This study was conducted to examine the kinetics of manganese sorption on oxide-coated filter media. Initial experimentation confirmed the findings of other investigators, the Mn²⁺ sorption capacity of oxide-coated media increases as solution pH increases. Further study revealed that uptake rate kinetics could be described by first order kinetics and also increased with increasing solution pH. The addition of free chlorine (HOCl) to solution greatly enhanced Mn²⁺ uptake rate kinetics. Later studies indicated that the oxide coating had very little impact on the physical properties of the media tested. Actual data from a water treatment plant filter confirmed laboratory experimental results by showing that sorption of soluble manganese does indeed occur on oxide-coated filters. The water treatment plant data also suggested that the sorption kinetics were relatively rapid, again upholding laboratory findings. Results from the manganese kinetics and sorption experiments were combined to formulate a theoretical model which would predict manganese breakthrough in a filter, given a known set of loading parameters. Preliminary use of the model indicated that oxide-coated filters could sorb significant quantities of soluble manganese before detectible levels of manganese appear in the effluent. / Master of Science

Treatability studies were performed on oily wastewaters produced by petroleum and canning industries. Chlorine dioxide was used for the removal of phenolic compounds from these oily wastewaters. Most of phenolic compounds can be destroyed by chlorine dioxide within 15 minutes if CI02-to-phenol ratios of higher than 5.0 are provided. Factors such as pH, temperature, and COD have little effect on phenol removal. The effectiveness of chlorine dioxide treatment depends critically on the performance of the chlorine dioxide generator. High yields of chlorine dioxide generation can be achieved by maintaining the pH between 2.5 and 3.5, and by controlling the concentration of feed chemicals. For small treatment plants, chlorine dioxide treatment may be an economical process because no expensive equipment is required. / Master of Science

Manganese is typically found in all water supplies in the United States. Manganese concentrations are usually higher in water obtained from groundwater sources or resei:voir hypolinutlons. This is because manganese is more soluble in the reducing conditions normally found in these waters. Although manganese is not known to cause any health related problems, the secondary drinking water MCL for manganese is 0.05 mg/L. This standard was set to eliminate aesthetic problems associated with manganese bearing waters. In this study continuous-flow filters were operated in both pre-oxidative (oxidized Mn applied to filters) and auto-oxidative (soluble Mn applied) modes. The oxidants used were dllorine (HOCl/OCl⁻) , potassium permanganate (KMnO₄), chlorine dioxide (ClO₂), and ozone (O₃). Other experimental parameters included: filter media type - manganese coated or non-coated, filter loading rate --2 to 5 gpm/f², operating pH -- pH 6 to pH 9, and temperature --5 to 25℃. The most important experimental parameter was whether or not the filter media had a prior oxidized coating of manganese. If this was the case the filter produced an effluent concentration of manganese below the MCL under all pre-oxidative conditions and under auto-oxidative conditions when the pH was above neutral. Increased flow rate through the filter caused deeper penetration of manganese into the filter bed. This should not prove to cause an effluent breakthrough problem for filter depths typically used in water treatment plants. Temperature and pH effected the reaction rate of manganese oxidation in both the pre- and auto-oxidative modes. In most cases th.is did not effect the effluent quality from manganese coated filter media. However, when non-coated media was used and no oxidant was added, a decrease in pH or temperature usually adversely effected effluent quality. / M.S.

Although there is abundant research on the underutilization of mental health services by Asian Americans, there is limited research on the utilization patterns of family counseling services by the Chinese American population. Moreover, there is even less research that examined the perception of Chinese Americans toward family counseling and how that perception affects their utilization of family counseling services. With the intention to explore Chinese Americans' sentiments toward the field of family counseling, this qualitative study investigated what knowledge they had about the profession and how they would feel about seeking counseling services for their relationship problems. Using the guiding theoretical framework of phenomenology, in-depth interviews were conducted with eight individuals and were coded for themes. Findings indicated that Chinese Americans had a need for family counseling but cultural inhibitions about seeking counseling services and concerns such as financial burden and lack of convincing results served as utilization barriers. Implications for clinical practice, including barrier-removal ideas, and suggestions for future research are included. / Master of Science

