In an attempt to understand the environment of the Precambrian weathering at Rispond, and compare it with weathering processes taking place at the present time, samples weathered to different degrees have been taken at various distances immediately below the Cambrian Unconformity. These samples have been subjected to chemical analysis by X-ray fluorescence spectometry and wet analysis, and to mineralogical analysis by X-ray diffraction and polarised light microscopy. Interpretation of these results indicate that the samples represent a weathering profile (although not necessarily an unchanged one as these rocks have been subjected to a maximum temperature of 250°C during burial subsequent to the deposition of the Cambrian strata). This is inferred from the minerals present in the soil, the nature of the chemical changes observed, the similarities of the data on the Kronberg weathering diagram to those of present-day weathering, and the position of the profile immediately below the unconformity. Further interpretation of the results in terms of the thermodynamic properties of the minerals present in the profile, the chemical reactions believed to have taken place, the geological evidence and a survey of the chemical composition of present-day surface waters leads to the conclusion that the rocks below the Cambrian Unconformity at Rispond represent a fossil soil profile. These rocks contain pyrophyllite, considered to have been formed by low-grade metamorphism rather than by weathering. Three possible modes of origin have been considered, and that involving the weathering of potassium feldspar to kaolinite alone in an acid environment rejected. The two mechanisms involving the weathering of the feldspar to illite in an arid alkaline environment with restricted drainage are considered to be more likely. The illite produced in these mechanisms was further weathered to produce, in the one case, kaolinite, and in the other one, potassium beidellite as a mixed layer mineral with illite. These two mechanisms can be mixed in any proportion, the exact amount of potasium beidellite present depending upon the relative thermodynamic stabilities of kaolinite and beidellite. As the latter is unknown, further accuracy cannot be achieved at present. The presence of abundant potassium feldspar in the Fucoid Beds, and the existence of trace fossil planolites in such rocks as well as the temperature to which they have been heated (about 250°C) suggested the possible existence of an ammonium feldspar in the area. Therefore, a method to measure the amount of ammonia content in these rocks has been designed. The results of twenty-two samples from the Cambro-Ordovician succession of N.W. Scotland analysed by this method show that the ammonia content is very low. If all the ammonia is present as an ammonium feldspar (buddingtonite), it represents about 0.3% of the mineral in the shales and even less in other rock types.

The inland region of the McMurdo Dry Valleys (MDV) of Antarctica represents a subzero, hyper-arid endmember for physical weathering, and is Earth’s closest terrestrial analog to the Martian surface. In order to document the style and rate of rock breakdown in this region, I conducted field-based, experimental, and numerical modeling studies of supraglacial debris (Mullins till) on Mullins Glacier. These investigations were designed to (1) quantify the rate and processes of physical breakdown of surface rocks on Mullins till, particularly of Ferrar Dolerite, (2) determine the efficacy of thermal stress weathering as an agent in rock erosion, and (3) examine the role of physical weathering in altering the sublimation of buried glacial ice. Results from morphometric field surveys characterizing changes in rock shape, strength, and small-scale surface features, coupled with an iterative cosmogenic nuclide-based age model for Mullins Glacier, show that total erosion rates for clasts of Ferrar Dolerite on Mullins till range from 1.1 to 15 cm Myr-1. In situ field measurements of rock surface temperatures and local ambient conditions recorded at 15-second intervals, combined with a numerical finite element model elucidating changes in internal rock temperatures and associated strain, show that thermal stress weathering is sufficient to induce spalling by propagating existing microcracks of ≥1.1 cm that typically occur at the base of thin, mm-scale alteration rinds. The implication is that thermal stress weathering, previously undocumented in this region, may account for >80% of the total estimated erosion of Ferrar Dolerite. Furthermore, the spalled fragments (up to 5% of Mullins till) provide a negative feedback that slows the rate of subsurface ice sublimation and internal vapor diffusion. Experimental analyses in a controlled environmental chamber set with Mullins till and driven by local meteorological conditions measured in the field yields an average effective diffusivity of 4.5 x 10-6 m2 s-1 for Mullins till and annual rates of buried ice loss of <0.068 mm (assuming Fickian diffusion); these values are consistent with theoretical estimates, demonstrate the importance of physical weathering in modifying supraglacial deposits, and support arguments for persistent cold-desert conditions in the MDV for the last several million years.

