We apply a variety of teleseismic methodologies to investigate the upper mantle structure in extensional environments. Using a body wave dataset collected from a regional deployment in the Woodlark Rift, Papua New Guinea, we image anisotropic velocity structure of a rapidly extending rift on the cusp of continental breakup. In the process, we develop a technique for azimuthal anisotropy tomography that is generally applicable to regions of relatively simple anisotropic structure. The Cascadia Initiative ocean bottom seismometer (OBS) deployment provides coverage of an entire oceanic plate in unprecedented detail; we measure attenuation and velocities of teleseisms to characterize the temperature and melt structure from ridge to trench. Our study of shear wave splitting reveals strong azimuthal anisotropy within the Woodlark Rift with fairly uniform fast directions parallel to extension. This observation differs markedly from other continental rifts and resembles the pattern seen at mid-ocean ridges. This phenomenon is best explained by extension-related strain causing preferential alignment of mantle olivine. We develop a simple relationship that links total extension to predicted splitting, and show that it explains the apparent dichotomy in rifts’ anisotropy. Finite frequency tomography using a dataset of teleseismic P- and S-wave differential travel times reveals the upper mantle velocity structure of the Woodlark Rift. A well developed slow rift axis extending >250 km along strike from the adjacent seafloor spreading centers demonstrates the removal of mantle lithosphere prior to complete crustal breakup. We argue that the majority of this rift is melt-poor, in agreement with geochemical results. A large temperature gradient arises from the juxtaposition of upwelled axial asthenosphere with a previously unidentified cold structure north of the rift that hosts well located intermediate depth earthquakes. Localization of upper mantle extension is apparent from the velocity structure of the rift axis and may result from the presence of water following recent subduction. In order to resolve potential tradeoffs between anisotropy and velocity gradients, we develop a novel technique for the joint inversion of ∆Vs and strength of azimuthal anisotropy using teleseismic direct S-waves. This approach exploits the natural geometry of the regional tectonics and the relative consistency of observed splits; the imposed orthogonality of anisotropic structure takes care of the non-commutative nature of multi-layer splitting. Our tomographic models reveal the breakup of continental lithosphere in the anisotropy signal, as pre-existing fabric breaks apart and is replaced by upwelling asthenosphere that simultaneously advects and accrues an extension-related fabric. Accounting for anisotropy removes apparent noise in isotropic travel times and clarifies the velocity model. Taken together, our results paint a detailed and consistent picture of a highly extended continental rift. Finally, we collect a dataset of differential travel time (δT) and attenuation (∆t*) measurements of P- and S-waves recorded on OBS stations that span the Juan de Fuca and Gorda plates. We observe large gradients in ∆t*, with values as high as 2.0 s for S-waves at the ridge axes. Such high values of differential attenuation are not compatible with a purely thermal control, nor are they consistent with focusing effects. We assert that melt, grainsize, and water enhance anelastic effects beneath the ridge. The combination of attenuation and velocity measurements enables us to place quantitative constraints on the properties of the upper mantle in the vicinity of the spreading axis.

