Thesis (M.S.)--University of Wisconsin--Madison, 1965. / eContent provider-neutral record in process. Description based on print version record. Bibliography: l. 45-49.

Thesis (M.S.)--University of Wisconsin--Madison, 1982. / Typescript. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references (leaves 113-118).

Thesis (M.S.)--University of Wisconsin--Madison, 1983. / Typescript. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references (leaves 170-175).

Thesis (M.S.)--University of Wisconsin, 1970. / eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references (leaves 126-129).

Thesis--University of Florida. / Description based on print version record. Typescript. Vita. Includes bibliographical references (leaves 268-286).

No description available.

Turf growers have been farming the Ladner soil in the Boundary Bay area for the last decade. At each harvest, approximately a 2cm layer from the A horizon is taken out with grass. Consequently, the cultivation layer is becoming thinner year after year and the growers are already cultivating the B horizon. The possible improvement of the B horizon structure through sewage sludge application will benefit the fanners in the area. A greenhouse experiment was conducted using a Ladner subsoil. Treatments included application rates of 0, 33, and 100 t/ha of composted sewage sludge. The effect of sludge application on the soil structural stability in relation to the destructive action of water was evaluated. Soil columns were subjected to periodic 24-hour simulated ponding events. Adding sewage sludge increased the ponding tolerance of the soil. This was reflected by statistically significant differences in satiated hydraulic conductivity ('Ks') between the sludge-amended columns and the control columns. The significant decrease of 'Ks' of the control treatment as a result of ponding was responsible for widening the gap between 'Ks' of the control columns and 'Ks' of the sludge-treated columns. The incorporation of sewage sludge slowed down the decrease of 'Ks' but could not stop it. The most plausible explanation is that the addition of sewage sludge was effective in increasing the resistance of aggregates to breakdown when subjected to ponding. Fifty days after the last ponding event, the percent stable aggregates averaged 13.7, 26.9, and 48.1% for the 0, 33, and 100 t/ha treatments respectively. In no case was a significant difference in bulk density observed between the treatments. The soil structure deterioration as a result of ponding was not reflected by the bulk density measurements. Thus, it was concluded that hydraulic conductivity and aggregate stability are better idices of soil structural deterioration than bulk density. A side investigation was carried out to illustrate trends of essential nutrient and heavy metal uptake by bermuda grass. Sludge incorporation at 33 t/ha did not seem to increase nutrient and metal uptake by bermuda grass. However N, Cd, and Zn uptake appeared to increase at 100 t/ha. / Land and Food Systems, Faculty of / Graduate

No description available.

published_or_final_version / Environmental Management / Master / Master of Science in Environmental Management

Fluorinated alkyl substances, which can be persistent, toxic, and bioaccumulative, have been quantitated in many densely populated and remote regions, including in air, surface waters, groundwater, and biota; however, little is known about their transport or behavior in the environment. Wastewater effluent is one of the principal routes for introducing environmental contaminants into aquatic environments. The partitioning behavior of fluorinated alkyl substances between aqueous and particulate phases is not well characterized; thus, sorption onto sludge can be a removal mechanism of fluorinated alkyl substances from the wastewater stream. This is another route into the environment if the biosolids are land-applied. In an attempt to analyze for the fluorinated alkyl substances in wastewater, known aqueous-film-forming-foam (AFFF)-laden groundwater sampled from 3 military bases was used to develop an assay using liquid chromatography (LC), electrospray ionization (ESI) tandem mass spectrometry (MS/MS). While working on the method development, fluorotelomer sulfonates were detected at Wurtsmith AFB, MI, and Tyndall AFB, FL, where total fluoroatkyl sulfonates ranged respectively from below quantitation (���0.60 ��g/L) to 182 ��g/L and from 1100 ��g/L to 14,600 ��g/L. The LC ESI-MS/MS method was modified to quantitate fluorinated alkyl sulfonates in wastewater by incorporating a htgh volume sample loop (500 ��L), which lowered detection and quantitation limits by at least a factor of 50. This method was applied to 24 h composites of influents and effluents collected from treatment plants distributed nationwide. Fluorinated alkyl substances were observed at all 10 plants sampled, and each wastewater treatment plant was found to have a unique distribution of fluorinated alkyl substances, despite similar treatment processes. In 9 out of the 10 plants sampled, at least one class of fluorinated alkyl substance exhibited significant increases in the effluent as compared to the influent levels. The high-volume-injection LC ESI-MS/MS method was also used to monitor the mass flows of perfluoroalkyl sulfonates and carboxylates through a municipal wastewater treatment plant for 10 d. The perfluoroalkyl carboxylates were overall removed by the wastewater treatment process (25-40% removal). Perfluoroalkyl sulfonates were found to increase significantly (~200%) in the final effluent, and the fluoroalkyl sulfonamide acetic acids were found to increase by approximately 500% throughout the sludge process. From this plant, significant quantities of fluorochemicals are discharged with treated wastewater and biosolids, indicating that wastewater treatment plants are point sources of fluorinated alkyl substances and must be considered when determining origins and behavior of fluorinated alkyl substances in the environment. / Graduation date: 2005