Thesis (M.S.)--Rochester Institute of Technology, 2006. / Typescript. Includes bibliographical references (leaves 182-186).

Energy plays a vital role in socio-economic development and raising living standards of human beings. The overreliance on fossil fuels results in the depletion of fossil fuels as well as environmental pollution from the green-house gases that result from the use of fossil fuels. Biomass feedstock are able to ameliorate this situation by utilizing the CO2 that has been used by plants during photosynthesis. This study investigated the suitability of the three garden grass species (Chloris gayana, Cynodon dactylon and Pennisetum clandestum) as biomass feedstock for gasification purposes. The three garden grass species were collected at the Alice Campus of the University of Fort Hare. These grass species were characterized using elemental analyser (CHNS), FT-IR, EDX and TGA. The Activation energy (Ea) of the three grass species were 48.22 kJ/mol for P. clandestum, 36.8 kJ/mol for C. gayana and 258 kJ/mol for C. dactylon. Of the three grass species, C. gayana had the lowest Activation energy of 36.8 kJ/mol and also had the highest maximum efficiency of 69 percent compared to 65.3 percent for P. clandestum and 63.5 percent for C. dactylon. Actual gasification was not carried out but the results on maximum efficiency were obtained from computer simulation of gasification.

Organo-metallic halide perovskite solar cells (PSCs) are considered as a promising alternative photovoltaic technology due to the advantages of low-cost solution fabrication capability and high power conversion efficiency (PCE). PSCs can be made using a conventional (n-i-p) structure and an inverted (p-i-n) configuration. PCE of the conventional p-i-n type PSCs is slightly higher than that of the inverted n-i-p type PSCs. However, the TiO2 electron transporting layer adopted in the conventional PSCs is formed at a high sintering temperature of >450 °C. The TiO2 electron transporting layer limits the application of conventional PSCs using flexible substrates that are not compatible with the high processing temperature. The hole extraction layer (HEL) in the inverted p-i-n type PSCs can be prepared by low-temperature solution fabrication processes, which can be adopted for achieving high performance large area flexible solar cells at a low cost. Inverted PSCs with a PCE range from 10 to 20% have been reported over the past few years. In comparison with the progresses of other photovoltaic technologies, the rapid enhancement in PCE of the PSCs offers an attractive option for commercial viability. The aim of this PhD project is to study the origin of the improvement in the performance of solution-processable inverted PSCs. The surface morphological and electronic properties of the HEL are crucial for the growth of the perovskite active layer and hence the performance of the inverted PSCs. Enhancement in short circuit current density (Jsc), reduced loss in open circuit voltage (Voc), improvement in cha Organo-metallic halide perovskite solar cells (PSCs) are considered as a promising alternative photovoltaic technology due to the advantages of low-cost solution fabrication capability and high power conversion efficiency (PCE). PSCs can be made using a conventional (n-i-p) structure and an inverted (p-i-n) configuration. PCE of the conventional p-i-n type PSCs is slightly higher than that of the inverted n-i-p type PSCs. However, the TiO2 electron transporting layer adopted in the conventional PSCs is formed at a high sintering temperature of >450 °C. The TiO2 electron transporting layer limits the application of conventional PSCs using flexible substrates that are not compatible with the high processing temperature. The hole extraction layer (HEL) in the inverted p-i-n type PSCs can be prepared by low-temperature solution fabrication processes, which can be adopted for achieving high performance large area flexible solar cells at a low cost. Inverted PSCs with a PCE range from 10 to 20% have been reported over the past few years. In comparison with the progresses of other photovoltaic technologies, the rapid enhancement in PCE of the PSCs offers an attractive option for commercial viability. The aim of this PhD project is to study the origin of the improvement in the performance of solution-processable inverted PSCs. The surface morphological and electronic properties of the HEL are crucial for the growth of the perovskite active layer and hence the performance of the inverted