Mantle xenoliths allow us to investigate the geochemical and dynamic evolution of the mantle beneath the western margin of Antarctica and reconstruct a timeline of geologic events that are obscured on the surface. For this study, mantle xenoliths, brought to the surface by recent volcanism, were collected along a transect from the rift shoulder and into the rift basin in the western margin of the West Antarctic Rift System (WARS), thus providing a recent snapshot of the lithospheric mantle after major episodes of rifting. The second chapter of my thesis focuses on determining the age and persistence of the mantle within the rift. The rhenium-osmium (Re-Os) isotope system has proven to be an invaluable tracer of the tectonic history of the lithospheric mantle and can constrain the age of melt extraction and subsequent stabilization of the lithospheric mantle. This allowed us to track the age of the lithospheric mantle across this rifted margin. Os isotopes, combined with major element compositions, reveal widespread Paleoproterozoic (1.7-2.4 Ga) stabilization of the lithosphere and subsequent preservation, suggesting the lithosphere has dynamically thinned in response to rifting. Major element data allowed us to place temperature (T) constraints on the mantle and characterize the thermal history in the WARS. This study also revealed the oldest lithosphere ages recorded in Antarctica (3.3 Ga) and is the first to report ages that coincide with adjacent crustal ages, thus confirming the coupled relationship between the lithospheric mantle and continental crust. An integral factor controlling the composition of magmas generated at Earth’s surface is the composition of the SCLM. Magmas generated at depth must pass through it, and subsequently may take on geochemical signatures of the lithosphere, or may leave behind geochemical imprints of the migrating magma in the SCLM. Trace elements provide a means to investigate both the depletion and re-enrichment history of the SCLM. The third chapter of my thesis investigates the metasomatic overprinting of the Paleoproterozoic SCLM. Metasomatism, which is the chemical alteration of a rock by a migrating melt and/or fluid, leaves behind diagnostic signatures of the metasomatizing agent (e.g. subduction related fluids or carbonated melts). This can occur cryptically, where a melt percolates through the rock, changing the composition of the rock, but not the lithology. Modal metasomatism produces new mineral phases that are not typically expected in the rock. In xenoliths, trace elements enable us to decode geochemical signatures, and determine the sources of metasomatism. The WARS lithosphere has experienced varying degrees of re-enrichment, broadly characterized by low high field strength element (HFSE) abundances and rare earth element (REE) enrichments that correspond with carbonatite metasomatism. In addition, the presence of secondary hydrous phases (e.g. amphibole and phlogopite) imparted distinct geochemical signatures, revealing that the SCLM beneath the WARS was modified by reactive porous flow with an evolving metasomatic fluid/melt. Widespread Cenozoic rift-related volcanism (<20 Ma) is observed throughout the western margin of the East Antarctic Craton. It has been proposed that the Cenozoic basaltic volcanism in the region of our study site originated from a SCLM source that had been metasomatized during subduction along the paleo-Pacific margin of Gondwana, and subsequent extension in the WARS during the Late Cretaceous (~90 Ma). The fourth chapter of my thesis utilizes strontium (Sr), neodymium (Nd), and hafnium (Hf) isotopes to date depletion and refertilization events in the lithosphere, as well as understand the role of the SCLM in the formation of WARS volcanism. Together with lithologic features (e.g. presence of hydrous phase additions), Sr and Nd isotopic ratios in WARS xenoliths provide a geochemical link to the Cenozoic rift-related magmatism, and supports the SCLM’s role in the formation of diffuse alkaline magmatism throughout the region. Lu-Hf isotope model ages add a constraint on the timing of melt depletion, and establish a relationship between depleted and refertilized domains. Sr isotopes constrain a genetic link between the metasomatized Archean lithosphere sampled on the rift shoulder and the highly radiogenic character of the Ferrar flood basalts, and indicate long-term storage of subduction modified mantle domains in the SCLM. The Sm-Nd isotope system is variably overprinted by metasomatism throughout the WARS. The most highly metasomatized location produces a well-correlated isochron that indicates that the SCLM acquired its trace element metasomatic signature about 130 Ma ago, during the late stages of subduction along the paleo-Pacific margin of Gondwana.

Thesis (M.S.)--Rutgers University, 2009. / "Graduate Program in Geological Sciences." Includes bibliographical references (p. 45-51).

Thesis (M.S.)--West Virginia University, 2004. / Title from document title page. Document formatted into pages; contains vi, 63 p. : ill. (some col.), maps (some col.). Includes abstract. Includes bibliographical references (p. 29-37).

