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Non-planar polycyclic aromatic molecules: synthesis, chemical properties and applications. / CUHK electronic theses & dissertations collectionJanuary 2013 (has links)
非平面多環芳香化合物因其獨特的結構,性能和在材料科學中的應用引起了有機化學家的濃厚興趣。此論文討論了由於引入七元環或空間位阻效應而導致扭曲的多環芳香化合物,重點強調其合成,化學性質和潛在的應用。第1章介紹了常見的非平面多環芳香烴及其有代表性的兩類分子,即芳香碗和螺烯。它們分別因包含五元環或空間原子擁擠效應而偏離平面結構。本章論述了芳香碗及螺烯的合成,分子和超分子的結構及其應用。第2章詳細闡述了關於一類空間過度擁擠的庚富瓦烯衍生物的合成,表徵及順反異構化的研究。庚富瓦烯衍生物在光異構化和熱異構化過程中具有異常高的選擇性和大的分子結構變化。這些結果表明空間過度擁擠的庚富瓦烯衍生物是一類可被潛在應用為分子開關或者分子機器的化合物。第3章闡述了一種新的具有負曲率且與六苯並蔻等π電子的多環芳烴分子。向六苯並蔻(HBC)分子中引入七元環,我們得到了一種新穎的馬鞍狀大π分子。相比先前報導的[7]圈烯,該分子的具有較小的平均高斯曲率但卻有大的分子剛性。第4章闡述了另一種同六苯並蔻等π電子體系的非平面六苯並苝衍生物。空間原子的過度擁擠導致六苯並苝衍生物存在手性扭曲和反式折疊兩種構象。在升溫條件下該兩種構象之間可相互轉變並達致平衡。該結果連同進一步的熱力學和動力學研究加深了我們對六苯並苝的構象認知。手性扭曲的分子之間同時存在著面對面和邊對面的π-π相互作用,其可被用作場效應晶體管中的半導體材料。研究表明,分子彎曲的π體系在決定前線分子軌道能級和π-π相互作用中起到至關重要作用,因此在設計新的有機半導體材料時必須加以考慮。 / Non-planar polycyclic aromatic molecules are of great interests to organic chemists because of their unique structures, properties and useful applications in materials science. Detailed in this thesis are studies toward non-planar polycyclic aromatic molecules, which are forced out of planarity either by embedded seven-membered rings or by the steric strain from atom crowding, emphasizing on their synthesis, chemical properties and potential applications. / Chapter 1 introduces nonplanar polycyclic aromatic hydrocarbons (PAHs) with focus on two representative groups of non-planar PAHs, namely aromatic bowls and helicenes, which are forced out of plane by five-membered rings and atom crowding respectively. Here aromatic bowls and helicenes are reviewed in terms of synthesis, molecular and supramolecular structures as well as applications. / Chapter 2 details a comprehensive study on synthesis, characterization and syn/anti isomerism of overcrowded heptafulvalene derivatives. It was found that the heptafulvalene derivatives have achieved unusually high selectivity in both photo-isomerization and thermal isomerization. The predominance of syn isomer in the photo-isomerization has been clearly explained with DFT calculations in terms of the arrangement of the excited state and ground state potential energy surfaces. Another interesting finding is that the energy barrier of thermal syn-to-anti isomerization is directly related to the rigidity and crowdedness of the seven-membered rings. These findings suggest that overcrowded heptafulvalene derivatives are promising candidates for molecular switches and machines. In addition, a correction of the previously claimed synthesis of hexabenzooctalene is also introduced in this chapter. / Chapter 3 presents a new negatively curved polycyclic aromatic molecule that is π-isoelectronic to the well-known hexa-peri-hexabenzocoronene (HBC). Embedding a seven-membered ring into HBC leads to a novel saddle-shaped π-molecule, whose π-backbone is slightly less curved than the previously reported [7]circulene in terms of the average Gauss curvature, but surprisingly much more rigid than [7]circulene. The resulting heptagon-embedded PAH molecules not only are of theoretical interests in relation to aromaticity and curved π-orbitals but also can serve as segments, models and, in principle, synthetic precursors for graphitic carbon networks containing negative curvature, such as graphene containing heptagonal defects and toroidal carbon nanotubes / In Chapter 4, another type of curved π-molecule that has the same number of Clar's aromatic sextets as HBC is presented. Overcrowded fjord