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FABRICATION OF SOLID, POROUS, AND MAGNETIC CERAMIC MICROPARTICLES VIA STOP-FLOW LITHOGRAPHYAlejandro Manuel Alcaraz Ramirez (7469432) 30 April 2020 (has links)
<p>Microparticles
have been investigated not only as feedstock spherical or amorphous bulk
materials used for shape molding, but also as agents that can perform work in
the micron scale. The fabrication of microparticles with active properties of
self-propulsion, self-assembly, and mobility with enhanced mechanical, thermal,
and chemical properties is of particular interest for emerging technologies
such as drug delivery, micro-robotics, micro energy generation/harvesting, and
MEMS. Conventional fabrication methods can produce several complex particle
shapes in one fabrication session or hundreds of spheroid shaped particles per
second. Innovative techniques, as flow lithography, have demonstrated control
over particle form and composition for continuous fabrication cycles. In recent years predefined shape polymer microparticles have been
fabricated as well as ceramic microparticles through suspension processing with
these set of techniques. Even though ceramic materials have been fabricated,
there is still a strong need to increment the palette of available materials to
be processed via flow lithography. We have pioneered the production of shaped
ceramic microparticles by Stop-Flow Lithography (SFL) using
preceramic polymers, providing control of particle size and shape in the range
of 1 – 1000
μm. The principal arranged technique (SFL) combines aspects of
PDMS-based microfluidics and photolithography for the continuous cyclable fabrication
of microparticles with predefined shapes. The PDMS microchannel devices used
were fabricated with vinyl film molds in a laminar hood avoiding the need for a
cleanroom, procedure that reduced fabrication costs. After a fabrication
session, the preceramic polymer microparticles were collected, washed, and
dried before entering an inert atmosphere furnace for pyrolysis. Additionally, by treating the material initially as liquid polymer,
special properties can be added by converting it into an emulsion or a
suspension. Microparticles
were functionalized by introducing porosity and magnetic nanoparticles in the
preceramic polymer matrix. The porous characteristic of a particle leads to an
increase in surface area, allowing the particle to be infiltrated with a
catalyzer or act as a chemical/physical carrier, and the magnetic behavior of
the particles allows a controllable trajectory with defined external magnetic
fields. These two properties can be used to fabricate bifunctional
microparticles to serve as drug carriers through human arteries and veins for drug delivery purposes.
We
successfully fabricated solid and functional ceramic microparticles in the 10 – 50
μm range with predefined shapes as hexagons, gears, triangles, and ovals. This
system is an economical route to fabricate functional defined shape particles
that can serve as microrobots to perform tasks in liquid media.</p>
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Late Preceramic Period Public Architecture and the Conceptual Challenge of Andean Urbanism / La arquitectura pública del Periodo Precerámico Tardío y el reto conceptual del urbanismo andinoMakowski Hanula, Krzysztof 10 April 2018 (has links)
An analysis of the architecture and spatial organization of the Caral-Chupacigarro complex is compared with Pachacamac and other Central Andean prehispanic settlements and also with Çatal Hüyük in Anatolia. It is concluded that the term "settled ceremonial center" describes these sites better than the term "city". The formal diversity of the architectural spaces that make up these early monumental complexes is explained by the ritual activities carried out at them, including banquets, feasts, dances, offerings, sacrifices, etc. The differences in size, volume, and duration of continuous use of buildings in the same complexes, as well as the ceremonial centers, is believe to have no relationship with the number of permanent settlers at them; rather, it is suggested to be directly proportional to the number of regular visitors, and therefore, to the religious and political prestige of these sites. The construction of monumental ceremonial spaces, jointly used by a single community or by an alliance of several communities, and their maintenance and eventual expansion are, in this context, a mechanism for the materialization of the memory of the ritual kinship relations established and periodically legitimized through shared rituals at these localities. / El análisis de la arquitectura y de la organización espacial del complejo Caral-Chupacigarro en comparación con Çatal Hüyük, por un lado, y con Pachacamac y otros asentamientos complejos prehispánicos en los Andes centrales por el otro, lleva al autor a la conclusión de que la expresión "centro ceremonial poblado" describe mejor sus características que el término "ciudad". La diversidad formal de ambientes arquitectónicos de la que se componen los edificios monumentales tempranos se explicaría por las necesidades involucradas en el culto como, por ejemplo, banquetes, ayunos, bailes, ofrendas y sacrificios. Las diferencias en la extensión, volumen construido y duración del uso continuo tanto entre los edificios del mismo complejo como entre diferentes centros ceremoniales no guardan relación proporcional directa con el número de eventuales habitantes permanentes, pero sí con el de la cantidad de visitantes periódicos y, por ende, con su prestigio religioso y político. En este contexto, la construcción del espacio ceremonial y monumental de manera mancomunada por una comunidad o por una alianza de varias comunidades, su mantenimiento y eventuales ampliaciones se constituyen en el mecanismo de materialización de la memoria sobre los lazos de parentesco ritual establecidos por este medio, el que se legitima periódicamente gracias a determinados rituales compartidos.
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