Stratiform and stratabound ore deposits commonly show a direct relationship with rifts. This association is studied by developing a geodynamic model of mantle processes and crustal responses. The geodynamics of the earth can be modelled by the process of mantle advection, which involves the episodic generation and segregation of low density mantle diapirs and their rise and subsequent interaction with the crust. The theory of mantle advection explains the genetic association between rifting, magmatism, basin development and subsequent orogeny and metamorphism. Global evolution has passed through a number of major stages of non-uniformitarian development in which each cycle was characterized by fairly uniform behaviour terminated by intense geodynamic upheaval. The relationship between geological evolution and mantle advection is examined by reviewing the major characteristics of each of the cycles, which correspond to the Archean, Early Proterozoic, Mid Proterozoic, Late Proterozoic-Palaeo2oic, and Mesozoic - Cainozoic eras. Although mentle advection has controlled crustal processes throughout time, the decrease in the thermal energy of the earth has caused >the major evolutionary changes in response to thickening and a greater rigidity of the sialic crust. Rifts are penetrative taphrogenic faults in the earths crust which act as major conduits for the transfer of magmas, from the mantle and lower crustal levels, to the upper crust and the surface. Rifts are also permeable zones for the migration of metalliferous brines, generated by magmatic differentiation. These metalliferous brines would either be exhaled at surface to form stratiform volcanogenic and volcanosedimentary ore deposits , or would interact with preferential host horizons to form stratabound ore deposits . The associat ion between rifting and stratiform and stratabound ore deposits is illustrated by examining :he tectonic setting, and st ratigraphic relationships of typical ore deposit types .

MSc., Faculty of Science, University of the Witwatersrand, 2011 / Granitoid intrusions are numerous in southwestern Rajasthan and are useful because they can provide geochronological constraints on tectonic activity and geodynamic conditions operating as the time of intrusion, as well as information about deeper crustal sources. The particularly voluminous Neoproterozoic felsic magmatism in the Sirohi region of Rajasthan is of particular interest as it may have implications for supercontinental (Rodinia and Gondwana) geometry. The Mt. Abu granitoid pluton is located between two major felsic suites, the older (~870-800 Ma) Erinpura granite and the younger (~751-771 Ma) Malani Igneous Suite (MIS). The Erinpura granite is syn- to lateorogenic and formed during the Delhi orogeny, while the MIS is classified as alkaline, anorogenic and either rift- or plume-related. This tectonic setting is contentious, as recent authors have proposed formation within an Andean-type arc setting. The Mt. Abu granitoid pluton has been mapped as partly Erinpura (deformed textural variant) and partly younger MIS (undeformed massive pink granite). As the tectonic settings of the two terranes are not compatible, confusion arises as to the classification of the Mt. Abu granitoid pluton. Poorly-constrained Rb-Sr age dating place the age of formation anywhere between 735 ± 15 and 800 ± 50 Ma. The older age is taken as evidence that the Mt. Abu intrusion was either a late phase of the Erinpura granite. However, U-Pb zircon geochronology clearly indicates that the Mt. Abu felsic pluton is not related to- or contiguous with- the Erinpura granite suite. The major results from this study indicate that the all textural variants within the Mt. Abu pluton were formed coevally at ~765 Ma. Samples of massive pink granite, mafic-foliated granite and augen gneiss from the pluton were dated using U-Pb zircon ID-TIMS at 766.0 ± 4.3 Ma, 763.2 ± 2.7 Ma and 767.7 ± 2.3 Ma, respectively. The simple Mt. Abu pluton is considered as an enriched intermediate I- to A-type intrusion. They are not anorogenic A-types, as, although these felsic rocks have high overall alkali and incompatible element enrichment, no phase in the Mt. Abu pluton contains alkali rich amphibole or pyroxene, nor do REE diagrams for the most enriched samples show the gull-wing shape typical of highly evolved alkaline phases. The alkali-enriched magma may be explained by partial melting of a crustal source such as the high-K metaigneous (andesite) one