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Ion radical cycloadditions and the synthesis of novel, electron-rich polymer structuresRoh, Yeonsuk 28 August 2008 (has links)
Not available / text
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The use of bulky ligands for the stabilization of group 15 radicals and cationsWiacek, Robert Johnny 09 May 2011 (has links)
Not available / text
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The rearrangement of 2,2-diphenyl-3-p̲-tolylpropyllithiumBrantley, Troy Ellis 08 1900 (has links)
No description available.
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Optimization of L-serine crystallization using methanol as an anti-solventKennedy, Victoria Angela 05 1900 (has links)
No description available.
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Study of entry mechanism in emulsion polymerizationKashirsagar, Ravindra S. 12 1900 (has links)
No description available.
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The study of free radicals produced by photochemical meansPorter, George January 1949 (has links)
No description available.
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Investigation into the generation and structure of radicalsMaling, G. Q. January 1983 (has links)
No description available.
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The Effects of Chemical and Physical Pressure on Heavy Atom RadicalsLekin, Kristina January 2013 (has links)
Neutral radicals have been pursued as building blocks for conductive and magnetic materials for several decades. Carbon-based materials are typically plagued by dimerization and quenching of spins, but the incorporation of heteroatoms has led to many systems that remain open-shell. Radicals based on the thiazyl subunit, which are the subject of this thesis, have evolved through many generations. While the early frameworks possessed a very high onsite Coulomb repulsion energy, U, which caused the spins to be localized so that the radicals were trapped in Mott insulating ground states, the development of resonance stabilized bisdithiazolyl radicals, and their selenazyl counterparts, has led to decreased values of U, in addition to inducing major improvements in the bandwidth, W. Variation in the ligand environment and selenium content can significantly change solid state packing and hence physical properties. This so-called effect of chemical pressure has been explored and structure-property correlations have been well established.
In addition to studies involving the variation of chemical pressure, in this thesis the effect of physical pressure on these resonance stabilized heavy atom radicals is presented. In the radical building blocks of the present systems there are four possible combinations of sulfur and selenium atoms, sets of which constitute a family. The families may crystallize as an isostructural set in the solid state, but this is rare. Earlier work established that radicals in one isostructural family crystallize as undimerized π-radicals in the P4¯21m space group, the selenium variants of which all order magnetically. In this thesis, subtle molecular modification of this family is first explored. Exploration of the substituent effects with selenium fixed in the central position of the heterocycle has provided radicals that order as bulk ferromagnets in the range Tc = 9–12 K. The highest Tc ferromagnets in this group are those based on the all-selenium framework. The magnetic response of these radicals was studied under pressure, and it was discovered that with the initial application of pressure, Tc rises from 17–18 K to 21–24 K, before retreating upon further pressurization. In the 7–9 GPa range, the magnetic insulators begin to metallize, as evidenced by the loss in activation barrier to conductivity and a saturation of the resistance to a finite value at low temperature. The crystal structures in the entire pressure range have been determined and the changes in transport properties have been attributed to decreased slippage of the π-stacks with increasing pressure.
Although most of the resonance stabilized bisdithiazolyl radicals and their selenium variants are undimerized in the solid state, a few derivatives exist that dimerize through unique 4-center 6-electron S•••E–E•••S σ-bonds. When E = Se, hypervalent σ-dimerization is especially prevalent. Under ambient conditions, these materials pack in crossbraced π-stacks and exhibit semiconducting behavior. Upon mild pressurization (P ≤ 5 GPa), however, conductivity increases 5–6 orders of magnitude and the activation energy decreases remarkably. Solid state structures have now been elucidated for these dimers under pressure. For two of the variants, including one (rare) E = S σ-dimer, increasing pressure results in simple contraction of the structure. This leads to enhanced orbital overlap and gradual coalescence of the valence and conduction bands, eventually leading to metallization at P > 13 GPa. This behavior is in sharp contrast to a previously reported σ-dimer, which undergoes a transition to a π-dimer at 5 GPa, the structure of which leads to abrupt closure of the HOMO-LUMO gap and, hence, the sudden onset of a weakly metallic state.
