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This thesis is a study of data on pp → ππ in the range 0.36 ≤ P(_lab) ≤ 1.55 GeV/c taken by the PS 172 experiment at CERN's LEAR facility. The aim is to elucidate the nature of mesonic states coupling both to baryon-antibaryon and meson-meson channels. The PS 172 data are compared with, and found to be consistent with, earlier data on the same channel, and, in a model independent way, the consistency of the PS 172 results with BNL data on pp pp → π(^0)π(^0) is also established. The first amplitude analysis of pp → π(^0)π(^0) to incorporate the PS 172 data is performed and it is found that from the hundreds of possible amplitudes, only two are compatible with the BNL pp → π(^0)π(^0) data and with threshold conditions. The latter may be applied in a far more rigorous way than has been previously possible since the PS 172 momentum range extends so close to threshold. Both of the solutions found exhibit resonances with spins 0-5 and the masses, widths and couplings of these states are deduced. The lowest spin resonances are found to have such large couplings to NN that they are unlikely to be simple qq states.

Molecular beam epitaxy (MBE) grown CaF₂-CdF₂ superlattices (SLs) and CaF₂ thin films doped with Eu ions were investigated by laser spectroscopic techniques. Eu ions were selectively doped into CaF₂ layers and were used as an optical probe to the SLs and thin films. Physical properties of the SLs and thin films were inferred from optical transitions of divalent and trivalent Eu centres. The 4ƒ⁶5d → 4ƒ⁷ transition of Eu²⁺ has shown strain dependent peak shifts of the zero phonon line. These shifts were thought to be a result of deformation in the crystal structure primarily due to the lattice mismatch with the Si substrate. Based on the amount of shifts, the strains associated with the MBE samples were calculated. Photoluminescence (PL) bleaching and its recovery of the same transition of Eu²⁺ in SLs were also explored. At low temperature the bleaching is best described as bi-exponential decay. Localisation of the liberated electrons from the 4ƒ⁶5d absorption band was considered for the bleaching effect. It was observed that at elevated temperatures the PL intensity of the 4ƒ⁶5d → 4ƒ⁷ transition was recovered. Combined excitation-emission spectroscopy (CEES) was employed to investigate trivalent Eu centres in SLs. The strong ⁷F₀ → ⁵D₁ excitation and the ⁵D₀ → ⁷F₁ emission of Eu³⁺ were studied. A novel centre, which is assigned as I, of Eu³⁺ in SL was observed and investigated in comparison with the cubic centre (O centre) of Eu³⁺. Relative to the O centre the I centre has shown a strong thickness dependent PL which can be demonstrated with a mono layer (1 ML = 3.15 Å) resolution. Possible transformation of the I centre to the O centre was also observed by additional thermal and UV excitations. The I and the O centres are proposed as the same centre except for having an electron in the vicinity of the I centre.

Cellulose is the main load-bearing component in plant fibre due to its covalent β-1→4- link that bonds glucose molecules into a flat ribbon and tight network of intra- and intermolecular hydrogen bonds. It is possible to manipulate the intra- and intermolecular hydrogen bonds in order to embed highly crystalline cellulose in a matrix of non-crystalline cellulose, thereby creating self-reinforced cellulose composites. Cellulose is an excellent choice of raw material for the production of sustainable and high-strength composites by selfconsolidation of cellulose since it is readily biodegradable and widely available. Nowadays, the cellulose industry makes extensive use of solvents. A multitude of solvents for cellulose is available but only a few have been explored up to the semi-industrial scale and can qualify as "sustainable" processes. An effective solvent for cellulose is a mixture of the LiCl salt and organic solvent N,N-Dimethylacetamide (DMAc). Once cellulose has been dissolved, the cellulose/LiCl/DMAc mixture can be precipitated in water. Preliminary results showed that a solution of 1 wt.% kraft cellulose in 8 wt.