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A nordehydroabietyl amide-containing chiral diene for rhodium-catalysed asymmetric arylation to nitroolefinsLi, R., Wen, Z., Wu, Na 02 June 2020 (has links)
Yes / A highly enantioselective rhodium catalysed asymmetric arylation
(RCAA) of nitroolefins with arylboronic acids is presented using
a newly developed, C1-symmetric, non-covalent interacted,
phellandrene derived, nordehydroabietyl amide-containing chiral
diene under mild conditions. Stereoelectronic effects were
studied, suggesting an activation of the bound substrate through
the secondary amide as a hydrogen-bond donor.
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