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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Analytical model for phonon transport analysis of periodic bulk nanoporous structures

Hao, Qing, Xiao, Yue, Zhao, Hongbo 25 January 2017 (has links)
Phonon transport analysis in nano- and micro-porous materials is critical to their energy-related applications. Assuming diffusive phonon scattering by pore edges, the lattice thermal conductivity can be predicted by modifying the bulk phonon mean free paths with the characteristic length of the nanoporous structure, i.e., the phonon mean free path (Lambda(pore)) for the pore-edge scattering of phonons. In previous studies (Jean et al., 2014), a Monte Carlo (MC) technique have been employed to extract geometry determined Lambda(pore) for nanoporous bulk materials with selected periods and porosities. In other studies (Minnich and Chen, 2007; Machrafi and Lebon, 2015), simple expressions have been proposed to compute Lambda(pore). However, some divergence can often be found between lattice thermal conductivities predicted by phonon MC simulations and by analytical models using Lambda(pore). In this work, the effective Lambda(pore) values are extracted by matching the frequency-dependent phonon MC simulations with the analytical model for nanoporous bulk Si. The obtained Lambda(pore) values are usually smaller than their analytical expressions. These new values are further confirmed by frequency-dependent phonon MC simulations on nano porous bulk Ge. By normalizing the volumetric surface area A and Lambda(pore) with the period length p, the same curve can be used for bulk materials with aligned cubic or spherical pores up to dimensionless p.A of 1.5. Available experimental data for nanoporous Si materials are further analyzed with new Lambda(pore) values. In practice, the proposed model can be employed for the thermal analysis of various nanoporous materials and thus replace the time-consuming phonon MC simulations.

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