The penetration of chloride ions plays a crucial role in reinforcement corrosion and affects the durability and service life of marine structures. The problem is even more acute once cracking occurs in a concrete member. The presence of cracks is shown to have a significant impact on chloride penetration into concrete. It has been recognized, for concrete cracked in flexure, the chloride diffusion coefficient in the tension zone is higher than that in the compression zone. Even a single crack in the tensile zone could contribute to a higher diffusion coefficient compared to that of uncracked members. In this study, the influence of flexural cracks on chloride ion penetration into reinforced concrete beams has been investigated experimentally and a two-dimensional theoretical model is developed. The experimental study investigated the influence of multiple flexural cracks on the chloride diffusivity of reinforced concrete beams and on the corrosion rate of reinforcing bars. The size of the reinforced concrete beams tested is 200 x 250 x 2200 mm with 20mm concrete cover. The beams were pre-cracked using a compression testing machine and the crack widths induced were maintained between 0.1 mm to 0.2 mm. The chloride profile was determined after 1 month, 1 year and 2 years of immersion in 3.0% NaCl solution. The measured chloride profiles of the beams with multiple cracks are compared to those obtained from the uncracked (control) beam. An observation was also made on the effect of cracks on the corrosion development of steel bar after two years of immersion in salt solution. Chloride concentration varied linearly with the depth of crack (at crack planes). A twodimensional model using finite element analysis is developed to evaluate the chloride penetration into cracked concrete. This model was used to verify the chloride penetration data which is obtained from the experimental results. The prediction of chloride ingress, using the two dimensional model agrees well with the short-term and long-term chloride profiles.

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Thesis (M.S.)--University of Hawaii at Manoa, 2005. / Includes bibliographical references (leaves 120-121). / xii, 282 leaves, bound ill. (some col.) 29 cm

In order to predict the future needs of existing bridges, Bridge Management Systems use models to predict the time when damage will reach a level to cause repair, rehabilitation, or replacement of the structure. One such model is the deterioration model, which has three distinct phases. The second phase of the model, the corrosion phase, is the focus of this study. During the corrosion phase, chloride ion concentration reaches a threshold level at the depth of the reinforcing steel which initiates corrosion. The corrosion continues until sufficient pressure is exerted on the surrounding concrete to cause cracking. This study is a continuation of a study implemented in the Materials Division at Va Tech. The study includes the monitoring of the corrosion rate of steel reinforcing bars placed in simulated bridge decks. The corrosion rates were varied by placing between 0 - 9.6 Ibs/yd³ of chloride ions in the concrete to produce six different series. Also, the depth of concrete cover, bar spacing, bar size, and exposure conditions were varied. The specimens were monitored until the time that the cracking of the concrete was observed. At that time, samples of the steel reinforcing bars were removed and the actual amount of corrosion which had occurred was determined as the weight loss of the steel. The actual weight loss of the steel reinforcing bars was then compared to the predicted weight loss from the corrosion rate measurement devices. The time to cracking and the mode of cracking was compared to Bazant's equations for cracking which are the basis for the corrosion phase of the deterioration model. Although only one series cracked during the study, corrections in the use of Bazant's equations were proposed. / Master of Science

A thesis submitted to the Faculty of Engineering and the Built Environment, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the degree of Doctor of Philosophy, Johannesburg, 2017 / Many reinforced concrete (RC) structures in inland environment deteriorate early due to carbonation-induced corrosion of their reinforcement. In some cases, the deterioration is visible within a few years of construction in the form of cover concrete cracking. This is widely accepted as one of the limit state indicators in defining the end of functional service life for existing RC structures undergoing corrosion. Many of the currently available service life prediction models are incapable of providing realistic service life estimates of RC structures beyond the corrosion initiation stage. Therefore, the need to incorporate the corrosion initiation and propagation stages in a comprehensive durability prediction approach has been receiving much research attention. In this research, empirical models were developed for predicting carbonation rate and the amount of steel radius loss required to initiate a first visible crack in concretes exposed to Johannesburg environment. The experimental data for the models were obtained from investigations of carbonation-induced reinforcement corrosion, which were explored in three phases; (i) concrete early-age durability and strength characteristics (ii) carbonation rate of different concrete mixes exposed to the natural inland environment (iii) amount of steel radius loss required to initiate the first visible crack on the pre-carbonated cover concretes exposed to an unsheltered environment. The experimental variables for the earlyage durability and strength tests were; water/binder ratio (w/b) and binder type; w/b, binder type, initial moist curing duration and exposure conditions are the experimental variables for the carbonation rate test. Cover depth, reinforcement diameter, binder type and w/b variables were considered for the corrosion cracking test. The results showed that an improvement in concrete quality (binder type, w/b ratio and extending the initial moist curing duration) and increment in cover thickness improved the durability of the RC structures exposed to the natural inland environment. Based on the trends in the observed experimental results, models to predict carbonation rate and the amount of steel radius loss required to initiate cover cracking in concrete were developed. The proposed models’ predictions are more closer to the measured values and compared well with the predictions of some previous models which indicate their respective predictive applications. They provide a general basis for durability analysis of RC structures in inland environment and can serve as basis for condition assessment of existing structures in the inland environment. Engineers can appreciate the consequences of design options on the service life of RC structures, while owners of RC structures can have information about how long their RC structures may last before any repair is envisaged / XL2018

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