regions in novel derivatives of hexabenzoperylene (HBP) lead to both chiral twisted and anti-folded conformers, which are found to isomerize to each other at elevated temperature to reach an equilibrium. This finding along with the study on the thermodynamics and kinetics of the thermal isomerization has improved the early understandings on the conformation of HBP. It is found that the chiral twisted molecule exhibit both face-to-face and edge-to-face π-π interactions leading to a semiconducting film, which functions as the active layer in field effect transistors. The study reveals that the curvature of π-face plays a role in determining the frontier molecular orbital energy levels and π-π interactions and thus needs to be considered when one designs new organic semiconductors. / Chapter 5 is conclusion and outlook. / Detailed summary in vernacular field only. / Luo, Jiye. / Thesis (Ph.D.)--Chinese University of Hong Kong, 2013. / Includes bibliographical references. / Electronic reproduction. Hong Kong : Chinese University of Hong Kong, [2012] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Abstracts also in Chinese. / Abstract --- p.i / 中文摘要 --- p.iii / Acknowledgement --- p.iv / Table of Contents --- p.vi / Chapter Chapter 1 --- Introduction --- p.1 / Chapter 1.1 --- Curved PAHs with non-hexagonal rings --- p.3 / Chapter 1.1.1 --- Curved PAHs with four-membered rings --- p.3 / Chapter 1.1.2 --- Curved PAHs with five-membered rings --- p.5 / Chapter 1.1.3 --- Curved PAHs with seven-membered rings --- p.17 / Chapter 1.2 --- Curved PAHs with steric strain from atom crowding --- p.20 / Chapter 1.2.1 --- General Properties --- p.20 / Chapter 1.2.2 --- Synthetic methodologies --- p.21 / Chapter 1.2.3 --- Large PAHs containing multiple helicene structures --- p.28 / Chapter Chapter 2 --- Switching and Cyclization of Overcrowded Heptafulvalene Derivatives --- p.43 / Chapter 2.1 --- Introduction --- p.43 / Chapter 2.2 --- Results and Discussion --- p.46 / Chapter 2.3 --- Conclusion --- p.64 / Chapter 2.4 --- Experimental --- p.65 / Chapter Chapter 3 --- Heptagon-Embedded Hexabenzocoronene of Negative Curvature --- p.94 / Chapter 3.1 --- Introduction --- p.94 / Chapter 3.2 --- Results and Discussion --- p.95 / Chapter 3.3 --- Conclusion --- p.102 / Chapter 3.4 --- Experimental --- p.103 / Chapter Chapter 4 --- Hexabenzoperylene: Synthesis, twisted/anti isomerization and semiconductor applications --- p.118 / Chapter 4.1 --- Introduction --- p.118 / Chapter 4.2 --- Results and Discussion --- p.120 / Chapter 4.3 --- Conclusion --- p.134 / Chapter 4.4 --- Experimental --- p.134 / Chapter Chapter 5 --- Conclusion and Outlook --- p.153 / Appendix --- p.155
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Formation and growth of polycyclic aromatic hydrocarbons by cyclopentadienyl moieties in combustionLu, Mingming 12 1900 (has links)
No description available.
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Spectroscopic Properties of Polycyclic Aromatic CompoundsTucker, Sheryl A. (Sheryl Ann) 05 1900 (has links)
The fluorescence spectrum of many polycyclic aromatic compounds (PACs) depends upon solvent polarity. The emission spectrum of PAC monomers consists of several major vibronic bands labeled I, II, etc., in progressive order. Emission intensity enhancement of select bands is observed in polar solvents.
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Azaarenes as contaminants of the urban atmosphereChen, Hung-Yu January 1997 (has links)
No description available.