PSCs. Enhancement in short circuit current density (Jsc), reduced loss in open circuit voltage (Voc), improvement in charge collection efficiency (ηcc) through suppression of charge recombination were investigated systematically via controlled growth of the perovskite active layer in solution-processed inverted PSCs. Poly (3,4-ethylenedioxythiophene): poly (4-styrenesulfonate) (PEDOT:PSS) is one of the widely used solution processable conductive materials for hole transporting in different optoelectronic devices. PEDOT:PSS HEL also is a perfect electron blocking layer due to its high LUMO level. However, it has been reported that PEDOT:PSS HEL is related to the deterioration in the stability of PSCs due to its acidic and hygroscopic nature. Modification of PEDOT:PSS using solvent additives or incorporating metallic oxide nanoparticles for improving the processability and the performance of the inverted PSCs were reported. This work has been focused primary on realizing the controlled growth of perovskite active layer via HEL/perovskite interfacial modification using sodium citrate-treated PEDOT:PSS HEL and WO3-PEDOT:PSS composite HEL. Apart from investigating the properties of the modified PEDOT:PSS HELs, the purpose of the work is to improve the understanding of the effect of modified HEL on the growth of the perovskite layer, revealing the charge recombination processes under different operation conditions, analyzing change extraction probability, and thereby improving the overall performance of the PSCs. PCE of >11.30% was achieved for PSCs with a sodium citrate-modified PEDOT:PSS HEL, which is >20% higher than that of a structurally identical control device having a pristine PEDOT:PSS HEL (9.16%). The incident photon to current efficiency (IPCE) and light intensity-dependent J-V measurements reveal that the use of the sodium citrate-modified PEDOT:PSS HEL helps to boost the performance of the inverted PSCs in two ways: (1) it improves the processability of perovskite active layer on HEL, and (2) it enables to enhance the charge extraction efficiency at the HEL/perovskite interface. The suppression of charge recombination in the PSCs with a modified HEL also was examined using photocurrent-effective voltage (Jph-Veff) and transient photocurrent (TPC) measurements. Morphological and structural properties of the perovskite layers were investigated using the scanning electron microscope (SEM) and X-ray diffraction (XRD) measurements. The results reveal that high quality perovskite active layer on the modified HEL was attained forming complete perovskite phase. The surface electronic properties of the modified PEDOT:PSS and pristine PEDOT:PSS layers were studied using X-ray photoelectron spectroscopy (XPS) and ultraviolet photoelectron spectroscopy (UPS) measurements. XPS results reveal that treatment of sodium citrate partially removes the PSS unit in the PEDOT:PSS, resulting in an increase in the ratio of PEDOT to PSS from 0.197 for a treated PEDOT:PSS HEL to that of 0.108 for the pristine PEDOT:PSS HEL. UPS measurements also show that there is an observable reduction in the work function of the modified HEL, implying that sodium citrate-modified PEDOT:PSS HEL possesses an improved electron blocking capability, which is beneficial for efficient operation of the inverted PSCs.;The performance enhancement in MAPbI3-based PSCs with a tungsten oxide (WO3)-PEDOT:PSS composite HEL also was analyzed. The uniform composite WO3-PEDOT:PSS HEL was formed on indium tin oxide (ITO) surface by solution fabrication process. The morphological and surface electronic properties of WO3-PEDOT:PSS composite film were examined using AFM, XPS, UPS and Raman Spectroscopy. SEM images reveal that the perovskite films grown on the composite HEL had a full coverage without observable pin holes. XRD results show clearly that no residual of lead iodide phase was observed, suggesting a complete perovskite phase was obtained for the perovskite active layer grown on the composite HEL. The volume ratio of WO3 to PEDOT:PSS of 1:0.25 was optimized for achieving enhanced current density and Voc in the PSCs. It is demonstrated clearly that the use of the WO3-PEDOT:PSS composite HEL helps to improve the charge collection probability through suppression of the charge recombination at the MAPbI3/composite HEL interface. The charge extraction efficiency at the perovskite/PEDOT:PSS and perovskite/composite HEL interfaces were investigated by analyzing the PL quenching efficiency of the MAPbI3 