Atmospheric acidic deposition has negatively impacted many Appalachian watersheds in the eastern United States and soils play a key role in the biogeochemical processes that govern the fate and transport of the acidic pollutants. Thus, the collection of soil chemistry data, a previously lacking component, is essential to understand the soil processes related to the retention or release of basic and acidic ions and is imperative for the prediction of ecosystem recovery. Soil chemical properties related to acidification were characterized for 25 sites within eight acid-sensitive watersheds located in the Great Smoky Mountains National Park (GRSM). Relationships were identified by comparing soil chemistry to watershed characteristics including site location, soil characteristics, forest type, geomorphic factors and the presence of Anakeesta. The Walker Camp Prong watershed had significantly higher soil base saturation, calcium and magnesium than all other study watersheds as a result of the application of dolomitic limestone to roadways for wintertime traction control. Significant differences in soil chemistry between the spatially close watersheds of Cosby and Rock Creek demonstrated how local factors can substantially influence the watershed acidification response. The chemical properties of the six study soil types, representing 60% of the entire GRSM, had no significant differences, suggesting soil chemistry must be governed by external inputs and basin characteristics, more so than parent material. This idea was strengthen by the ability to relate many soil chemical properties to forest type and identifying other chemical properties as functions of elevation, slope and soil depth. Also, the presence of unexposed Anakeesta did not seem to have any significant effect on soil chemical properties because all significant differences could be linked to factors unrelated to surficial geology. The majority of the soils of the GRSM study watersheds seem to be experiencing the deleterious effects of long-term exposure to acidic deposition and it could be assumed that soils in many other areas of the park may be enduring the same. The results provide a comparative baseline dataset and important input parameters for biogeochemical modeling. The relationships identified among watershed factors and soil chemical properties can aid in future study designs.

In 2005 the highest global surface temperature ever was recorded. A virtual consensus exists today among scientists that global warming is underway and that human greenhouse gas (GHG) emissions are a significant cause. Possible mitigation of climate change through reduction of net GHG emissions has become a worldwide concern. Under the United Nation’s Framework convention on Climate Change, the Kyoto Protocol was formed in 1997 and required ratifying countries to co-operate in stabilizing atmospheric GHG concentrations. The protocol took effect on February 16, 2005. The mitigation cost for reducing GHG emissions for the US economy has been argued to be high particularly through the energy sector. Agriculture and Forestry (AF) can provide some low cost strategies to help with this mitigation principally through carbon sequestration but must be competitive with mitigation costs in the rest of the economy. A general equilibrium approach is used herein to evaluate the role of AF mitigation in an economy wide setting. The results show that the AF sectors have significant mitigation potential. Higher carbon prices lead to more sequestration, less emissions, reduced consumer and total welfare, improved environmental indicators and increased producer welfare. AF mitigation increases as the carbon price increase over time. In the earlier periods, while the carbon price is low, AF emissions and sink are quite small compared to the energy sector. As carbon prices increase over time, the AF sectors mitigate about 25% of the net emissions. This verifies McCarl et al's (2001) argument that the AF sectors “may be very important in a world that requires time and technological investment to develop low-cost greenhouse gas emission offsets.” AF GHG emission mitigation is sensitive to saturation of sequestration sinks. This research finds that ignoring saturation characteristics leads to a severe overestimate of mitigation potential with estimates being inflated by as much as a factor of 6.

<p>This study evaluated SO4 2- removal from circumneutral mine water (CMW) collected from Middleburg coal mine using coal FA collected from Hendrina power station. The following parameters were investigated: the effect of the amount of FA, the effect of the final pH achieved during treatment, the effect of the initial pH of the mine water and the effect of Fe and Al on SO4 2- removal from mine water. The precipitation of ettringite at alkaline pH was evaluated to further reduce the SO4 2- concentration to below the DWAF limit for potable water. Removal of SO4 2- from mine water was found to be dependent on: the final pH achieved during treatment, the amount of FA used to treat the mine water and the presence of Fe and Al in the mine water. Treatment of CMW using different CMW:FA ratios / 5:1, 4:1, 3:1, and 2:1 resulted in 55, 60, 70 and 71 % SO4 2- removal respectively. Treatment of CMW to pH 8.98, 9.88, 10.21, 10.96, 11.77 and 12.35 resulted in 6, 19, 37, 45, 63 and 71 % SO4 2- removal respectively. When the CMW was modified by adding Fe and Al by mixing with Navigation coal mine AMD and treated to pH 10, 93 % SO4 2- removal was observed. Further studies were done to evaluate the effects of Fe and Al separately. Treatment of simulated Fe containing AMD (Fe-AMD) to pH 9.54, 10.2, 11.8, and 12.1 resulted in 47, 52, 65, and 68 % SO4 2- removal respectively. When Al containing AMD was treated to pH 9.46, 10.3, 11.5 and 12 percentage SO4 2- removal of 39, 51, 55 and 67 % was observed respectively.</p>