suggested by Roberts & Clemens (1993), not derivation from a mantle-derived mafic magma. The fairly restricted composition of Mt. Abu granitoids suggests that partial melting and a degree of assimilation/mixing may have been the major factors affecting the evolution of this granitoid pluton; fractional crystallization was not the major control on evolution of these granitoids. Revdar Rd. granitoids that are similar in outcrop appearance and petrography to Mt. Abu granitoids also conform to Mt. Abu granitoids geochemically and are classified as part of the Mt. Abu felsic pluton. Mt. Abu samples from this study have a maximum age range of 760.5-770 Ma, placing the Mt. Abu pluton within the time limits of the Malani Igneous Suite (MIS) as well as ~750 Ma granitoids from the Seychelles. Ages of the Sindreth-Punagarh Groups are also similar. These mafic-ultramafic volcanics are thought to be remnants of an ophiolitic mélange within a back-arc basin setting at ~750-770 Ma. The three Indian terranes are spatially and temporally contiguous. The same contiguity in space and time has been demonstrated by robust paleomagnetic data for the Seychelles and MIS. These similarities imply formation within a common geological event, the proposed Andean-type arc (Ashwal et al., 2002) on the western outboard of Rodinia. The implications are that peninsular India did not become a coherent entity until after this Neoproterozoic magmatism; Rodinia was not a static supercontinent that was completely amalgamated by 750 Ma, as subduction was occurring here simultaneous with rifting elsewhere. Pageiv The Mt. Abu pluton has undergone deformation, with much of the pluton having foliated or augen gneiss textures. The timing of some of the deformation, particularly the augen gneiss and shear zone deformation, is thought to have occurred during intrusion. The Mt. Abu and Erinpura granitoids have experienced a common regional metamorphic event, as hornblende (Mt. Abu) and biotite (Erinpura) give 40Ar/39Ar ages of 508.7 ± 4.4 Ma and 515.7 ± 4.5 Ma, respectively. This event may have reactivated older deformatory trends as well. The temperature of resetting of argon in hornblende coincides with temperatures experienced during upper-greenschist to lower-amphibolite facies metamorphism. These late Pan-African ages are the first such ages reported for the Sirohi region and southern part of the Aravalli mountain range. They offer evidence for the extension of Pan-African amalgamation tectonics (evidence from southern India) into NW India. The age of formation of the Erinpura augen gneiss magma is 880.5 ± 2.1 Ma, thus placing the Erinpura granitoids within the age limits of the Delhi orogeny (~900-800 Ma; Bhushan, 1995). Most deformation observed here would have been caused by compression during intrusion. The Erinpura granitoids are S-type granitoids due to their predominantly peraluminous nature, restricted SiO2-content, normative corundum and the presence of Al-rich muscovite and sillimanite in the mode. Weathered argillaceous metasedimentary material may also have been incorporated in this magma, while the presence of inherited cores suggests relatively lower temperatures of formation for these granitoids as compared to the Mt. Abu granitoids. The age of inheritance (1971 ± 23 Ma) in the Erinpura augen gneiss is taken as the age of the source component, which coincides with Aravalli SG formation. The Sumerpur granitoids differ from the Erinpura granitoids in terms of macroscopic and microscopic texture (undeformed, rarely megaporphyritic) but conform geochemically to the Erinpura granitoid characteristics and may thus be related to the Erinpura granitoid suite.The Revdar Rd. granitoids that are similar in macroscopic appearance to Erinpura granitoids also conform geochemically, and may similarly belong to the Erinpura granite suite. A Revdar Rd. mylonite gneiss with the Erinpura granitoids’ geochemical signature was dated at ~841 Ma, which does not conform to the age of the type-locality Erinpura augen gneiss dated here, but later intrusion within the same event cannot be ruled out because of the uncertainty in the age data (~21 Ma). The presence of garnet in one Revdar Rd. (Erinpura-type) sample implies generation of these granitoids at depth and/or entrainment from the source, similar to the S-type Erinpura granitoids. The Ranakpur granitoids differ significantly from both the Erinpura and Mt. Abu intrusives due to their low SiO2-content and steep REE profiles (garnet