The aim of the study, which was carried out in two main parts, was to investigate the atomic and magnetic ordering in various full Heusler alloy systems.In the theoretical part of the thesis, investigations based on the statiscothermodynamical theory of ordering by means of Bragg-Williams-Gorsky (BWG) method combined with electronic theory in the pseudopotential approximation have been conducted to model order-order (L21&amp / #8596 / B2) and order-disorder (B2&amp / #8596 / A2) phase transformations in Ni-Mn-C (C=Ga, In, Sb) and A2BGa (A=Fe, Ni, Co / B=Ni, Mn, Co, Fe) Heusler alloys. The partial ordering energies, calculated according to the electronic theory of alloys in pseudopotential approximation for the first two coordination spheres were utilized as input data for the theoretical superlattice formation models based on BWG approximation. Furthermore, the trends of L21&amp / #8596 / B2 transition temperatures with electron concentration at A, B and C atomic sites were determined. In the experimental part of the thesis, structural and magnetic properties of Ni-Mn-Ga and Ni-Mn-Al Heusler alloys were investigated. For the Ni-Mn-Ga Heusler alloy system, it was found that the martensitic (TM) and Curie temperatures (TC) merge for Ni54Mn20Ga26 and Ni56Mn18Ga26 alloys by compositional tuning. For the Ni-Mn-Al Heusler alloy system, it was found that ferromagnetism was introduced into these alloys by low temperature aging, as a result of the stabilization of the L21 phase. In addition to that, magnetocaloric effect (MCE) was determined in the vicinity of the first order magneto-structural transition for Ni-rich Ni-Mn-Ga alloys and near the second order magnetic transition for the Ni2MnAl alloy.

Nickel zinc ferrites (NZF) have been considered as one of the basic components in high frequency electromagnetic applications especially in the field of telecommunications. In the present study, the aim was to produce high quality nickel zinc ferrite ceramics at low soaking temperatures. For this purpose, conventional ceramic manufacturing method based on mixed oxide precursors was followed using calcium fluoride, CaF2, as sintering additive. During the sintering studies, it was noticed that both the microstructure and the electromagnetic properties of the NZF ceramics were modified to a great extent by CaF2. Therefore, material characterization studies involving microstructural, dielectric and magnetic properties were conducted with respect to CaF2 content of ceramics and soak duration. The results showed that due to the presence of CaF2 in ceramics, significant improvements were achieved not only in kinetics of sintering but also in the parameters / DC electrical resistivity, dielectric constant and dielectric loss factor. For example, 1.0 wt% CaF2 added NZF ceramic produced in this study had a DC electrical resistivity of 1011 &amp / #61527 / -cm which was 100,000 times bigger than the one attained in pure NZF ceramic. On the other hand, the dielectric constant exhibited a flat behavior up to 40 MHz with a value around 16. In addition, no resonance peak was observed in dielectric loss factor spectra, and the typical values of dielectric loss factor lied below 0.01. Besides the achievements mentioned, the magnetic properties such as relative magnetic loss factor and hysteresis parameters were also improved.