Use of dye sensitized photooxidation is potentially a low cost means of degrading many of the hazardous compounds found in wastewaters. This study investigated the use of methylene blue as a sensitizer to degrade ortho-, meta-, and para-cresol, carbofuran and acrylonitrile. Significant reductions were found when aqueous solutions of the cresol isomers and carbofuran were illuminated and aerated in the presence of methylene blue. An average of 78% reduction of cresol was observed in seven hours. Carbofuran showed an average percent reduction of 56% in two hours. No loss was observed when the dye was absent. Acrylonitrile was found to be volatile and was stripped from solution by aeration. / M.S.

Drainage ditches, or grassed waterways, collect nutrient-laden runoff from agricultural fields and transport it to nearby waterbodies. The high nitrogen and phosphorus content in this water leads to negative effects, such as eutrophication in the receiving waters. In-ditch bioreactors are a simple, inexpensive treatment technology that could potentially remove nitrogen and phosphorus from agricultural runoff. In-ditch bioreactors are intended to reduce flow rate and stimulate denitrification and sedimentation. Using experimental ditch segments and simulated runoff, this study evaluated nutrient removal in 1) vegetated ditches, 2) vegetated ditches with woodchip bioreactors and 3) vegetated ditches with combination woodchip and biochar bioreactors. Biochar was added in an effort to increase phosphorus removal. Inlet and outlet concentrations of nitrate, ammonium and phosphate were measured for each of the three treatments in triplicate. There were no statistically significant differences between treatments on load removed for any of the three nutrients of interest. Issues in measuring outlet flow rate made drawing definitive conclusions on nutrient load reductions difficult. Further experimentation using adjusted outlet flow measuring methods and bioreactor design would help establish whether in-ditch bioreactors are suitable for use as a nutrient removal technology in agricultural grassed waterways. / Master of Science / Drainage ditches, or grassed waterways, are located at the edge of agricultural fields where runoff migrates naturally. These ditches help to direct runoff from the field to receiving waterbodies while reducing erosion. Agricultural runoff often contains high levels of nitrogen and phosphorus from fertilizer added to promote crop growth. When runoff with a high nutrient content reaches a waterbody, it reduces the quality of the water for the plants and animals that live in it and for human recreation or consumption. In-ditch bioreactors are a simple, inexpensive treatment technology that could potentially remove nitrogen and phosphorus from agricultural runoff. In-ditch bioreactors have the potential to remove nitrogen from the water by creating optimal conditions for the microorganisms that transform nitrogen in the water to nitrogen in the air. Phosphorus removal has the potential to be enhanced by in-ditch bioreactors that reduce flow and allow for phosphorus to settle out of the water. In addition, settling of phosphorus may be increased by adding a material, such as biochar, that phosphorus can attach to. Using experimental ditch segments and simulated runoff, this study looked at nutrient removal in 1) vegetated ditches, 2) vegetated ditches with woodchip bioreactors installed and 3) a vegetated ditch with combination woodchip and biochar bioreactors installed. Concentrations of two nitrogen compounds and one phosphorus compound were measured before and after passing through each ditch. There were no significant differences between any of the three ditch types on how much of each compound they could remove. These results are inconclusive due to inaccuracies in measuring flow rate at the outlet of the ditches. Further experimentation using improved flow measuring techniques and bioreactor designs would likely help establish whether in-ditch bioreactors are suitable for use as a nutrient removal technology.