active layer. It is shown that the PL efficiency quenching at the MAPbI3/composite HEL samples is one order of magnitude higher than that measured for the perovskite/pristine PEDOT:PSS sample, suggesting an enhanced hole extraction probability at the MAPbI3/composite HEL interface. The combined effects of improved perovskite crystal growth and enhanced charge extraction capabilities result in the inverted PSCs with a PCE of 12.65%, which is 22% higher than that of a structurally identical control device (10.39%). The use of the WO3-PEDOT:PSS composite HEL also benefits the efficient operation of the PSCs, demonstrated in the stability test, as compared to that of the control cell under the same aging conditions. With the progresses made in improving the performance of MAPbI3-based PSCs, the research was extended to study the performance of efficient PSCs with mixed halide of MA0.7FA0.3Pb (I0.9Br0.1)3. The effect of the annealing temperature on the growth of the mixed MA0.7FA0.3Pb (I0.9Br0.1)3 perovskite active layer was analyzed. It was found that the optimal growth of the mixed perovskite active layer occurred at an annealing temperature of 100°C. UPS results reveal that the ionization potential of 5.76 eV measured for the mixed cation perovskite is lower than that of MAPbI3-based single cation perovskite layer (5.85 eV), while the corresponding electron affinity of the mixed perovskite was 4.28 eV and that for the MAPbI3 layer was 4.18 eV, respectively. The changes in the bandgap and the energy levels of the MA0.7FA0.3Pb (I0.9Br0.1)3 and MAPbI3 active layers were examined using UV-vis absorption spectroscopy and UPS measurements. Compared to the MAPbI3-based control cell, a 23% increase in Jsc, a 15% increase in Voc and an overall 25% increase in PCE for the MA0.7FA0.3Pb (I0.9Br0.1)3 were achieved as compared to that of the MAPbI3-based PSCs. An obvious improvement in charge collection efficiency in MA0.7FA0.3Pb (I0.9Br0.1)3-based PSCs operated at different Veff was clearly manifested by the light intensity dependent J-V characteristic measurements. PL quenching efficiency also shows the charge transfer between MA0.7FA0.3Pb (I0.9Br0.1)3 and PEDOT:PSS HEL is one order of magnitude higher as compare to that in the MAPbI3-based PSCs, suggesting the formation of improved interfacial properties at the MA0.7FA0.3Pb (I0.9Br0.1)3/HEL interface. The impact of incorporating mixed MA0.7FA0.3Pb (I0.9Br0.1)3 perovskite active layer on PCE and the stability of the PSCs was further studied using a combination of TPC measurement and aging test. The stability of MA0.7FA0.3Pb (I0.9Br0.1)3- and MAPbI3-based PSCs with respect to the aging time was monitored for a period of >2 months. The MA0.7FA0.3Pb (I0.9Br0.1)3-based PSCs are more stable compared to the MAPbI3-based PSCs aged under the same conditions. The aging test supports the findings made with the TPC and light intensity dependent J-V measurements. It shows that the improved interfacial quality at the perovskite/HEL and the enhanced charge extraction capability are favorable for efficient and stable operation of MA0.7FA0.3Pb (I0.9Br0.1)3-based PSCs.

Energy is integral to the quality of life of any society. However, meeting the demand for energy sustainably is the main challenge facing humanity. In general, non-renewable energy resources are used to supply the ever increasing energy demand. However, the extraction and processing of these resources is accompanied by the production of wastes which are a health hazard and impact negatively on climate change. Considering the finite nature of non-renewable sources, the environmental concerns which are associated with their usage and ensuring energy security, renewable energy sources have been brought in the energy supply chain. Wind energy is one of the renewable energy sources which has been supplying electrical energy to the ever increasing energy demand of humanity. Wind energy technology is a mature technology which over and above the bare (conventional) wind turbine technology has seen the development of duct augmented wind turbines. Ducts are used to encase wind turbine rotors to augment the power output of wind turbines especially in low wind speed areas. Though the technology has been under study for decades now, research indicates that there is no known model to estimate the power output of a diffuser augmented wind turbine. This thesis presents the development of the conical Diffuser Augmented Wind Turbine (DAWT) power output estimation model and its validation.