The purpose of this research was to investigate the physical weathering of rock along the Victoria Land Coast, Antarctica. It was designed to contribute to the Latitudinal Gradient Project, a joint initiative between the New Zealand, Italian and United States Antarctic Programmes. The Latitudinal Gradient Project aims to improve our understanding of the ecosystems of the Dry Valleys and ice-free areas of the Ross Sea Region and, by using latitude as a proxy measure, identify how they might be affected by future climate change. The approach taken for this research was to use information on rock (from one rock group) temperature and moisture conditions gathered from three field locations to inform laboratory simulations. The laboratory simulations would then be used to investigate the weathering of small rock blocks and aggregates. Two temperature cycles approximating those experienced during summer and spring/autumn were identified and simulations undertaken in a specially adapted freezer. Three levels of moisture were applied: no moisture, half saturation and full saturation. Results of the laboratory simulations indicated that although rocks responded in different ways to different processes, granular disintegration took place even in the absence of additional moisture and did not require crossings of the 0 OC isotherm, nor were high levels of moisture required for across zero temperature cycling to produce weathering effects. A model that related weathering to latitude was developed and changes in climate explored. It was found that the weathering effect of summer and spring/autumn cycles was different and depended on rock characteristics rather than latitude. Increasing the ratio of summer to spring/autumn temperature cycles by 10% indicated that weathering could decrease or remain the same depending on the particular rock. Changes in temperature were found to be more important than changes in moisture. A weathering index that related local climate and rock properties to weathering was also developed and this highlighted the difficulties of using laboratory results to predict field rates of weathering. There were some surprising results from the field, including the presence of much more moisture on the surface of the rock, primarily from blowing snow, than had been predicted for this dry environment. This occurred even in the presence of negative rock surface temperatures. In addition, winter rock surface temperatures can fluctuate up to 25 OC, getting as warm as -10 OC. Macro-climate and changes in air temperature in response to foehn and katabatic winds were the drivers for these fluctuations.

The purpose of this research was to investigate the physical weathering of rock along the Victoria Land Coast, Antarctica. It was designed to contribute to the Latitudinal Gradient Project, a joint initiative between the New Zealand, Italian and United States Antarctic Programmes. The Latitudinal Gradient Project aims to improve our understanding of the ecosystems of the Dry Valleys and ice-free areas of the Ross Sea Region and, by using latitude as a proxy measure, identify how they might be affected by future climate change. The approach taken for this research was to use information on rock (from one rock group) temperature and moisture conditions gathered from three field locations to inform laboratory simulations. The laboratory simulations would then be used to investigate the weathering of small rock blocks and aggregates. Two temperature cycles approximating those experienced during summer and spring/autumn were identified and simulations undertaken in a specially adapted freezer. Three levels of moisture were applied: no moisture, half saturation and full saturation. Results of the laboratory simulations indicated that although rocks responded in different ways to different processes, granular disintegration took place even in the absence of additional moisture and did not require crossings of the 0 OC isotherm, nor were high levels of moisture required for across zero temperature cycling to produce weathering effects. A model that related weathering to latitude was developed and changes in climate explored. It was found that the weathering effect of summer and spring/autumn cycles was different and depended on rock characteristics rather than latitude. Increasing the ratio of summer to spring/autumn temperature cycles by 10% indicated that weathering could decrease or remain the same depending on the particular rock. Changes in temperature were found to be more important than changes in moisture. A weathering index that related local climate and rock properties to weathering was also developed and this highlighted the difficulties of using laboratory results to predict field rates of weathering. There were some surprising results from the field, including the presence of much more moisture on the surface of the rock, primarily from blowing snow, than had been predicted for this dry environment. This occurred even in the presence of negative rock surface temperatures. In addition, winter rock surface temperatures can fluctuate up to 25 OC, getting as warm as -10 OC. Macro-climate and changes in air temperature in response to foehn and katabatic winds were the drivers for these fluctuations.