Orbital debris is a current and growing threat to reliable space operations and new space vehicle traffic. As space traffic increases, so does the economic impact of orbital debris on the sustainability of systems that increasingly support national security and international commerce. Much of the debris collision risk is concentrated in specific high-density debris clusters in key regions of Low Earth Orbit (LEO). A potential long-term solution is to employ a constellation of observation satellites within these debris clusters to improve monitoring and characterization efforts, and engage in Laser Debris Removal (LDR) as means of collision mitigation. Here we adapted and improved a previous methodology for evaluating such designs. Further, we performed an analysis on the observer constellations' effectiveness over a range of circular, elliptical, and self-maneuvering designs. Our results show that increasingly complex designs result in improved performance of various criteria and that the proposed method of observation could significantly reduce the threat orbital debris poses to space operations and economic growth. / Master of Science / Orbital debris is defined as all non-operational, man-made objects currently in space. US national space regulations require every new satellite to have a de-orbit plan to prevent the creation of new debris, but fails to address the thousands of derelict objects currently hindering space operations. As space traffic increases, so does the economic impact of orbital debris on the sustainability of systems that increasingly support national security and commercial growth. While orbital debris is usually assessed by looking at the full volume of space, most massive debris objects are concentrated in high-density clusters with a higher than normal probability for collision. A potential solution to the growing orbital debris problem is to place a group of observation satellites within these debris clusters to both improve monitoring capabilities and provide a means for preventing potential collisions by engaging with debris via Laser Debris Removal (LDR). This research presents a methodology for comparing and contrasting different observer satellite constellation designs. Our results show that increasingly complex orbit designs improve various performance criteria, but ultimately orbits that more closely match those of the debris objects provide the best coverage. The proposed method of observation and engagement could significantly reduce the threat orbital debris poses to space operations and economic growth.

Yes / Fly ash is a toxic industrial waste, mainly consisting of silica and alumina particles, that has been found discharged into the environment. It is proposed that alginate, a naturally occurring biopolymer, can bind to these minerals and thus play a role in water purification. The binding forces involved in this process consist of weak interactions, such as van der Waals forces and electrostatic interactions. Although the attachment of alginate to mineral surfaces is mainly governed by its carboxylate groups, hydroxyl moieties could play a role in the interaction between the polymer and minerals. This work aims to use the SiO2 and Al2O3 particles as models for fly ash and to show the use of alginate biopolymers (fluorescently labelled with an aminonaphthaline sulfonate fluorophore (AmNS)) to coagulate them. The addition of simple electrolytes like NaCl and CaCl2 encourages the coiling of the polymer chain at high pH values which has an effect on its capability to bind to the inorganic particles. A combination of fluorescence and ICP-MS demonstrated that alginate has a considerable adsorption affinity for Al2O3, whereas it attracts SiO2 weakly. The adsorption process is pH dependent: strong adsorption was observed at low pH values. The dependence of adsorption on the mineral (Al2O3 and SiO2) concentration was also examined under different pH conditions: the adsorption amount was observed to increase by increasing the solid concentration. Adsorption isotherms obtained at low and high mineral concentrations were found to be Henry in type.

The goal of this research was to characterize the effects of temperature changes on the denitrification process in a biological nutrient removal (BNR) system. Specifically, there were three objectives. First, the effects of temperature changes on denitrification rates by a bacterial population from a BNR system were investigated. Next, the role which PHAs (poly-beta-hydroxyalkanoates) played in the denitrification process were examined. Finally, the effect of temperature changes on the production and consumption rates of PHAs was determined. Sacrificial batch experiments were performed to assess the kinetic and chemical trends present in the denitrification process. Mixed liquor from the last anaerobic zone of a pilot scale BNR system was injected into vials. These vials were pre-purged with nitrogen gas in order to prevent dimolecular oxygen (02) from being entrained in the mixed liquor. Next, the vials were placed on a shaker table for 30 minutes in order to allow all external COD to be consumed. Following this, each vial was injected with nitrates and various macronutrients. This process was repeated for three different sets of batch tests; each set was identical except for the added substrate. One set received no added substrate while the other two received either acetate or glucose. Vials were sacrificed over a period of three hours and analyzed for nitrate, phosphate, PHB (polybeta-hydroxybutyrate), PHV (poly-beta-hydroxyvalerate), glucose and acetate. / Master of Science