PV systems in practice experience excessive thermal energy dissipation that is inseparable from the photo-electric conversion process. The temperature of PV cells under continuous illumination can approach 40°C above ambient, causing a drop in the electrical performance of about 30%. The significance of elevated temperature on PV cells inspired various thermal management techniques to improve the operating temperature of the cells and hence their conversion efficiency. Hybrid PV/Thermal (PV/T) collectors that can supply both electrical and thermal energy are attractive twofold solution, being able to cool the PV cells and thus improving the electrical power output as well as collecting the thermal energy by-product for practical utilization. The challenges present on the performance of PV systems due to elevated operating temperature is considered the research problem within this work. In this research, an integrated hybrid heat pipe-based PV/Thermoelectric (PV/TEG) collector is proposed and investigated theoretically and experimentally. The hybrid collector considers modular integration of a PV absorber rated at 170W with surface area of 1.3 m2 serving as power generator as well as thermal absorber. Five heat pipes serving as the heat transport mediums were attached to the rear of the module to extract excessive heat accumulating on the PV cells. The extracted heat is transferred via boiling-condensation cycle within the heat pipe to a bank of TEG modules consisting of five 40 mm x 40 mm modules, each attached to the condenser section of each heat pipe. In principle, the incorporation of heat pipe-TEG thermal waste recovery assembly allow further power generation adopting the Seebeck phenomena of Thermoelectric modules. A theoretical numerical analysis of the collector proposed is conducted through derivation of differential equations for the energy exchange within the system components based on energy balance concepts while applying explicit finite difference numerical approach for solutions. The models developed are integrated into MATLAB/SIMULINK environment to assess the cooling capability of the integrated collector as well as the addition power generation through thermal waste heat recovery. The practical performance of the collector proposed is determined experimentally allowing for validation of the simulation model, hence, a testing rig is constructed based on the system requirements and operating principles. Reduction in the PV cell temperature of about 8°C, which account for about 16% reduction in the PV cell temperature response compared to a conventional PV module under identical conditions is attained. In terms of the power output available from the PV cells, enhanced power performance of additional 5.8W is observed, contributing to an increase of 4% when compared with a PV module. The overall energy conversion efficiency of the integrated collector was observed to be steady at about 11% compared to that of the conventional PV module (9.5%) even at high ambient temperature and low wind speeds. Parametric analysis to assess the performance enhancements associated to the number of heat pipes attached to the PV module is conducted. Increasing the number of heat pipes attached to 15 pipes permits improved thermal management of the PV cells realised by further 7.5% reduction in the PV module temperature in addition to electrical output power improvement of 5%.

Issues from global warming with increased CO2 emissions have been to a main concern over world. As an example in the UK, the energy demand in the domestic sector has risen by 17% in 2010 compared with that of 1970. Applying renewable energy is widely agreed to be the most effective and promising way to solve the problem where solar energy and photovoltaic technology have been greatly developing from the last century. Photovoltaic combines with Phase Change Material (PV/PCM) system is a hybrid solar system which uses phase change material to reduce the PV temperature and to store energy for other applications. This thesis aims to investigate the performance of a designed building integrated photovoltaic thermal system (BIPVT) with PCM as thermal storage for building applications. The research objectives are to increase the building integrated photovoltaic (BIPV) efficiency by incorporating PCM while utilising the stored heat in PCM for controlling indoor conditions and reduce the total building energy consumption. The research starts with solar energy convection technologies including solar thermal and solar photovoltaic. Then a combined technology named photovoltaic thermal system (PVT) was introduced and discussed. Research work on a different type of PVT using water and air as thermal energy medium was further reviewed and discussed. An analytical approach investigation was presented on a PVT system and the results were used to design the experiment work on PV/PCM configuration. Experiments have been carried out on a prototype PV/PCM air system using monocrystalline photovoltaic modules. Transient simulations of the system performance have also been performed using a commercial computational fluid dynamics (CFD) package based on the finite volume method. The results from simulation were validated by comparing with experimental results. The results indicated that PCM is effective in limiting temperature rise in PV device and the heat from PCM can enhance night ventilation and decrease the building energy consumption to achieve indoor thermal comfort for certain periods of time. An entire building energy simulation with designed PV/PCM air system was also carried out under real weather condition of Nottingham, UK and Shanghai, China. The result also shows a market potential of PV/PCM system and a payback time of 11 years in the UK condition if using electrical heater.