present in the source magma); they are thought to have been generated under higher pressures from a more primitive source. The deeper pressure of generation is confirmed by the absence of a negative Eu-anomaly. The Ranakpur quartz syenite dated at 848.1 ± 7.1 Ma is younger by ~30 m.y. than the Erinpura augen gneiss. It is within the same time range as numerous other granitoids from this region as well as the Revdar Rd. granitoid dated in this study. The prevalence of 830- 840 Ma ages may indicate that a major tectonic event occurred at this time. The Ranakpur quartz syenite may have been generated near a subduction or collision zone, where thickened crust allows for magma generation at depth. The deeply developed Nb-anomaly in the spider diagram also implies a larger subduction component to the magma. The Swarupganj Rd. monzogranite is interpreted to have formed by high degrees of partial melting from a depleted crustal source and is dissimilar to other granitoids from this study. More sampling, geochemical and geochronological work needs to be done in order to characterize this intrusion. Pagev The Kishengarh nepheline syenite gneiss is situated in the North Delhi Fold Belt and is the oldest sample dated within this study. The deformation in this sample is due to arc- or continental- collision during a Grenvillian-type orogeny related to the amalgamation of the Rodinia supercontinent (and peninsular India), dated by the highly reset zircons at ~990 Ma. This is considered a DARC (deformed alkaline rock and carbonatite) and represents a suture zone (Leelanandam et al., 2006). The primary age of formation of this DARC is older than 1365 ± 99 Ma, which is the age of xenocrystic titanites from the sample. The granitoid rocks from this study area (Sirohi region) range widely in outcrop appearance, petrography and geochemistry. Granitoids from the Sirohi region dated in this study show a range of meaningful ages that represent geological events occurring at ~880 Ma, ~844 Ma, ~817 Ma, ~789 Ma, ~765 Ma and ~511 Ma. Granitoid magmatism (age of formation) in this region is predominantly Neoproterozoic, and the number of events associated with each granitoid intrusion as well as diverse tectonic settings implies a complexity in the South Delhi Fold Belt that is not matched by the conventional and simplified view of a progression from collision and orogeny during Grenvillian times (Rodinia formation), through late orogenic events, to anorogenic, within-plate (rift-related) alkaline magmatism during Rodinia dispersal. Instead, it is envisaged that convergence and subduction during the formation of Rodinia occurred at ~1 Ga (Kishengarh nepheline syenite deformation), with a transition to continental-continental collision at ~880-840 Ma (Erinpura and Ranakpur granitoids). This was then followed by far-field Mt. Abu and MIS magmatism, related to a renewed period of subduction at ~770 Ma. The last deformatory event to affect this region was that associated with the formation of Gondwana in the late Pan-African (~510 Ma).

Acompanha 2 mapas / Orientador: Peter Christian Hackspacher / Coorientador: Antonio Roberto Saad / Banca: Renato Rodriguez Cabral Ramos / Banca: Carlos Alberto Tello Saenz / Resumo: O Rift Continental do Sudeste do Brasil representa uma importante feição geológica, tanto por seu potencial econômico (areias, argilas, turfas e hidrocarbonetos), quanto para fins de estudos geológicos, pois trata-se de uma estrutura, de graben e horts, preservada e que não se encontra recoberto por águas, o que facilita suas pesquisas. Este estudo compreende a aplicação de análises termocronológicas por traços de fissão, em apatitas e zircões, com o intuito de verificar mudanças nos padrões térmicos que causaram alterações no ambiente, soerguimentos tectônicos, alçamento de isotermas e denudações. Utilizando para isto amostras coletadas em três bacias do segmento central (Taubaté, Resende e Volta Redonda). As idades obtidas remontam uma história complexa do ponto de vista evolutivo da região sudeste do Brasil, desde o Cretáceo Inferior, com o início do processo de quebramento do Continente Gondwana, passando por registros associados a intrusões alcalinas e um soerguimento regional, no início do Cretáceo Superior e finalmente entre o Paleoceno-Eoceno é resgatado o período em que ocorreu todo o processo de abertura do Rift Continental do Sudeste do Brasil (RCSB) e alterações em seu entorno. A disposição geral das idades por traços de fissão evidencia