Landfills are considered to be one of the major sources of anthropogenic methane (CH4) emissions in the environment. A landfill biocover system optimizes environmental conditions for biotic CH4 consumption that controls the fugitive and residual emissions from landfills. A compost material has more oxidation potential in comparison to any other material due to its high porosity, organic content, free flux for gases and water holding capacity. Thermal, hydraulic, bio – chemical and mechanical (THMCB) properties are important factors that can significantly affect the performance of biocover material with regards to CH4 oxidation potential as well as structural stability. Technical data on the thermal, hydraulic and mechanical (THM) properties of compost based biocover materials are quite limited. Hence, a detailed experimental program has been carried out at the University of Ottawa to study the THM properties and behaviour of compost biocover material by conducting experimental tests on small compost samples as well as by performing column experiments. The test results indicate that lower water content (dry of optimum for compaction curve) shows more free air space (FAS) in comparison to higher water content. The compost has almost the same shear strength for various initial water contents and dry unit weights; however, it settles and swells more at higher water content than lower water content per mechanical test results. The thermal and hydraulic properties of compost are a function of the compaction degree in addition to various other parameters. It is also found that the THM properties of compost are strongly coupled and the degree of saturation greatly affects the FAS.

Starting a few decades ago, the unmanned wheeled vehicle research has drawn lately more attention, especially for off-road environment. As the demand to use electric vehicles increased, the need to conceptualize the use of electrically driven vehicles in autonomous operations became a target. That is because in addition to the fact that they are more environmentally friendly, they are also easier to control. This also gives another reason to enhance further the energy economy of those unmanned electric vehicles. Off-road vehicles research was always challenging, but in the present work the nature of the off-road land is utilized to benefit from in order to enhance the energy consumption of those vehicles. An algorithm for energy consumption optimization for electrically driven unmanned wheeled vehicles is presented. The algorithm idea is based on the fact that in off-road conditions, when the vehicle passes a ditch or a hole, the kinetic energy gained while moving downhill could be utilized to reduce the energy consumption for moving uphill if the dimensions of the ditch/hole were known a distance ahead. Two manipulated variables are evaluated: the wheels DC motors supply voltage and the DC armature current. The developed algorithm is analysed and compared to the PID speed iii controller and to the open-loop control of DC motors. The developed predictive controller achieved encouraging results compared to the PID speed control and also compared to the open-loop control. Also, the use of the DC armature current as a manipulated variable showed more noticeable improvement over using the DC input voltage. Experimental work was carried out to validate the predictive control algorithm. A mobile robot with two DC motor driven wheels was deployed to overcome a ditch-like hindrance. The experimental results verified the simulation results. A parametric study for the predictive control is conducted. The effect of changing the downhill angle and the uphill angle as well as the size of the prediction horizon on the consumed electric energy by the DC motors is addressed. The simulation results showed that, when using the proposed approach, the larger the prediction horizon, the lower the energy consumption is.

Cette thèse a permis d'étudier la perméabilité du béton sous conditions thermiques et hydriques variables, ainsi que l'effet de fissuration. Nombreux essais (mesures de saturation et perméabilité, essai de compressions uniaxiales et triaxiales et hydrostatiques) ont été menés afin d'évaluer l'influence de la température et de la saturation sur le comportement hydraulique du béton sain et microfissuré. En parallèle, un dispositif de mesure de la perméabilité sur béton macro fissuré permet d'étudier le comportement d'une macro-fissure de béton confinée et soumise à écoulement de gaz sec ou l'air très humide à différentes températures. Les essais mécaniques multiaxiaux sont couplés aux mesures de perméabilité sur béton sain et micro-fissuré par gel-dégel, qui permet d'évaluer la perméabilité sous charge déviatorique et l'effet de préfissuration sous contrainte. Nous avons également effectué un essai de perméabilité relative du béton en fonction de la saturation en eau, soumis à la dessiccation ou à la resaturation, en conditionnant par les différentes humidités relatives imposées