The demand for modern energy services is increasing rapidly. Solar energy has the potential to meet a significant share of the world’s energy request. Solar energy is one of the cleanest renewable forms with little or no effect on the environment. The concentrating solar power is one of the methods to harvest sun’s energy. Concentrating solar power has the advantage of easier energy storage compared to photovoltaic systems. However, the cost of energy generated by those systems is higher than conventional energy sources. It is necessary to improve the performance of concentrating solar power to make them cost competitive. Moreover, few countries such as Saudi Arabia are moving from energy based on fossil fuel to renewable energy, therefore, improving the performance of concentrating solar systems and reducing their cost is considered to emulate photovoltaic systems. This research aims to develop an innovative design of parabolic trough solar collector that uses magnetic nanofluids as a heat transfer fluid to enhance the thermal efficiency compared to conventional parabolic trough. Based on past researches, new parabolic trough design is then proposed and investigated. Ferromagnetic nanoparticles dispersed in common heat transfer fluids (ferrofluids) exhibit better thermos-physical properties compared to the base fluids. By applying the right magnetic intensity and magnetic field direction, the thermal conductivity of the fluid increased higher than typical nanofluids. Moreover, the ferrofluids exhibit excellent optical properties. The external magnetic source is installed to alter the thermo-physical properties of the fluid. This thesis is comprised of four studies including two experimental studies, one heat transfer analysis, and one economic and environmental study. A small scale parabolic trough collector was manufactured and assembled at the laboratory based on the British Standards. A steady-state method was used to measure the performance of the parabolic trough collector in corresponding studies. The performance of the ferrofluids as a heat transfer fluid was compared to the base fluid. The two experimental studies differ in the absorber used. The two absorbers used were a conventional non-direct absorber and a direct absorber without a selective surface that allows ferrofluids to absorb the incoming solar irradiation directly. The effects of nanoparticle concentration, anti-foaming, external magnetic field intensity were investigated. The volume fraction of nanoparticles was 0.05%, 0.25%, and 0.75%. Three different magnetic field intensities were investigated, 3.14 mT, 6.28 mT, and 10.47 mT. Using ferrofluids to enhance the heat transfer performance the efficiency of the ferrofluids solar collector was compared to the based fluid (water). The results show that the parabolic trough solar collector in the experiment has similar performance of flat-plate solar collectors. The efficiency of the collector improved when ferrofluids water used compared to water. Ferrofluids with low concentration improved the performance of the solar collector. The ferrofluids showed much better performance at higher reduced temperature with lower overall heat loss coefficient. Due to the non-Newtonian behaviour of the fluid, increasing the volume fraction of particles will suppress the enhancement. The pH of ferrofluids influences the behaviour of the fluid. pH values higher than 5 showed a Newtonian behaviour of the fluid. In the presence of magnetic field, the performance of the solar collector enhanced further. By increasing the magnetic field intensity, the absorbed energy parameter increased, and at higher magnetic field intensity, the rate of enhancement decreases due to the magnetic saturation of ferrofluids. In this study, the performance of non-direct absorption receiver was better than the direct absorption receiver. However, the performance of the collector with a direct absorption receiver and using ferrofluids in the presence of the external magnetic field in some cases was higher than the performance of non-direct receiver with water as heat transfer medium. The performance of ferrofluids based parabolic trough collector was theoretically investigated. The