um envelhecimento em direção ao interior do continente, porém amostras muito próximas ao RCBS mostram um rejuvenescimento, possivelmente em função de um evento tectônico que culminou no surgimento das depressões que geraram as bacias deste rift. Cálculos de taxas de soerguimento e exumação mostram que os eventos foram intensificados durante o Cretáceo, aumentando consideravelmente os valores de soerguimento e exumação em períodos mais recentes. Com base nos resultados dos altos estruturais... (Resumo completo, clicar acesso eletrônico abaixo) / Abstract: The Continental Rift of southeastern Brazil is an important geological feature, both for its economic potential (sand, clay, turfs and oil), as for geological studies, because it is a structure of graben and horsts, preserved and which is not covered by water, which facilitates their resources. This study includes the application of analysis of fission tracks in apatites and zircons, for determine changes in thermal patterns that a caused change in the environment, tectonic's uplift, rises isotherms and denudations. Making use of samples collected in three basins of the central segment (Taubaté, Resende and Volta Redonda). The ages obtained a complex history dating back from the rolling region of southeastern Brazil, from the Lower Cretaceous, with the beginning of the Gondwana break, through records associated with alkaline intrusions and a strong uplift at the beginning of the Upper Cretaceous. Finally between Paleocene-Eocene is identified the time (interval) that happened all the process of opened the Brazilian Southern Continental Rift (RCSB) and changes around this structure. The general features of the age of fission shows an aging toward the interior of the continent, but samples near of RCBS shows a ages that have a rejuvenescence, possibly for apparition of basin of rift. Calculations of rates of exhumation and uplift show that the events have been intensified during the Cretaceous, increasing considerably the values in recent periods. Based on the results of high internal structural supports and between the basins, our agree ... (Complete abstract click electronic access below) / Mestre

Mt. Morning is a 2,732 m high, Cenozoic, alkaline eruptive centre situated in the south-west corner of McMurdo Sound in the Ross Sea, Antarctica. Mt. Morning is approximately 100 km south-west of Mt. Erebus, the world's southernmost active volcano. Several Cenozoic, alkali eruptive centres in this region make up the Erebus Volcanic Province. The region is currently undergoing continental extension. Regional-scale, north-striking faulting on the northern flank of Mt. Morning has offset vertical dykes, as young as 3.9 Ma, by up to 6 m dextrally. This is consistent with the trans-extensional regime in the region. The faults also have a dip-slip component, downthrown to the east. These faults define part of the western boundary of the West Antarctic Rift System. Mt. Morning straddles the boundary between the continental rift shoulder of the Transantarctic Mountains in Southern Victoria Land, and the perceived oceanic crust of the Ross Sea. Age determination of the youngest offset dyke constrains movement in the last 3.88 � 0.05 m.y., to an average rate of 0.0015 mm per year. Volcanism on Mt. Morning is divided into two phases. Phase I was erupted between 18.7 � 0.3 and 114 � 0.2 Ma and Phase II between 6.13 � 0.20 and 0.15 � 0.01 Ma. The two phases are separated by a 5.3 m.y. period of quiescence. The geochemistry of Phase I is mildly alkaline; it is composed of volcaniclastic deposits, dykes, sills, and volcanic plugs of nepheline-basanite, nepheline-trachyte, quartz-mugearite, quartz-trachyte, and rhyolite. Phase I rocks evolved along at least two trends: a quartz normative trend, and a nepheline normative trend. Chemical variation in Phase I can be explained in part by crystal fractionation, which has been modelled using major element multiple linear regression. Phase I quartz-mugearite can fractionate to quartz-trachyte after 44% crystallisation. Quartz-trachyte can fractionate to rhyolite after a further 6% erystallisation. The models indicate that clinopyroxene + plagioclase + opaque oxides � alkali feldspar � apatite are the dominant fractionated phases. Many of the Phase I quartz normative volcanic rocks have relatively high ⁸⁷Sr/⁸⁶Sr ratios (0.70501), suggesting that assimilation, most likely of crustal material, has modified them. Phase I nepheline-basanite can fractionate to