As a departure from the behavior of any of the other known hypervalent σ-dimers, one bisdithiazolyl variant undergoes an abrupt S = 0 → S = ½ transition. This change can be initiated thermally, optically and with mild pressure. The thermal process, which is observed in the magnetic susceptibility measurements, is hysteretic, with T↑ = 380 K and T↓ = 375 K, giving rise to a small region of bistability. Irradiation results in the photomagnetization of the metastable S = ½ state that persists to an unprecedented relaxation temperature of 242 K. Under the influence of pressure, the same dimer-to-radical transition occurs (at room temperature) near 0.7 GPa. In all cases, the crystal structure of the metastable excited state has been determined by single crystal or powder X-ray diffraction. The novel behavior of the σ-dimer is in addition to the existence of a second polymorph of this material, which is paramagnetic and belongs to the P4¯21m space group under ambient conditions.
Further exploration of the effects of chemical pressure on bisdithiazolyl radicals has led to new systems with extremely long alkyl chains. This was explored for the purpose of separating the plates to generate lower dimensional frameworks. The crystal structure of one derivative belongs to the familiar tetragonal space group P4¯21m. However, upon increasing chain length of the alkyl substituent, an isomorphous set is generated, with all three compounds crystallizing in the P21/c space group. The structures consist of pairs of radical π-stacks pinned together by strong intermolecular F•••S' bridges to create spin ladder arrays. The slipped π-stack alignment of radicals produces close non-covalent S•••S' interactions which serve as the “rungs” of a spin ladder, and the long chain alkyl substituents serve as buffers that separate the ladders from each other laterally. The “legs” of the spin ladder are generated by magnetic exchange along the π-stacks. Magnetic susceptibility measurements reveal the presence of very strong antiferromagnetic coupling in all three compounds, which have been successfully modeled as strong-leg spin ladders.
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New Directions in the Coordination Chemistry of Verdazyl RadicalsMcKinnon, Stephen David James 27 September 2013 (has links)
A series of palladium and platinum complexes of verdazyl radicals were prepared
to study the intermolecular magnetic exchange coupling. Reaction of bidentate verdazyl
radicals with (RCN)2MCl2 (R = Me or Ph; M = Pd or Pt) yielded square planar
(verdazyl)MCl2 complexes. The isolated complexes crystallized in either an infinite 1D
array or as loosely associated p-stacked dimer pairs. Molecules stacked with either M–M
or M–N(verdazyl) close contacts. Molecules that stacked with a M-M close contact
exhibited weak antiferromagnetic coupling. Molecules that stacked with a M–
N(verdazyl) close contact had coupling that was an order-of-magnitude weaker, but the
type of exchange was also metal dependent. While the palladium complex exhibited
weak antiferromagnetic coupling, the exchange in the analogous platinum complex was
ferromagnetic. The difference between the two was attributed to increased spin leakage
onto the platinum centre relative to palladium. The differing electronic behaviour of the
two metals was evident in the data from EPR and UV/vis spectroscopies.
Ruthenium complexes of a verdazyl radical were prepared by the reaction of a
bidentate verdazyl with Ru(L)2(MeCN)2 (L = acac or hfac). The complexes were isolated
in two or more oxidation states and all characterized by FT-IR, UV/vis/NIR, and EPR
spectroscopies, and their structures determined by X-ray crystallography. Experimental
data was further explained and supported with time-dependant DFT calculations which
were performed by Dr. A. B. P. Lever at York University, Toronto, Ontario. When the
complex contained an electron-rich metal fragment, Ru(acac)2, noninnocent behaviour
was observed. There was a large degree of orbital mixing, so that the spin distribution
was approximately 39% metal and 56% ligand. The contrasting complex with the
electron-poor fragment, Ru(hfac)2, behaved more innocently, the majority of charge was
localized and the spin was ligand-based.
