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Thesis (Ph. D.)--Ohio University, March, 1989. / Title from PDF t.p.

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Thesis (Ph. D.)--Chemistry and Biochemistry, Georgia Institute of Technology, 2004. / Collard, David, Committee Co-Chair ; Schiraldi, David, Committee Member ; Liotta, Charles, Committee Member ; Weck, Marcus, Committee Member ; Srinivasarao, Mohan, Committee Member ; Kumar, Satish, Committee Co-Chair. Vita. Includes bibliographical references.

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by Chiu Chi-Wai. / Thesis (M.B.A.)--Chinese University of Hong Kong, 1996. / Includes bibliographical references (leaves 75-78). / ACKNOWLEDGMENT --- p.ii / ABSTRACT --- p.iii / TABLE OF CONTENTS --- p.iv / LIST OF FIGURES --- p.vi / LIST OF TABLES --- p.vii / Chapter / Chapter I. --- INTRODUCTION --- p.1 / Objective --- p.1 / Background --- p.1 / Outline of Subsequent Sections --- p.2 / Summary of Conclusions --- p.3 / Chapter II. --- METHODOLOGY --- p.4 / Chapter III. --- PTA GLOBAL AND REGIONAL OUTLOOK --- p.6 / The PTA - Polyester Chain --- p.6 / Polyester Products --- p.6 / Polyester Raw Material Outlook --- p.8 / Asian PTA Supply and Demand --- p.9 / Conclusion: Asian PTA Supply and Demand --- p.11 / Chapter IV. --- COUNTRY ANALYSIS --- p.12 / Macroeconomics Overview --- p.12 / Regulatory and Investment Environment --- p.15 / India vs. China --- p.18 / Chapter V. --- MARKET ANALYSIS --- p.20 / PET Market --- p.20 / PTA Market --- p.24 / India PTA Supply and Demand --- p.26 / Conclusion: India PTA Supply and Demand --- p.27 / Chapter VI. --- TECHNICAL ANALYSIS --- p.28 / Oxidation --- p.28 / Purification --- p.29 / Chapter VII. --- ECONOMIC ANALYSIS --- p.31 / Review of Petrochemical Industry in India --- p.31 / Project Economics and Assumptions --- p.34 / Conclusion --- p.43 / Chapter VIII. --- PROJECT FUNDING ANALYSIS --- p.49 / Risk Factors --- p.50 / Principle Terms of Bank Syndication --- p.56 / Chapter IX. --- CONCLUSION --- p.58 / Current Environment and Future Trends --- p.58 / Investment Opportunity --- p.60 / Summary of Economic Analysis --- p.60 / Factors for Future Success --- p.61 / APPENDIX --- p.62 / BIBLIOGRAPHY --- p.75

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The effect of process conditions, temperature, time and rate of temperature rise, on the exhaustion of disperse dye on polyester yarn under High-Temperature dyeing conditions was investigated. Two ply spun type Dacron 54 polyester yarn was dyed with Disperse Red 60 in 0.5 g/l dye bath concentration using an Ahiba Texomat Dyeing Apparatus under High-Temperature Dyeing conditions. The dyeing process design used, consists of three levels of dyeing temperature (105°C, 120°C, 135°C), four levels of holding time (0 min, 15 min, 30 min, 60 min) and two levels of rate of temperature rise (1ºC/min, 3°C/min). After the dyeing process, the dye concentration in the yarn was obtained through extraction and measured spectrophotometrically. A factorial analysis of variance (ANOVA) test was used to determine whether or not significant differences existed among dyeing process conditions in regard to the dye uptake of the yarn. If significant differences existed, which parameter of process conditions (temperature, time, rate of temperature rise or their interactions) was responsible. The results of this study indicated that a three-way interaction of temperature, time, and rate of temperature rise was responsible for the differences in dye uptake of the yarn. The dye uptake of the yarn increased by increasing dyeing temperature from 105°C to 120°C for all levels of holding time and rate of temperature rise. However, increasing dyeing temperature from 120°C to 135°C, did not increase dye uptake of the yarn. The dye uptake of the yarn increased by increasing holding time from zero to 15 minutes for dyeing temperature of 120°C. However, increasing holding time from 15 to 60 minutes, did not increase dye uptake of the yarn. At the dyeing temperature of 120°C, a slower rate of temperature rise resulted in greater dye uptake of the yarn. It can be concluded that high temperature dyeing of polyester yarn at 120°C for 15 minutes with a rate of temperature rise of 1°C/min was the optimum dyeing process in achieving full exhaustion. / Master of Science

The effect of carrier concentration and dye type on carrier and dye uptake of Dacron type 54 yarn was determined. Disperse Red 60 and Disperse Yellow 54 dyes were used. 0-phenyl phenol was used with six different concentrations of this carrier (0, 1, 2, 3, 4 and 5 gm/l). Spun Dacron type 54 polyester yarn of 490 denier weighing ten grams was obtained. Dyeing was done using the Ahiba Texomat dyeing machine. The standard composite curves and equations were established for both dyes as well as the carrier. The dye in the yarn was extracted with dimethyl formamide as a solvent using the Fisher Shaking Water Bath. To measure the dye and carrier uptake of the polyester yarn, the extraction and dye bath solutions were analyzed spectrophotometrically. A two-way factorial Analysis of Variance (ANOVA) was used to test the hypotheses. The first null hypothesis indicating that there will be no difference in the uptake of disperse dye by polyester fiber due to initial carrier concentration was rejected. The second null hypothesis indicating that there will be no difference in the uptake of disperse dye by the polyester fiber due to dye type was also rejected. The third and fourth null hypotheses of no difference in the carrier uptake of polyester fiber due to initial carrier concentration and dye type respectively were likewise rejected. The results of this study indicated that both carrier concentration and dye type as well as their interaction have a significant effect on dye and carrier uptake of the polyester yarn. / Master of Science

Changes in nylon 6.6 and polyester filament yarns were determined after heat treatment with dry heat at various temperatures under constant length conditions. An attempt was made to relate structural changes and changes in physical properties due to heat setting. Density, obtained by the density gradient column technique, was used to calculate the degree of crystallinity as a structural parameter. Filament tensile strength and elongation at break were measured on a constant-rate-of-extension machine, and then toughness of the sample was obtained from the load elongation curve. The amount of dye uptake was estimated spectrophotometrically. Degree of crystallinity increased significantly as temperature increased for both nylon 6.6 and polyester fibers. Tenacity decreased substantially for nylon 6.6 and increased marginally for polyester. Elongation and toughness at break decreased for both nylon 6.6 and polyester. Tenacity of nylon 6.6 decreased despite an increase in degree of crystallinity. This suggests degradation of the fibers. Therefore, degree of crystallinity appeared to be of little importance as a contributor to change in tensile strength for degraded nylon 6.6. Tenacity of polyester was well predicted by degree of crystallinity. As crystallinity increased, tenacity of polyester increased. Elongation and toughness of both nylon 6.6 and polyester decreased as degree of crystallinity increased, but the relationship to crystallinity for polyester was not significant. Dyeability of both nylon 6.6 and polyester was well predicted by degree of crystallinity. In both cases, the amount of dye uptake decreased as crystallinity increased. This research suggests that determinations for structural changes such as degradation and orientation might be utilized in addition to crystallinity to predict tenacity of nylon 6.6 and elongation and toughness of polyester. / Ph. D.