correlation, equations, and specifications used in the model were discussed in detail. The model was used to study two different parabolic trough designs. First, the parabolic trough was validated with the experimental results of AZTRAK platform. The results of the model show a good agreement with the experimental data. Thereafter, nanoparticles were added to the heat transfer fluid, and the performance of the collector with and without the presence of external magnetic field was determined. The performance of the collector did not change a lot unless the external magnetic field was present. Moreover, the effect of the glass envelope on the performance was observed. A glass cover with vacuum in the annulus has higher performance and less thermal loss. Second, the model was used to study the performance of the test rig ferrofluids based parabolic trough. The performance of the parabolic trough was first considered as concentrating collector and then as a non-concentrating collector. With the lack of an external magnetic field, the efficiency changed slightly, wherein the presence of the external magnetic field the performances of the collector enhanced and showed higher performances. In General, the presence of the magnetic field showed promising enhancement. Economic and environmental effects of using ferrofluids based solar collector compared to a flat-plate collector for household water heating systems. Results show that the ferrofluids based parabolic trough has lower payback period and higher economic saving at its useful life end than a flat-plate solar collector. The ferrofluids based collector has higher embodied energy and pollution offsets tan flat-plate collector. Moreover, if 50% insertion of ferrofluids based parabolic trough for domestic hot water could be achieved in Tabuk over 83,750 metric Ton of CO2 could be eliminated.

This study provides an insight into the fundamentals of PV performance enhancement under different environmental conditions. The study also presents a new concept of PCM integrated PVT system which has a better performance from both electrical and thermal perspectives. The study employs both analytical and computational techniques to investigate the PV performance under the effect of different parameters such as wind speed, solar radiation level, ambient temperature and additional cooling condition. A parametric analysis of the PCM is also carried out under different solar radiation level, water inlet temperature and flow speed. Additional analysis regarding to the effects of PCM’s thermal physical properties against its thermal performance is also presented. A validation analysis is carried out prior to the parametric analysis to ascertain the reliability of the CFD models used, the prediction result of the CFD model is compared with analytical calculations as well as data from literature. The study found that the active water cooling is the best solution which can provide guaranteed performance enhancement regardless effects of ambient conditions. The novel PVT-PCM system is found to have a noticeable electrical performance enhancement over conventional PV panel as well as having the ability to store a significant amount of thermal energy. It is found that the PVT-PCM system has much lower PV cell temperature (maximum temperature reduction of 36.5°C and 38.3°C respectively) compared to conventional PV systems when used in both Nottingham and Shanghai area, hence provide up to 5.4kWh (5.7kWh in Shanghai) more energy per unit module. The stored thermal energy could be utilized to provide moderate heating to air and/or water. The air preheated by PVT-PCM system could satisfy space heating requirement during April to October in Nottingham without any additional energy consumption. On the other hand, the preheated water could reduce boiler heating energy from up to 20% and 41% respectively for Nottingham and Shanghai climate. The overall performance benefits of the proposed PVT-PCM system could be greater if used in hotter climates. Finally, a cost analysis was carried to prove the whole system is financially feasible for use in both climates of Nottingham and Shanghai with a discounted payback period of 10.67 and 12.83 years respectively.