Verdazyl-bridged diruthenium complexes were prepared from a bisbidentate
verdazyl and Ru(L)2(MeCN)2 (L = acac or hfac) to study the effect of a neutral radical
bridge on mixed-valence properties. Structural data from X-ray crystallography,
spectroscopic data from EPR, FT-IR, and UV/vis/NIR spectroscopies, and comparison to
the mononuclear ruthenium-verdazyl complexes were used to assess the charge
distribution in these complexes. The complex in which the verdazyl ligand bridged two
electron-rich metal centres exhibited a NIR absorption at approximately 1716 nm.
Together, this long wavelength transition and the structural data indicate a delocalized
electronic structure, [RuIII−vd–−RuII « RuII−vd•−RuII « RuII−vd–−RuIII]. The EPR
spectrum was also consistent with the delocalization of ligand spin onto the ruthenium
centres. With the verdazyl bridging two electron-poor Ru(hfac)2 fragments, the spin is
ligand-based and best described as RuII−vd•−RuII. Like the analogous mononuclear
complexes, the dinuclear complexes were each isolated in their other accessible oxidation
states. / Graduate / 0485
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Free radical methodology and approaches to the synthesis of roseophilinBurrows, Jeremy N. January 1996 (has links)
The homolytic Brook rearrangement is discussed and homolytic fragmentations of epoxides and epoxysilane chemistry are reviewed. Thiyl radical induced isomerisation was performed on spiro alkenylepoxysilanes to generate novel alkenyl-α-trimethylsilylaldehydes rather than the products of radical Brook rearrangement. The trimethylsilylaldehydes were shown to isomerise on heating to silyldienol ethers and, via the addition of a Grignard reagent, to act as stereoselective vinyl cation equivalents. Attempts to extend the scope of the isomerisation to non-rigid systems met with failure. A review of the antibiotic Roseophilin is presented. Cycloaddition-fragmentation approaches to medium and large rings are reviewed as a prelude to our first route, the proposed Michael addition-retro-aldol fragmentation of the Diels-Alder adduct derived from isopropyl-cyclopentadiene and cyclodec- 2-yn-1-one. The novel ynone, synthesised via the intramolecular Friedel-Crafts acylation of 10-trimethylsilyl-9-decynoyl chloride, was found to isomerise readily to bicyclo[4.4.0]dec-1(6)-en-2-one therefore the model Diels-Alder reaction with cyclopentadiene was effected in one-pot from the cyclisation precursor. Details of the attempted fragmentation of tricyclo[10.2.1.0<sup>2,11</sup>]pentadeca-2(11),13-dien-3-one are then described but, due to inconclusive results, an alternative study was instigated. The use of free-radical macrocyclisations in the synthesis of large rings is reviewed with particular reference to the synthesis of natural products. Three strategies for the formation of a bicyclo[10.2.1]pentadecanone skeleton are reported, and subsequent model studies described. Cuprate additions to vinyl lactones and epoxides are discussed. The preferred strategy, involving a cycloalkyl tether between the radical donor and radical acceptor groups, was extended to a system which was derived from the addition of various cuprates to 2-oxabicyclo[3.3.0]oct-7-en-3-one The preparation of cuprates derived directly from 6-iodohexan-1-ol and 1-chloro-6-iodohexane is described. The trans- cuprate addition products were converted successfully to bicyclo[10.2.1]pentadec-12-en-3-one, and the cis- analogues, accessible through a novel regio- and stereoselective hydroboration-fragmentation reaction of 7- (6'-chlorohexyl)-2-oxabicyclo[3.3.0]oct-7-en-3-one, led to bicyclo[10.2.1]pentadec- 13-en-3-one. The successful cyclisations of model oximes, to form nitrones having the correct connectivity for the third ring of Roseophilin, are described. Cuprate additions to 6-(1'-methylethyl)-2-oxabicyclo[3.3.0]oct-7-en-3-one resulted in anti- attack; the cis- adducts were inaccessible via the above methodology but a few intermediates in the trans- series were prepared. Future routes and modifications to the methods developed are then discussed.
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