Anaerobic digestion is widely used for stabilization of solids in sewage sludges. Recent changes in the priorities and goals of digestion processes are focusing more attention on the efficiency of these processes. Increasing hauling cost and restrictions for land applications are two factors which are driving the increased attention to digestion efficiency. Noxious odor production from the land applied biosolids is another important issue related to digestion efficiency. Existing anaerobic digestion or aerobic digestion processes failed to provide simultaneous solution to biosolids related problems i.e. simultaneous VS reduction, better dewatering of biosolids and lesser odors from the biosolids. Studies done by Novak et al. (2004) using different activated sludges show that anaerobic-aerobic digestion and aerobic-anaerobic digestion both increase volatile solids reduction compared to a single digestion environment. They proposed that there are 4 VS fractions in sludges: (1) a fraction degradable only under aerobic conditions, (2) a fraction degradable only under anaerobic conditions, (3) a fraction degradable under both anaerobic and aerobic conditions, and (4) a non degradable fraction. It has also been found (Akunna et al., 1993) that anaerobic-aerobic sequential treatment of wastewater can help in achieving substantial nitrogen removal. These results suggest that sequential anaerobic-aerobic digestion can address multiple biosolid related problems. This study was designed to understand the effect of sequential anaerobic-aerobic digestion on the properties of resulting effluent biosolids. The study was carried out in two operation phases and during both phases one digester was maintained at thermophilic conditions and the other at mesophilic temperature conditions. In first operation phase (Phase-I) thermophilic digester was operating at 20 day SRT and mesophilic anaerobic digester was at 10 day SRT. The aerobic digesters following anaerobic digesters were operating at 6 day SRT. In second operation phase (Phase-II), both thermophilic and mesophilic anaerobic digesters were operating at 15 day SRT and both had two aerobic digesters operating in parallel at 3 day and 6 day SRTs. In addition, batch experiments were also conducted to measure the performance of aerobic-anaerobic digestion sequence. Another study was carried out to understand the nitrogen removal mechanism during aerobic digestion of anaerobic digested sludge. The feed sludge was spiked with four different concentrations of nitrate and nitrite. It was observed during the study that aerobic digestion of anaerobic sludge helps in achieving higher Volatile solid reduction (~65% vs ~ 46% for mesophilic digestion and ~52% for thermophilic digestion). This result supports the hypothesis concerning the different fractions in volatile solids. Experimental results also show that the increase in VSR upon increasing anaerobic digestion SRT (more than 15 days) is less than the increase in the VSR due to the same increment of aerobic digestion SRT. Reduction in COD and VFA were also measured to be more than 50% during aerobic digestion. Investigation of nitrogen fate during the sequential anaerobic-aerobic digestion show more than 50% total nitrogen removal. Higher nitrogen removal was in thermophilic anaerobic – aerobic digester combination than that in mesophilic anaerobic–aerobic combination. The most probable reason for the removal was simultaneous nitrification and denitrification. Higher concentration of readily available VFA from thermophilic anaerobic digested sludge provide advantage in denitrification in following aerobic digester. The resulting biosolids produced during sequential digestion process were also analyzed for dewatering properties and odor production. Proteins and polysaccharides concentrations were observed to decrease during aerobic digestion for thermophilic anaerobic - aerobic digestion combination, while in another combinations polysaccharide concentrations increases at aerobic phase with 3 day digestion. The concentration of polysaccharides decreases at higher digestion period of 6 and 9. The result of decrease in polysaccharide and protein was reflected by the reduction in the polymer dose consumption and decrease in the optimum CST for the biosolids resulting from the sequential anaerobic aerobic digestion. Experimental results from odor experiments show that odor production potential of the biosolids decreases with increase in both anaerobic phase SRT and aerobic phase SRT. Thermophilic biosolids produces comparatively low odors but for longer periods, while mesophilic biosolids produces higher magnitude of odors during storage but only for comparative shorter period. Aerobic digestion of anaerobic sludge helps in reducing more than 50% odor production, but freeze-thaw cycle experiment shows that in both anaerobic and sequential anaerobic – aerobic digested sludges have higher potential for odor production. Higher aerobic digestion SRTs (6 days and above) shows more potential of reducing odors, but more experimental work is required to be done. / Master of Science