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Cascade radical cyclizations of benzannulated enyne-allenes and development of new synthetic strategies for novel polycyclic aromatic compoundsYang, Yonghong, January 1900 (has links)
Thesis (Ph. D.)--West Virginia University, 2004. / Title from document title page. Document formatted into pages; contains xii, 201 p. : ill. Includes abstract. Includes bibliographical references (p. 109-123).
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Polycyclic compounds of manganese /Reginato, Nada. McGlinchey, Michael J. January 2003 (has links)
Thesis (Ph. D.)--McMaster University, 2003. / Advisor: M. McGlinchey. Includes bibliographical references (leaves 182-195). Also available via World Wide Web.
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The preparation of polycyclic aromatic compoundsShuttleworth, A. J. January 1965 (has links)
No description available.
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Tracking the History of Alberta Oil Sands Contaminants Using Lake Sediment CoresSalat, Alexandre 21 October 2019 (has links)
Petroleum hydrocarbons are emitted into the environment via natural and anthropogenic activities. Once emitted, these hydrocarbons can be transported globally, persisting and accumulating in aquatic ecosystems. In the Alberta oil sands region (AOSR), mining activities have significantly altered and polluted the surrounding aquatic and terrestrial environments with heavy metals and various petroleum hydrocarbons including polycyclic aromatic hydrocarbons (PACs). Though PACs have been tracked through time using dated lake sediment cores, separating natural and anthropogenic PACs can be difficult. In the Peace Athabasca Delta (PAD) this task is especially difficult as this region has been receiving annual inputs of naturally eroded bitumen throughout history. Petroleum biomarkers are unique petrogenic compounds (i.e. derived from petroleum) which may provide a secondary proxy to track mining impacts.
This thesis investigated the impacts of mining activities on the AOSR and the PAD using two different proxies, PAC and petroleum biomarkers. These two regions were compared to reference lakes to the south and northwest of the Athabasca oil sands formation, in order to provide a natural signal, with minimal oil sands mining contamination. Historically deposited PACs and petroleum biomarkers were analysed in radiometrically dated lake sediment cores from the AOSR and the PAD, Alberta. Sediment profiles in the AOSR (Saline Lake) showed increases in PAC fluxes for both alkylated and parent compounds coeval with mining activities. Alkylated PAC fluxes in reference lakes (Mariana Lake and BM11) increased at the height of oil sands development (1990s). PAD lakes showed no statistical increase in PAC flux through time due to high levels of naturally eroded bitumen entering the system. Parent PAC diagnostic ratios, however, showed clear shifts from pyrogenic (primarily wood burning) in pre-development sediments to petrogenically derived PACs in modern sediments, in both AOSR and PAD lakes, coeval with oil sands development. Petroleum biomarker diagnostic ratios in Saline Lake and PAD lakes remained stable through time, indicating a clear current and historical petroleum signal originating from the AOSR. Reference lakes (Mariana Lake and BM11) showed the greatest change in petroleum biomarkers. Historically, these lakes had signatures uncommon of petroleum sources, however, in recent years petroleum inputs from mining development were revealed by these petroleum biomarkers. This study compared the historical trends of several petroleum hydrocarbons in lake sediment to the historical emissions of these petroleum hydrocarbons from oil sands mining operations. Notably, we show the potential for petroleum biomarkers to trace petroleum hydrocarbon contamination in the environment.
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Toward the synthesis of polycyclic aromatic compounds as nano-carbon cagesZhang, Ruoxin, January 2008 (has links)
Thesis (M.S.)--West Virginia University, 2008. / Title from document title page. Document formatted into pages; contains vii, 45 p. : ill. Includes abstract. Includes bibliographical references (p. 24-26).
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The chemistry of nickel on the edge of polycyclic aromatic hydrocarbons /Brown, James S., January 2004 (has links)
Thesis (M.S.)--University of Missouri-Columbia, 2004. / Typescript. Includes bibliographical references (leaves 58-63). Also available on the Internet.
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