abstract: Portable devices rely on battery systems that contribute largely to the overall device form factor and delay portability due to recharging. Membraneless microfluidic fuel cells are considered as the next generation of portable power sources for their compatibility with higher energy density reactants. Microfluidic fuel cells are potentially cost effective and robust because they use low Reynolds number flow to maintain fuel and oxidant separation instead of ion exchange membranes. However, membraneless fuel cells suffer from poor efficiency due to poor mass transport and Ohmic losses. Current microfluidic fuel cell designs suffer from reactant cross-diffusion and thick boundary layers at the electrode surfaces, which result in a compromise between the cell's power output and fuel utilization. This dissertation presents novel flow field architectures aimed at alleviating the mass transport limitations. The first architecture provides a reactant interface where the reactant diffusive concentration gradients are aligned with the bulk flow, mitigating reactant mixing through diffusion and thus crossover. This cell also uses porous electro-catalysts to improve electrode mass transport which results in higher extraction of reactant energy. The second architecture uses porous electrodes and an inert conductive electrolyte stream between the reactants to enhance the interfacial electrical conductivity and maintain complete reactant separation. This design is stacked hydrodynamically and electrically, analogous to membrane based systems, providing increased reactant utilization and power. These fuel cell architectures decouple the fuel cell's power output from its fuel utilization. The fuel cells are tested over a wide range of conditions including variation of the loads, reactant concentrations, background electrolytes, flow rates, and fuel cell geometries. These experiments show that increasing the fuel cell power output is accomplished by increasing reactant flow rates, electrolyte conductivity, and ionic exchange areas, and by decreasing the spacing between the electrodes. The experimental and theoretical observations presented in this dissertation will aid in the future design and commercialization of a new portable power source, which has the desired attributes of high power output per weight and volume and instant rechargeability. / Dissertation/Thesis / Ph.D. Mechanical Engineering 2010

Large Scale Wind Turbines (LSWTs) have been extensively examined for decades but very few studies have been conducted on the small scale wind turbines (SSWTs) especially for the applications near ground level where wind speed is of order of few meters per second. This study provides the first systematic effort towards design and development of SSWTs (rotor diameter<50 cm) targeted to operate at low wind speeds (<5 m/s). An inverse design and optimization tool based on Blade Element Momentum theory is proposed. The utility and efficacy of the tool was validated by demonstrating a 40 cm diameter small-scale wind energy portable turbine (SWEPT) operating in very low wind speed range of 1 m/s-5 m/s with extremely high power coefficient. In comparison to the published literature, SWEPT is one of the most efficient wind turbines at the small scale and very low wind speeds with the power coefficient of 32% and overall efficiency of 21% at its rated wind speed of 4.0 m/s. It has very low cut-in speed of 1.7 m/s. Wind tunnel experiments revealed that SWEPT has rated power output of 1 W at 4.0 m/s, and it is capable of producing power output up to 9.3 W at wind speed of 10 m/s. The study was further extended to develop a piezoelectric wind turbine which operates below 2.0 m/s wind speed. The piezoelectric wind turbine of overall dimension of 100mm x 78mm x 65mm is capable of producing peak electric power of about 450 microwatt at the rated wind speed of 1.9 m/s. / Master of Science

Distributed hydrogen generation from liquid hydrocarbon fuels to supply portable fuel cells presents an attractive, high energy density alternative to current battery technology. Traditional unit operation reactor design for hydrogen generation becomes inadequate with decrease in scale because of the unique challenges of size and weight minimization. To address the challenge of reactor scale-down, the concept of multifunctional reactors has emerged, in which synergistic combination of different unit operations is explored to achieve improved performance. The direct droplet impingement reactor (DDIR) studied here is based on this approach in which the liquid feed is atomized using a regularly spaced array of droplet generators with unparalleled control over droplet characteristics, followed by vaporization and reaction directly on the catalyst surface. Considering each droplet generator in the array as a unit cell, a comprehensive, first-principles model of the DDIR has been developed by considering the intimately coupled processes of 1) droplet transport, heating, evaporation, and impingement on the catalyst surface, 2) liquid reagent film formation, capillary penetration, and vaporization within the catalyst layer, and 3) gas phase heat and mass transfer and catalytic reactions. Simulations are performed to investigate the effect of reactor operating parameters on performance. Experimental validation of the model is carried out by visualizing droplet impingement and liquid film accumulation while simultaneously monitoring reaction product composition over a range of operating conditions. Results suggest an optimal unit cell shape for reaction selectivity based on a balance between reagent back diffusion and catalyst bed thermal resistance. Further, achieving a target throughput is best accomplished by adding together a larger number unit cells with optimized geometry and lower throughput (per unit cell) to more effectively spread heat and avoid hotspots at the catalyst interface. At the same time, conditions must be satisfied for ensuring droplet impingement on the catalyst surface, which become more stringent as unit cell throughput is decreased.

This diploma thesis is divided into two parts, namely the theoretical and practical part. In the theoretical part, the issue is dismantled from the current state of electric power, share the production of individual sources, the market for photovoltaic and mobile photovoltaic systems through the description of the theory of solar radiation and all the necessary components to build the isolated photovoltaic power plant. The practical part deals with dimensioning, selection of suitable components and the actual one own design and implementation of a mobile photovoltaic power plant.