoprinted. "Private edition, distributed by the University of Chicago Libraries, Chicago, Illinois."
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I. On the Mechanism of Acid Promoted Rearrangement of PCU-Derived Pinacols II. Synthesis of a Trimethyltrishomocubyl Helical Tubuland DiolLiu, Zenghui 05 1900 (has links)
I. Reductive dimerization of pentacyclo[5.4.0.0.^2,6.0^3,10.0^5'9]undecane-8-one-(PCU-8-one, 53) affords a mixture of meso and d,l pinacols (55a and 55b respectively). Acid promoted rearrangement of 55a and 55b conceivably can proceed with migration of C(7)-C(8) and/or C(8)-C(9) to form the corresponding pinacolone(s). In our hands, acid promoted rearrangement of 55a and 55b each proceeds with exclusive migration of C(7)- C(8) bond, thereby affording 58a and 59a respectively. Mechanistic features of this rearrangement are discussed.
II. 4,7,1 l-trimethylpentacyclo[6.3.0.0.^2,6.0^3,l0.0^5,9]undecane-exo-4,exo-7-diol
(23a) was successfully synthesized. This diol crystallizes in a helical tubuland lattice although its molecular structure does not possess C2 rotational symmetry.
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