Thesis (Ph. D.)--University of Hawaii at Manoa, 2002. / Includes bibliographical references (leaves 181-215). Also available on microfiche.

Th.--Sci. phys.--Grenoble 1, 1985.

The vapour pressures of various salts have been investigated at high temperatures and the results are presented here together with the values found by previous investigators. Sodium sulphate is extensively used in the glass producing industry and it is in this compound that interest is centred. Other salts have been included in this study for the purpose of comparison. The use made of sodium sulphate in glass making is discussed briefly below. Work previously reported on the determination of the vapour pressure of sodium sulphate will be shown to have produced confusing results, and it was for the purpose of introducing some harmony into the sometimes discordant evidence that the present work was undertaken.

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Brookhaven National Laboratory experiment E949 was designed to search for the rare K meson decay K⁺ → π⁺ , neutrino, and anti-neutrino, a decay sensitive to physics beyond the Standard Model. While previous data analyses dealt with the high π⁺ momentum region accessible for this reaction, this thesis concentrates on the lower range between 140 and 199 MeV/c. Analysis of this low π⁺ momentum region was performed to search for additional evidence of the process K⁺ → π⁺, neutrino, and anti-neutrino. A blind analysis technique was used to avoid bias when developing the selection criteria used to suppress the competing background processes. The blind analysis technique was based on identifying background sources a priori and only examining the signal region once all selection criteria and background estimates had been finalized. The background estimates were performed using a technique known as a "bifurcation method", which relied on using two uncorrelated selection criteria to suppress each background source. The analysis of an exposure of 1.71 x 10¹² K⁺ decays resulted in an observation of three events with an estimated background of 0.927 ± 0.168(stat.)⁺³²⁰-₀.₂₃₇(sys.) events and a single event sensitivity of (4.28 ± 0.43)x 10-¹⁰. Using a likelihood method, the three candidate events observed here were combine with the previous E787 and E949 results, yielding a branching ratio of ϐ(K⁺ → π⁺, neutrino, and anti-neutrino decay of (1.73+1.15-1.05) x 10⁻¹⁰ at the 68% confidence level. This branching ratio is consistent with the prediction of the Standard Model, (0.85 ± 0.07) x 10⁻¹⁰. / Science, Faculty of / Physics and Astronomy, Department of / Graduate

Erbium, a rare earth element, has been shown to exhibit characteristic luminescence at 1.54mum due to its internal 4f transition from the first excited state (4pi3/2) to the ground state (4pi5/2). As this emission wavelength falls inside the maximum transmission window of silicon based optical fibers, erbium doped silicon might lead to the opportunity of silicon based optoelectronics. The introduction of erbium in silicon allows excitation through electron-hole recombination and subsequent radiative emission from the rare earth centers. The works reported here describe the structural, electrical and optical properties of crystalline silicon codoped with erbium and boron by ion implantation technique. Four sets of samples, co-implanted with erbium and boron at different Er dose, implantation energy and at different conditions, were prepared. Post-implantation annealing has been performed to recover the implantation damage to an acceptable value and to activate the dopant atoms optically and electrically. PL and EL measurements have been performed in the temperature range between 80K to room temperature. The sample with the lowest erbium concentration and energy gives the best PL and EL results. The observed emission peaks in both PL and EL measurements were at around 1.129mum, ~1.303mum, 1.50mum and 1.597mum at 80K. At higher temperatures, a broader peak at around 1.50mum with long tail towards the both end of wavelength has been observed. The peak at 1.129mum corresponding to the Si band edge emission, the reason for the peaks at around l.303mum has not been identified while the remaining two peaks correspond the Er3+ emission. Virtually no temperature quenching of Er luminescence is observed in some samples rather room temperature intensity is higher than that at 80K. The improvement of the temperature quenching effect on Er luminescence at room temperature has been attained in our results, which is significant improvement in comparison to the result found in the literature. The structural properties were studied by TEM in both cross-sectional and plan view configurations. TEM analyses showed dislocation loops and other defects of random size and distribution from the surface to 600nm below the surface. Er precipitates defects were also seen in the sample doped with Er comparatively at higher dose (1x1015Er/cm2) and energy (1.0 MeV). No detectable room temperature PL and EL signals were observed from the sample implanted at higher doses and energies.