nepheline-trachyte after 68% crystallisation. Modelling indicates clinopyroxene + nepheline + olivine + opaque oxides are the dominant fractionated phases. Phase II volcanic rocks are strongly alkaline and are mapped as flows, volcaniclastic deposits, dykes, and sills. They have been erupted mainly from parasitic scoria vents and rarely from fissure vents. Rock types include picrobasalt, basalt, basanite, tephrite, hawaiite, mugearite, phonotephrite, tephriphonolite, benmoreite, and phonolite. Chemical variations in the Phase II volcanic rocks can be explained by simple fractionation. Phase II picrobasalt can fractionate to phonotephrite after 78% crystallisation. Phonotephrite can fractionate to phonolite after at least 35% crystallisation, depending on which of several multiple linear regression models are selected. Fractionation is dominated by the removal of clinopyroxene + plagioclase + nepheline + olivine + opaque oxides � apatite � kaersutite. Volcanic rocks in the Erebus Volcanic Province are strongly alkaline on a silica versus total alkalis plot, similar to the Phase II volcanic rocks from Mt. Morning. Mildly alkaline rocks of Phase I are, to date, unique within the Erebus Volcanic Province. Bulk rock isotope ratios of ⁸⁶Sr/⁸⁷Sr (0.70307 - 0.70371 and 0.70498 - 0.70501), �⁴�Nd/�⁴⁴Nd (0.512650 - 0.512902), and �⁰⁶Pb/�⁰⁴Pb (18.593 -20.039) show that the majority of Mt. Morning volcanic rocks lie on a mixing line between HIMU (high-[mu]; enriched in �⁰⁶Pb and �⁰⁸Pb and relatively depleted in ⁸⁶Sr/⁸⁷Sr values) and DM (depleted mantle; high �⁴�Nd/�⁴⁴Nd, low ⁸⁶Sr/⁸⁷Sr, and low �⁰⁶Pb/�⁰⁴Pb). This is similar to the majority of volcanic rocks from the SW Pacific, including Antarctica and New Zealand. Mt. Morning volcanic rocks have tapped this broadly common mantle reservoir. There are variations in radiogenic isotope ratios between Mt. Morning and Mt. Erebus. There are also differences between the incompatible element ratios in volcanic rocks from Mt. Morning, Mt. Erebus, and White Island (a third eruptive centre in the Erebus Volcanic Province), suggesting heterogeneity in the mantle beneath the Erebus Volcanic Province. Significant chemical differences are also noted between ultramafic xenoliths collected from Mt. Morning and from Foster Crater only 15 km away. This suggests a deca-kilometre, possibly even kilometre-scale, heterogeneity in the mantle. Such small-scale chemical differences appear difficult to reconcile with large-scale plume hypotheses for the initiation of volcanism in the Erebus Volcanic Province. Instead, volcanism is much more likely to be related to numerous small plumes, or the preferred hypothesis, metasomatism and amagmatic rifting, followed by decompression melting of upwelling mantle and volcanism during transtensional lithospheric rifting. This latter model is supported by a lack of regional updoming expected with a plume(s), and fits models of localised extension proposed in this thesis. Calc-alkaline and alkaline igneous xenoliths, of felsic to mafic crustal material, have been collected from Mt. Morning. U-Pb geochronology (545.4 � 3.7 Ma and 518.6 � 4.4 Ma) on crustal xenoliths from Mt. Morning illustrate that the basement is Cambrian. Bulk rock chemistry of crustal xenoliths has similarities to compositions reported for Ross Orogen rocks, suggesting the Mt. Morning volcanic edifice is built on a basement that is composed of Cambrian Ross Orogen rock types. Quartz-bearing felsic granulite xenoliths with greater than 70 weight percent silica, collected from Mt. Morning, suggest that part of the basement is felsic. This is the only occurrence of felsic xenoliths reported to date east of the present day coastline of Victoria Land. Mt. Morning crops out less than 25 km from the known northern end of the Koettlitz Glacier Alkaline Province in the Transantarctic Mountains. The partially alkaline basement beneath Mt. Morning suggests the province may continue beneath part of Mt. Morning. The mantle beneath Mt. Morning can be characterised as anhydrous and otherwise largely unmetasomatised, which is atypical of xenoliths collected from the western Ross Sea. Only a handful of Mt. Morning xenoliths show petrographic evidence of metasomatism, these include modal phlogopite, apatite, Fe-Ni sulphide, and plagioclase (in pyroxenite xenoliths), suggesting metasomatising fluids occur discretely in this region. Where present, the metasomatic fluid(s) beneath Mt. Morning are enriched in Ba, LREEs, Th, U, P, Fe, Ni, S, and