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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

EletrodeposiÃÃo, CaracterizaÃÃo e Estudos de CorrosÃo de Revestimentos de Ni-Mo e Ni-W / Electroplating,characterization and studies of behavior corrosion of Ni-Mo and Ni-W

Gustavo LeitÃo Vaz 05 February 2007 (has links)
CoordenaÃÃo de AperfeiÃoamento de Pessoal de NÃvel Superior / O comportamento da corrosÃo e as propriedades mecÃnicas de revestimentos de Ni-Mo e Ni-W em soluÃÃes de NaCl foram investigados neste trabalho, sendo feito um estudo comparativo com as propriedades do revestimento de cromo industrial. Todas as camadas foram obtidas sob controle galvanostÃtico em temperatura ambiente e foram avaliadas em termos de composiÃÃo quÃmica, microestrutura, icrodureza, cristalinidade e resistÃncia à corrosÃo. A morfologia superficial foi caracterizada por microscopia de varredura eletrÃnica (MEV), a composiÃÃo quÃmica foi determinada por energia dispersiva de raios X (EDX), a microdureza foi medida pelo teste de dureza de Vickers e a estrutura cristalina foi determinada por difraÃÃo de raios X (DRX). Os testes eletroquÃmicos de corrosÃo foram realizados por polarizaÃÃo potenciodinÃmica linear (PP) e pela espectroscopia de impedÃncia eletroquÃmica (EIE). Os resultados mostraram que os revestimentos de Ni-Mo e Ni-W apresentam boa resistÃncia à corrosÃo quando comparados com os revestimentos de Cr, sendo os melhores Ni-13Mo e Ni-14W. As camadas foram homogÃneas, com nÃdulos distribuÃdos na superfÃcie e a presenÃa de trincas para as camadas Ni-17Mo e Ni-25Mo. Os revestimentos apresentam uma estrutura cristalina do tipo cÃbica de face centrada com a formaÃÃo de uma soluÃÃo sÃlida. A microdureza aumentou com o percentual de Mo e W na camada e com o tratamento tÃrmico a dureza das ligas aumentaram, enquanto as camadas de Cr diminuÃram sua dureza com o tratamento tÃrmico. / The corrosion behavior and mechanical properties of Ni-Mo and Ni-W electrocoatings in NaCl solutions are investigated in this work. A comparative study has been done with the properties of Cr. All electrocoatings were obtained under galvanostatic control at room temperature and were evaluated in terms of composition, microstructure, microhardness, cristalinity and corrosion resistance. The surface morphology was characterized by scanning electron microscopy (SEM), the chemical composition was determined by energy dispersive X-rays (EDX), the microhardness was measured by the Vickers hardness test and the structure was determined by X-ray diffraction (DRX). The electrochemical corrosion tests were carried out by linear potenciodinamic polarization (PP) and electrochemical impedance spectroscopy (EIS). The results showed that Ni-Mo and Ni-W present good corrosion resistance when compared with Cr coatings, and the best were Ni-13Mo and Ni-14W. The layerâs micrographs present homogeneous layers with nodules distributed in the surface and cracks can be observed to Ni-17Mo and Ni-25Mo. Ni-Mo and Ni-W coatings are crystalline exhibiting a face-centred-cubic structure in the solid solution. The microhardness increased with the Mo or W percentage and heat treatments increased the hardness of the coatings, while Cr decreased its hardness with heat treatment.

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