Landfills are considered to be one of the major sources of anthropogenic methane (CH4) emissions in the environment. A landfill biocover system optimizes environmental conditions for biotic CH4 consumption that controls the fugitive and residual emissions from landfills. A compost material has more oxidation potential in comparison to any other material due to its high porosity, organic content, free flux for gases and water holding capacity. Thermal, hydraulic, bio – chemical and mechanical (THMCB) properties are important factors that can significantly affect the performance of biocover material with regards to CH4 oxidation potential as well as structural stability. Technical data on the thermal, hydraulic and mechanical (THM) properties of compost based biocover materials are quite limited. Hence, a detailed experimental program has been carried out at the University of Ottawa to study the THM properties and behaviour of compost biocover material by conducting experimental tests on small compost samples as well as by performing column experiments. The test results indicate that lower water content (dry of optimum for compaction curve) shows more free air space (FAS) in comparison to higher water content. The compost has almost the same shear strength for various initial water contents and dry unit weights; however, it settles and swells more at higher water content than lower water content per mechanical test results. The thermal and hydraulic properties of compost are a function of the compaction degree in addition to various other parameters. It is also found that the THM properties of compost are strongly coupled and the degree of saturation greatly affects the FAS.

Introduction: Oxygen delivery, or utilization, is a function of retinal blood flow and blood oxygen saturation. The retinal pigment epithelium (RPE), in particular, has been shown to have the highest levels of metabolic activity within the human body. Oxygen delivery is therefore of extreme importance to the maintenance of the health and integrity of the retina. Animal models presuppose that the oxygen tension in the retina is highest in the innermost layers at the level of the choriocapillaris, less in the photoreceptors and further decreases throughout the outer retinal structures. The choroid provides by far the largest component of the oxygen for consumption by the photoreceptors. A lack of oxygen stores in the inner retina therefore makes a constant supply crucial for its normal functioning. Blood flow dysfunction and subsequent hypoxia are both a feature in the pathogenesis of several major ocular diseases such as retinopathy of prematurity (ROP), age-related macular degeneration (ARMD), diabetic retinopathy (DR) and glaucoma. The development of methods to measure retinal blood flow and blood oxygen saturation is crucial to improve understanding of the patho-physiology of major ocular diseases. Purpose: The aims of this work were, firstly, to determine the least variable (range ± standard deviation) wavelength combination (610/548, 600/569 and 605/586) and subsequent ODR with the prototype HRC device. Secondly, using the ODR with the lowest measurement variability, we sought to quantify retinal blood SO2 in arterioles and venules and investigate the relationship between retinal blood SO2 and total retinal blood flow (TRBF) in response to stepwise changes in PETO2 in healthy participants. Retinal blood SO2 and TRBF were assessed using the IRIS HRC (Photon etc. Inc. Montreal, Canada) and the RTvue Doppler Fourier Domain OCT (Optovue Inc, Freemont, CA) instruments, respectively. Methods: Ten healthy participants between the ages of 23 and 37, with an average age of 28.3 years were evaluated in two descriptive cross-sectional studies. Two gas provocation protocols; hyperoxia (end-tidal oxygen; PETO2 of 100, 200, 300, 400mmHg) and hypoxia (PETO2 of 100, 80, 60, 50mmHg) were administered in a fixed sequential order. In each phase of gas provocation (via modulation of