K, and depleted in Ti relative to the metasomatic fluid composition described at nearby Foster Crater. Oxygen fugacity (fO₂) of the Antarctic shallow mantle has been measured from xenoliths collected from Mt. Morning, where fO₂ was demonstrated to be strongly dependant upon spinel Fe�⁺ content that was measured using Mössbauer spectroscopy, and calculated from the olivine-orthopyroxene-spinel oxybarometer. fO₂ in the rifted Antarctic mantle varies between 0.1 and -1 log units relative to the fayalite-magnetite-quartz buffer and is coupled to melt depletion, with increasing degrees of melt extraction resulting in a more oxidised mantle. This range of upper mantle fO₂ is commonly observed in continental rift settings worldwide. The mantle beneath Mt. Morning is composed of, in increasing degree of fertility, dunite, harzburgite, and lherzolite. Xenoliths representing discrete samples of this mantle have mostly crystallised in the spinel stability field of the mantle at pressures of approximately 15 kb and temperatures between 950 - 970 �C. Symplectites of spinel and pyroxene have been interpreted as petrographic evidence that some of the spinel peridotite originated in the garnet stability field of the mantle. Rare plagioclase-bearing spinel lherzolite (plagioclase lherzolite) is also present in the mantle beneath Mt. Morning, which crystallised at temperatures of between 885 and 935 �C at 5 kb. The Mt. Morning peridotite xenoliths plot along the pre-defined geotherm for the Erebus Volcanic Province, strongly supporting it as the appropriate choice of geothermal gradient for south-west McMurdo Sound. Mineral and bulk rock compositions are nearly identical between the plagioclase lherzolite xenoliths and spinel lherzolite xenoliths. Mineral and bulk rock chemistry suggest it is unlikely that the plagioclase is due to metasomatism. Petrographic evidence and mass balance calculations suggest that the plagioclase lherzolite has crystallised via a sub-solidus (metamorphic) transition from spinel lherzolite upon decompression and upwelling of the mantle. The occurrence of plagioclase lherzolite beneath Mt. Morning could be explained by lithospheric scale uplift along faults that define the western margin of the West Antarctic Rift System. Plagioclase lherzolite has also been collected and described from White Island. White Island is also interpreted to straddle lithospheric scale faults. Rifting and buoyant uplift is sufficient to explain the presence of plagioclase lherzolite in the Erebus Volcanic Province. Plagioclase lherzolite has also been described from Mt Melbourne, an eruptive centre in Northern Victoria Land. Known occurrences of plagioclase lherzolite from the western shoulder of the Ross Sea now cover an area 430 km long and 80 km wide. This is one of the largest provinces of plagioclase peridotite worldwide so far reported.

A quantitative forward model has been developed to investigate the controls on the deposition, erosion, and preservation of passive rift margin stratigraphy. The model includes thermal subsidence, variable absolute sealevel, flexural isostasy, subaerial and submarine deposition on fluvial and marine equilibrium profiles, and the facility to vary sediment supply through time. Results from the quantitative model can be used to reproduce elements of the sequence stratigraphic depositional model. Conducting sensitivity tests demonstrates that variables such as sediment supply and fluvial profile behaviour are likely to be of equal importance to thermal subsidence and eustasy in passive margin stratigraphy. Sensitivity tests with the quantitative model also demonstrate the problems associated with attempting to use a discretised stratigraphic model to investigate unforced cyclicty resulting from complex interactions in stratigraphic systems. Although the model appears capable of producing such unforced cyclical behaviour, this cyclicity is shown to be due to a numerical instability within the model which occurs with certain initial conditions and assumptions. The applicability of the model to observed stratigraphy is tested by comparing specific model output to patterns of stratigraphy from the North American Atlantic margin. The results from this test demonstrate that although the model is in many respects simplistic when compared to the complexities of natural systems, it is nevertheless capable of reproducing some of the basic elements of the observed stratigraphic patterns.

Graduation date: 1998