Luminescent lanthanide coordination complexes have attracted significant attention due to their unique optical properties. The poor absorption of a lanthanide ion can be resolved by so-called antenna effect and improve the intensity of its luminescence. Three bidentate chromophores: phosphate-pyridine chromophore, 1,2-Hydroxy pyridone (1,2-HOPO) and 2-thenoyltrifluoroacetone (TTA), functioned as both chelator and sensitizer, their energy levels are well matched with the excited state energy levels of the Eu(III) and Sm(III).. To get highly luminescent and stable lanthanide complex, we designed and synthesized various Eu(III) complexes with different backbones to compare different parameters that will affect the sensitizing efficiency of the chromophores, such as rigidity, geometry and coordination saturation.. In chapter two we combined the phosphate-pyridine chromophore with the well-studied cyclen-based chelator to fulfil the requirement of high stability and brightness. We designed a nine-coordinate europium(III) complex as platform, through coupling reactions to realise fast screen of the chromophores energy transfer efficiency.. Chapter three focuses on the structure modifications based on the chromophore of 1,2-HOPO, different chelators and backbones were compared, a europium complex EuL4 with the highest quantum yield with this chromophore was obtained and it could goes into cells and localized on lysosome very fast. Two-phonon in vitro imaging was done which showed its high potential bioapplications.. Chapter four focuses on the structure modification based on the chromophore of TTA. Different backbone directly determined the europium complexes saturation number and sensitization efficiency, therefore, their quantum yields.

No description available.

The ligands di(2-pyridyl) ketone (DPK) and cis-1,2 di(2-pyridyl) ethylene (DPE) are N,N,Odonor ligands that can undergo nucleophilic addition and become more flexible for coordination. The reaction between the lanthanide thiocyanate salt and DPK gave rise to seven novel complexes of the general formula [Ln(NCS)3(DPKOH)3], where Ln = La, Ce, Nd, Eu, Tb, Dy and Ho. 1H NMR spectroscopy verified that the ligand underwent nucleophilic addition upon coordination. This was further confirmed using UV-Vis spectroscopy which showed a shift in the absorption bands due to conjugation of electrons within the pyridyl ring upon coordination. UV-Vis spectroscopy was also utilised to test the covalent character of the neodymium and holmium complexes. X-ray diffraction and IR spectroscopy showed that three DPK ligands coordinated bidentately through a pyridinic nitrogen and a hydroxyl oxygen, while three isothiocyanato molecules completed the coordination environment around each metal. Furthermore, X-ray diffraction also revealed that these complexes are isostructural, ninecoordinate and the polyhedron which encloses each ion is of trigonal tricapped prismatic shape with D3h symmetry. Micro-analysis on all the complexes, except lanthanum and holmium confirmed the molecular formulae produced from the crystallographic data of each complex. The reaction between the lanthanide thiocyanate salt and DPE produced poor quality crystals which could not be detected by X-ray diffraction. The lanthanide salts used for this reaction were lanthanum, neodymium, europium, dysprosium and holmium. Upon coordination, conductivity measurements detected the presence of lanthanide ions in each solution. 1H NMR and IR spectroscopic studies showed that the ethylenic moiety of DPE underwent nucleophilic addition upon coordination. UV-Vis spectroscopy further confirmed nucleophilic addition upon coordination due to shifts in absorption bands. IR spectroscopy verified the possibility of a bidentate coordination to each metal through a pyridinic nitrogen and a hydroxyl oxygen as well as a monodentate coordination through isothiocyanato ligands. A micro-analysis on all the complexes provided the molecular formulae that can best fit each complex. The effect of the solvent molecules on the bonding parameters of the lanthanum complex was investigated. An analysis of the results produced from crystallographic data revealed the presence of intermolecular forces which interacted and stabilised the complex.