PETO2), retinal blood SO2 and TRBF measurements were acquired with the HRC and Doppler FD-OCT. The precise and repeated control of the partial end tidal pressures of oxygen (PETO2) and carbon dioxide (PETCO2) over the pre-determined phase duration, irrespective of the individuals’ respiratory rate, was made possible with the RespirAct (Thornhill Research Inc., Toronto, Canada); a sequential re-breathing gas delivery Results: In arterioles, the group range (±SD) of ODR values for baseline measurements (PETO2 of 100mmHg) was 0.169±0.061 for the 605/586 wavelength combination, 0.371±0.099 for the 600/569 wavelength combination and 0.340±0.104 for the 610/548 wavelength combination. In venules, the group range (±SD) of ODR values was 0.600±0.198 for the 605/586 wavelength combination, 0.569±0.169 for the 600/569 wavelength combination and 0.819±0.274 for the 610/548 wavelength combination. With the 605/586 combination at baseline 1 and 2 in arterioles, the group range (±SD) of ODR values was 0.607 ± 0.224 and 0.619 ± 0.158, respectively (p = 0.370), while in venules the group range (±SD) of ODR at baseline 1 and 2 was 0.289±0.750 and 0.284 ± 0.729, respectively (p = 0.714). For the 600/569 combination at baseline 1 and 2 in arterioles, the group range (±SD) of ODR values was 0.747±0.350 and 0.761±0.391, respectively (p = 0.424) while in venules the group range (±SD) of ODR at baseline 1 and 2 was 0.329±0.675 and 0.366±0.659, respectively (p = 0.372). For the 610/548 combination at baseline 1 and 2 in arterioles, the group range (±SD) of ODR values was 0.604±0.263 and 0.685±0.450, respectively (p = 0.056) while in venules, the group range (±SD) of ODR at baseline 1 and 2 was 0.292±0.746 and 0.285±1.009, respectively (p = 0.131). There was no statistical difference found between baseline ODR values (baseline 1 and 2) across all three wavelength combinations in both arterioles and venules. The mean retinal blood SO2 value at baseline in arterioles for 4 participants was 95.19% ± 31.04% and venules was 53.89% ± 17.24% (p = 0.115). There was a negative linear relationship between group retinal blood SO2 and TRBF values in the 10 participants studied, although the results of any of the 10 individuals did not show evidence of such a relationship using the described methodology. The Pearson’s correlation coefficient (r) between TRBF and SaO2 was r = -0.354 and p = 0.001 and between TRBF and SvO2 was r = - 0.295, p = 0.008 Conclusion: Of the three wavelength combinations investigated (605/586, 600/569 and 610/548), the 605/586 combination was shown to have the overall least variability. It would be unwise at this stage to adopt this wavelength combination for clinical usage, however, since it is presupposed that the 605/586 combination is also the most reliable combination to detect change in retinal blood SO2 i.e. lower variability of the 605/586 combination may be irrelevant if this combination proves to be insensitive to change in retinal blood SO2. The absolute mean ± SD retinal blood SO2 in the arterioles (SaO2) was 95.19% ± 31.04% and in the venules (SvO2) was 53.89% ± 17.24%. These values fell within the range expected and described in the literature. The magnitude of the difference between the SaO2 and SvO2 was also consistent with the literature. These findings were all appropriate for a low flow, high oxygen exchange vascular network typical of the inner retinal vascular system. Using group rather than individual data, TRBF was found in this study to relate inversely with SaO2 (r = -0.354 and p = 0.001) and SvO2 (r = – 0.295 and p=0.008), respectively. This relationship between TRBF and SaO2 and SvO2, was as expected based upon data derived primarily from animal models. This study is ground-breaking and unique, in that, it is the first study to concomitantly measure both retinal blood SO2 and TRBF in human participants. Individual data showed extensive variability and noise, thus limiting the strength of the association between TRBF and SaO2 and SvO2..