The weathering of shales is a globally important process affecting both natural and built environments. Shales form roughly 70 % of worldwide sedimentary rock deposits and therefore the weathering of these rocks has substantial effects on the geochemical cycling of elements such as carbon, iron and sulfur. Microbes have been shown to play a key role in weathering shales, primarily through the oxidation of the iron and sulfur of embedded pyrite and the resultant production of sulfuric acid. Despite significant interest in the microbial weathering of shales within industrial sectors such as biohydrometallurgy and civil engineering, comparatively few studies have investigated microbial shale weathering in natural environments. Furthermore, the role of microbes in natural shale weathering processes beyond iron oxidation has largely remained unexplored. In this thesis, the weathering capabilities of microbial communities from natural weathered shale was investigated. The North Yorkshire coastline was used as a study location, due to the abundance and diversity of natural cliffs and historic, disused industrial sites. Cliff erosion and recession on the North Yorkshire coastline is a major concern for local authorities and is the focus of current research. The aim of this work has been to evaluate microbial shale weathering processes within these environments, and hypothesise the possible contribution they may have to erosive processes. Phenotypic plate assays inoculated with weathered shale material were used to obtain rock weathering bacterial isolates that tested positive for a specific weathering phenotype, such as iron oxidation or siderophore production. Subsequent 16S rRNA sequencing enabled genera level identification, revealing 15 genera with rock weathering capabilities with several being associated with multiple weathering phenotypes including Aeromonas sp., Pseudomonas sp. and Streptomyces sp. Shale enrichment liquid cultures were incubated with shale rock chips to simulate natural biological weathering conditions, and the concentration of rock-leached elements in the fluid measured. No evidence of microbially-enhanced leaching was found consistently for any element, however the significant reduction in leachate iron concentration under biological conditions indicates that iron precipitation occurred via microbial iron oxidation. Enrichment cultures inoculated with weathered shale and containing organic matter (OM) rich rocks in water or M9 medium, both liquids lacking an organic carbon source, were grown over several months. The cultures yielded microbial isolates that could utilise rock bound OM sources and one bacterial isolate, Variovorax paradoxus, was taken forward for ecophysiological study. The shale rock that the organism was isolated from, along with other OM rich rocks (mudstones and coals), elicited complex responses from V. paradoxus including enhanced growth and motility. Finally, mineral microcosms in vitro and mesocosms in situ investigated microbial colonization and weathering of shale-comprising minerals (albite, calcite, muscovite, pyrite and quartz). Microcosms were established using iron oxidizing enrichment cultures, as based on the results of the simulated rock weathering experiments, while the in situ mesocosms were buried within weathered shale scree within a disused mine level. Levels of colonization significantly varied between minerals within the microcosms (pyrite > albite, muscovite > quartz > calcite). Although differences in mineral colonization were seen in the mesocosms, they did not match those in the microcosms and were not statistically significant. Pyrite incubated in the microcosms became significantly weathered, with extensive pit formation across the mineral surface that is consistent with microbial iron oxidation. In the mesocosms, pit formation was not identified on pyrite surfaces but dark etchings into the pyrite surface were found underneath fungi hyphal growth. The results of this thesis highlights that a range of microbial rock weathering mechanisms are abundant across weathered shale environments. Microbial iron oxidizing activity was a dominant biogeochemical process that altered rock-fluid geochemistry and weathered pyrite surfaces. However, the impact on rock or mineral weathering of other microbial mechanisms was not elucidated by this work. Given the known capabilities of these mechanisms, the conditions under which they are active may not have been met within the experimental setup used. Microbial iron oxidation in shale and shale-derived materials has previously been demonstrated to weaken rock structure through acid production and secondary mineral formation. From the results of this thesis, it is clear that microbial iron oxidation is an active process within some of the weathered shale environments studied, including cliff surfaces. Therefore, it can be hypothesised that microbial activity could play a role in structurally weakening shale rock within cliffs and accelerate their erosion. Future work should attempt to quantify the rate and extent of microbial iron oxidizing activity within shale cliff environments and investigate its contribution to erosive processes.