The emergence of decentralized energy resources has brought numerous novel and advanced designs of efficient power generation systems with utilisation of renewable energy for locally provided, sustainable and cost-effective energy production. The micro trigeneration system has been a highly anticipated solution to fulfil domestic energy requirements, allowing simultaneous generation of electricity, heating and cooling from one primary source. As a matter of fact, the micro trigeneration system is still under research and development stage, with limited available demonstrations around the world. Current laboratory experimental and simulation studies mainly focus on integrations of mature technologies, whereas many promising alternatives have not been widely explored, for example organic Rankine cycle (ORC) and liquid desiccant cooling technology. The main aim of this thesis is to technically develop and evaluate a novel micro trigeneration system with a combination of scroll-based ORC and membrane-based liquid desiccant cooling (MLDC). In principle, the micro trigeneration system provides highly efficient energy conversion in a decentralized manner, as the scroll-based ORC has superior abilities in generating electricity and providing sufficient thermal output that matches the low-temperature regeneration requirement of the liquid desiccant in the MLDC. In terms of system sustainability, compact linear Fresnel reflectors (CLFR) can be one option of the primary energy source for the micro trigeneration system. A comprehensive literature review has demonstrated that no work has been conducted previously on such a system. In this thesis, the possibility of integrating CLFR to power generation systems has been firstly investigated and a detailed optical design of the CLFR-hybrid system has been conducted through geometrical modelling and experimental work. Results demonstrate that the CLFR-hybrid system with polar orientation is feasible to efficiently convert the absorbed solar energy into thermal energy, which thereby can be utilised for powering the micro trigeneration system. The concept of the novel micro trigeneration system with scroll-based ORC and MLDC has been critically examined and energy performance of the two main components, namely scroll-based ORC and MLDC have been evaluated respectively through both theoretical modelling and experimental work. Experimental tests show that the scroll-based ORC electric output of 564.5W, scroll expander isentropic and volumetric efficiencies of 78% and 83% are achievable at a 1kW capacity. In terms of MLDC, experimental results indicate the importance of system mass balance between the membrane-based dehumidifier and regenerator for continuous operation. Under the steady operating condition of MLDC, a supply air temperature of 20.4°C with dehumidification effectiveness of 0.3 and system COP of 0.70 are attainable at calcium chloride (CaCl2) solution concentration of 36%. Simulations based on a validated and comprehensive system model demonstrate the feasibility of pairing the scroll-based ORC and MLDC for the microre trigeneration system. The exhaust heat from the scroll-based ORC effectively fulfils the regeneration requirement of the MLDC. The inclusion of MLDC facilitates the micro trigeneration system overall efficiency with an increase of approximately 35.49%, compared to that of ORC-based separate power generation. Theoretical results show that the proposed micro trigeneration system has the overall system efficiencies of 38.96% in cogeneration mode and 41.23% in trigeneration mode. The thesis makes contribution to the knowledge of micro trigeneration technology, distributed power generation, energy conversion and air conditioning. Moreover, the presented parametric studies of CLFR, ORC and MLDC can be employed for designing and optimizing the relevant individual components. Regarding the future work, this thesis recommends more in-depth system modelling with a combination of CLFR, ORC and MLDC, logic optimisation of the micro trigeneration system and comprehensive field trial testing of the micro trigeneration system in building context.

Key factors in using variable renewable energy to sustain crop growth were investigated using the Isle of Lewis as a case study. Methods investigated sought to exploit plants' abilities to accommodate a variable solar input by supplementing it with variable renewable energy. The extant solar resource on Lewis was characterised. The mean ratio of photosynthetically active radiation (PAR) to solar radiation (SR) (fE) recorded in 2010 was 0.458. fE was found to be significantly different between the first and last hour of daylight and 12:00 GMT (F, (2, 33) = 7.98, p<0.001) and between winter and summer months (F, (1, 10) = 20.86, p<0.001). This supports the suggestion that fE decreases as the atmospheric path length decreases. Significantly higher mean fE was also identified for the cloudiest days (F, (1, 22) = 6.22, p<0.05). Supplementing sunlight with intermittent, artificial illumination powered using wind energy significantly increased the growth of Brassica hirta. 53.26% of the additional dry weight produced using fixed diurnal illumination was achieved with 35% of the energy using this technique. The dry weight of B. hirta grown with illumination timed with tidal streams was not significantly different from that grown using fixed diurnal patterns. This is potentially important for the use of renewable energy for horticultural illumination. The possibility of using energy to prioritise lighting in well insulated growing structures and the compatibility of electricity production and horticultural demand on Lewis were considered. These findings support the direct use of variable renewable energy to sustain crop growth and promote the concept of using plants to store renewable energy. This is of potential benefit for problems of renewable energy intermittency, the predicted need to increase world food supply and providing economic opportunities for remote areas with a poor solar resource but good supplies of variable renewable energy.