Esta tesis se dedica en un estudio de estabilidad no lineal de la morfodinàmica de la zona de rompientes de playas de arena. El modelo numérico MORFO55 resuelve las ecuaciones de aguas someras no lineales para la hidrodinámica y actualiza la topografía a partir del transporte de sedimento. En primer lugar, se aplica en el caso de playas complejas longitudinalmente no uniformes con objeto de probar sus distintas formulaciones. En secundo lugar, se usa para estudiar la generación de estructuras rítmicas en playas longitudinalmente uniformes. Entre estos patrones se distinguen las barras transversales y oblicuas, las barras crescenticas y los sistemas de barras/surcos (ridges/runnels). La hipótesis de que emergen a partir de inestabilidades internas del acoplamiento entre la topografía y la hidrodinámica se investiga. Los estudios previos de modelización numérica se limitaban a las etapas iniciales de la generación de las barras. En particular, mostraban que las barras transversales y oblicuas pueden formarse en playas planas mientras que las barras crecenticas aparecen en playas con barra. La formación de los sistemas de barras/surcos se explica con modelos conceptuales de la observación mediante satélite según los cuales emergerán a partir de la deformación de la barra intermareal. Esta tesis estudia el régimen no lineal de la evolución de todos estos sistemas. Particularmente se obtiene un estado 'nal de equilibrio. Los resultados generales coinciden cualitativamente con las barras observadas en la naturaleza. Se da una interpretación física de la formación, de la evolución y de la saturación del crecimiento de las barras. / This thesis performs a nonlinear stability study of the surf zone morphodynamics of sandy beaches. To this end the MORFO55 model based on a wave and depth averaged nonlinear shallow water equations solver with wave driver, sediment transport and bed updating is presented. It is first applied to complex longitudinally non-uniform beaches in order to test different model formulations. Second, it is applied to study the generation of surf zone rhythmic features on alongshore uniform beaches. Shore-attached transverse or oblique bars, crescentic bars and ridge and runnel systems are well known examples of such features. The hypothesis that they emerge by self organisation of the coupling between topography, waves and currents is here tested. In absence of shore-parallel bars, the initial formation of transverse and oblique bars had been shown by previous modelling studies of linear stability analysis but is now extended to the finite amplitude regime. In most of barred beaches, crescentic bars and ridge and runnel systems appear. Conceptual models based on field observations suggest that ridges and runnels could emerge by the deformation of the alongshore intertidal bar intercepted by crescentic bars. Up to now, only the formation of crescentic bars had numerically succeeded with linear and non linear models. This study shows that a dynamical equilibrium state of each of these rhythmic bar systems may be described with a numerical model. General results are in qualitative agreement with the bar systems observed in nature. A physical explanation for their formation, their evolution and the saturation of their growth is given.

It is widely known in oil industry that changes in fluid flow conditions such as water breakthrough or unsteady flow due to well shut-in can lead to sand destabilization, with a possible consequent sand production. In this research, different flow situations are incorporated into stress and stability analysis for the region around a wellbore producing oil from weak or unconsolidated sands, and the analyses involve strength weakening, stress redistribution, and decrease of rock stiffness. Two main mechanisms, chemical reactions of rock with formation water and variations of rock capillary strength, are identified and analyzed to study strength weakening after water breakthrough, both qualitatively and quantitatively. Using theories from particle mechanics, rock mechanics, and interfacial science, four novel capillarity models are developed and verified to analytically capture the physical behaviors of capillary strength at the grain scale. Based on model calculations, significantly better understanding of strength behavior in two-phase fluid environments is achieved. Based on a simplified model that can conservatively but efficiently quantify capillary strength with only two input parameters (i. e. particle radius and water saturation), a verified new method that physically calculates pore pressure in a multiphase environment, and a coupled poro-inelastic stress model, the redistributions of effective stresses with water saturation around a wellbore are solved. In terms of stress changes and growth of a plastic radius defining shear-failure zone, the effects of different stability factors, including capillarity through water-oil menisci, pore pressure changes due to the variations of fluid relative permeabilities, and loss of strength through chemical reactions of water-sensitive cementation materials, are quantified and compared in order to clarify when and how they contribute to sand production after water breakthrough. The nonlinearities of rock elastic properties in stressed and biphasic fluid environments is analytically addressed, based on an improved nonlinear theory that considers both a failure-based mechanism and a confining-stress-based mechanism, the strength model, and the coupled stress model. The calculations demonstrate the redistributions of stress-dependent rock stiffness around a wellbore and its evolution with increase of water saturation, clarify the relative importance of each mechanism in reducing rock stiffness, and fundamentally explain why current predictive technologies are invalid when water appears in a flowing wellbore. To quantify the effect of well shut-down on rock stability, the redistributions of fluid pressure in reservoir are analytically solved and coupled with the stress model, while the water hammer equations provide a boundary condition for the bottom-hole pressure. This approach allows direct solution of the relationships among fluid properties, rock properties and production parameters, within the context of rock stability. The proposed new approaches and models can be applied to evaluate sand production risk in multiphase and unsteady fluid flow environment. They can also serve as points of departure to develop more sophisticated models, or to develop more useful constitutive laws for numerical solutions.