The International Maritime Organization(IMO) has adopted a draft of the International Convention for the Prevention of Pollution from Ships, 1973, as modified by the Protocol of 1978 relating thereto and by the Protocol of 1997(termed as MARPOL 73/78/97)since September 1997, amended the Convention and added a new Annex VI which regulates gas pollution emitted from ships, the latest Annex came into effect after the MARPOL convention. This study aims to discuss the effect of the Annex VI Prevention of Air Pollution from Ships after it was implemented on 19 May 2005 and the growth and decline status of pollution by document analysis and quantitative analysis methods. This study find that there were different concern positions from each PSC region, the enforcement state of Europe, Asia-Pacific and Indian Ocean regions were better than Black Sea, west and central Africa, Latin America and Caribbean regions. The statistical show that sulfur oxides decreased notably, nitrogen oxides and carbon dioxides decreased slowly by UNFCCC web; in addition, some countries did not submit their gas inventory, including developed countries: Canada, United States of America, Japan, Luxembourg and Netherlands et al. The quantitative analyses show that some countries has decreased or slow down the ship-source gas pollution with countries¡¦ economy developed, including Denmark, Ireland, Norway, Germany, Belgium, Luxembourg, Japan, Australia and United States of America et al.