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The photophysics of naphthalene containing synthetic polymersCarey, Michelle Jocelyn January 1995 (has links)
No description available.
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A study of conjugated polymers and their applications in light-emitting diodesDailey, Stuart January 1998 (has links)
The initiation of research into conjugated polymer electroluminescent devices in Durham is reported. The apparatus required for the fabrication and characterisation of polymer light-emitting diodes (LEDs) is outlined, and the essential assumptions and calculations required to determine their efficiency, brightness and colour are summarised. Optical and electrical characterisation of a range of polymers is reported, including polypyridine (PPY) and a range derivatives, poly(p-phenylene vinylene) (PPV) and poly(2-methoxy, 5-(2'ethyl-hexyloxy)-p-phenylene vinylene) (MEH-PPV). The optical properties of PPY in solution, film and dilute solid state are characterised. The conjugation length of PPY is investigated by deliberate disruption of the conjugation by the inclusion meta-links in the otherwise para-linked polymer. The effect of altering the chemical structure of PPY is investigated by the study of some PPY derivatives including random and regular copolymers. The consequences of using precursor polymers, especially the effects of conversion on indium tin oxide coated substrates are investigated using absorption and luminescence spectroscopy and capacitance-voltage analysis. Electroluminescence from a number of conjugated polymers is reported and the efficiency, spectral output and device characteristics are presented. The formation of Schottky barriers in some polymer devices is investigated using quasi-static capacitance-voltage measurements. Improvements in the quantum and power efficiency of polymer LEDs have been achieved using two hole-transporting polymers, poly(vinyl carbazole) and the doped, conducting form of polyaniline. A substantial improvement in quantum efficiency has also been demonstrated when PPY is used as an electron-transporting layer in PPV and MEH-PPV based light-emitting diodes. The variation in quantum efficiency and emission spectrum with the ratio of the thickness of the two polymer layers is reported and analysed.
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Enhancing fluorescence and charge transport in disordered organic semiconductorsThomas, Tudor Huw January 2018 (has links)
High performance optoelectronic applications require simultaneously high mobility ($\mu$) and high quantum efficiency of fluorescence ($\Phi$). While this has been realised for organic small molecule semiconductors, applications such as high efficiency organic photovoltaics and bright organic light-emitting diodes towards electrically driven lasing are hampered by an apparent trade-off between $\mu$ and $\Phi$ in disordered systems. Recent reports of state-of-the-art device performance often optimise $\mu$ and $\Phi$ in disordered organic materials separately, and employ multi-layer architectures. In this work, we investigate materials in a class of donor-acceptor polymer materials; the indacenodithiophene-$\textit{alt}$-benzothiadiazole family, which demonstrate high $\mu$ in spite of a low long-range structural order, to understand the interplay between these two important device figures-of-merit. In the first section, we evaluate the effect of various tuneable parameters on $\mu$ and device performance in organic field-effect transistors. Using chemical modifications to the solubilising side chains, we observe that the substitution of bulky groups leads to a reduction of the hole mobility $\mu_h$ > 2 cm$^{2}$/Vs to ~ 0.5 cm$^{2}$/Vs in the benchmark polymer of this family, indacenodithiophene-$\textit{alt}$-benzothiadiazole. Crystallographic and exciton-quenching based experiments confirm this observation is closely related to the degree of polymer backbone aggregation, and this leads to a different temperature evolution of the transport behaviour. In order to reliably improve $\mu$ in these systems, an elongation of the donor subunit is required. This increases the $\pi$-electron density on the donor, and can lead to an improvement in $\mu$ where the side chain density is decreasing. This chemical design, leading to a more highly aggregated structural motif is much more potent in determining $\mu$, it seems, than design strategies to further improve the energetic disorder in the joint density of states and the potential barrier to torsion, which may be near optimised in these low-disorder systems. In the second section, we unpick the precise relationship between the degree of aggregation apparently linking high $\mu$ to low $\Phi$. With a prototype system, we compare the photophysics of two indacenodithiophene-$\textit{alt}$-benzothiadiazole polymers differing by side chain bulkiness. Despite the aforementioned suppression of $\mu$, we observe an improvement to $\Phi$ of $< 0.02$ to $\sim 0.18$ upon backbone separation. This derivative has the highest $\Phi$ reported for any polymer with $\mu$ exceeding that of amorphous-Si. However, the $\Phi$ in the more aggregated derivative is not limited by the formation of non-emissive excitons, but rather by an additional internal conversion pathway which is strongly temperature dependent, and mediated by Raman-active vibrations and close chain coupling. Extending this study, we analyse additional materials in this family with the highest $\Phi \cdot \mu$ values reported for conjugated polymers. We find that increasing the energy gap leads to an increase in $\Phi$, and secondary emission pathways via weakly luminescent inter-chain charge transfer species. By solving the rate equations for exciton recombination, we use the radiative rate of inter-chain luminescence as a probe to show strong wavefunction mixing at close-contact points for some polymers, and suggest this as the origin for a superior $\mu$ in dithiopheneindenofluorene-$\textit{alt}$-benzothiadiazole compared to indacenodithiophene-$\textit{alt}$-benzothiadiazole. We demonstrate how low $\mu$ can be decoupled from the energy gap ($E_g$), and propose backbone elongation leading to increased inter-chain wavefunction overlap and a higher $E_g$ as a design rule to increase $\Phi$ and $\mu$ together. Finally, we assess the role of low-frequency vibrations in organic semiconductors displaying thermally activated delayed fluorescence (TADF). In the low-aggregation limit where $\Phi$ is maximised, we show that non-radiative triplet recombination is strongly related to low frequency torsional motion, and both are reduced in the presence of a rigid polymer host matrix for various TADF materials across different classes. However, we also explore the importance of rotational freedom in determining the oscillator strength, exchange energy, and spin-orbit coupling matrix elements which mediate luminescence in the absence of a rigid host. We demonstrate that suppressing dynamic motion is a powerful tool to modulate the photophysical properties of these emitters, and can lead to improved $\Phi$ particularly for low $E_g$ emitters.
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