% LiCl/DMAc that was precipitated in water formed an hydrogel where cellulose chains were held in their amorphous state and in which no crystalline phase was detected by wide angle X-ray diffraction (WAXD). The initially amorphous cellulose started crystallizing by cross-linking of hydrogen bonds between the hydroxyl groups of the cellulose chains when the cellulose gel was dried and the water to cellulose ratio reached 7 g/g. The final form was poorly crystalline but distinct from amorphous cellulose. In order to study all-cellulose composites at a fundamental level, model all-cellulose composite films were prepared by partly dissolving microcrystalline cellulose (MCC) powder in an 8% LiCl/DMAc solution. Cellulose solutions were precipitated and the resulting gels were dried by vacuum-bagging to produce films approximately 0.2-0.3 mm thick. Wide-angle X-ray scattering (WAXS) and solid-state ¹³C NMR spectra were used to characterize molecular packing. The MCC was transformed to relatively slender crystallites of cellulose I in a matrix of paracrystalline and amorphous cellulose. Paracrystalline cellulose was distinguished from amorphous cellulose by a displaced and relatively narrow WAXS peak, by a 4 ppm displacement of the C-4 ¹³C NMR peak, and by values of T₂(H) closer to those for crystalline cellulose than disordered cellulose. Cellulose II was not formed in any of the composites studied. The ratio of cellulose to solvent was varied, with greatest transformation observed for c < 15%, where c is the weight of cellulose expressed as percentage of the total weight of cellulose, LiCl and DMAc. The dissolution time was varied between 1 and 48 h, with only slight changes occuring beyond 4 h. Transmission electron microscopy (TEM) was employed to assess the morphology of the composites. During dissolution, MCC in the form of fibrous fragments were split into thinner cellulose fibrils. The composites were tested in tension and fracture surfaces were inspected by scanning electron microscopy (SEM). It was found that the mechanical properties and final morphology of all-cellulose composites is primarily controlled by the rate of precipitation, initial cellulose concentration and dissolution time. All-cellulose composites were produced with a tensile strength of up to 106 MPa, modulus up to 7.6 GPa and strain-to-failure around 6%. The precipitation conditions were found to play a large role in the optimisation of the mechanical properties by limiting the amount of defects induced by differential shrinkage. Dynamic mechanical analysis was used to study the viscoelasticity of all-cellulose composites over temperatures ranging from -150℃ to 370℃. A β relaxation was found between -72 and -45℃ and was characterized by an activation energy of ~77.5±9.9 kJ/mol, which is consistent with the relaxation of the main chain through co-operative inter- and intramolecular motion. The damping at the β peak generally decreases with an increase in the crystallinity due to enhanced restriction of the molecular motion. For c≤15%, the crystallinity index and damping generally decreased with an increasing dissolution time, whereas the size distribution of the mobile entities increases. A simple model of crystallinity-controlled relaxation does not explain this phenomenon. It is proposed that the enhanced swelling of the cellulose in solution after higher dissolution times provides a more uniform distribution of the crystallites within the matrix resulting in enhanced molecular constriction of the matrix material. For c = 20%, however, the trend was the opposite when the dissolution time was increased. In this case, a slight increase in crystallinity and an increasing damping were observed along with a decrease in the size distribution of the mobile entities. This phenomenon corresponds to a re-crystallisation accompanied with a poor consolidation of the composite. A relaxation ɑ₂ at ~200℃ is attributed to the micro-Brownian motion of cellulose chains and is believed to be the most important glass transition for cellulose. The temperature of ɑ₂ decreased with an increase in crystallinity supposedly due to enhanced restriction of the mobile molecular phase. A high temperature relaxation which exhibited two distinct peaks, ɑ₁﹐₂ at ~300℃ and ɑ₁﹐₁ at ~320℃, were observed. ɑ₁﹐₂ is prevalent in the cellulose with a low crystallinity. A DMA scan performed at a slow heating rate enabled the determination of the activation energy for this peak as being negative. Consequently, ɑ₁﹐₂ was attributed to the thermal degradation onset of the surface exposed cellulose chains. ɑ₁﹐₁ was prevalent in higher crystallinity cellulose and accordingly corresponds to the relaxation of the crystalline chains once the amorphous portion starts degrading, probably due to slippage between crystallites. The relative ɑ₁﹐₁/ɑ₁﹐₂ peak intensity ratio was highly correlated to the amount of exposed chains on the surface of the cellulose crystallites. Novel aerogels (or aerocellulose) based on all-cellulose composites were also prepared by partially dissolving microcrystalline cellulose (MCC) in an 8 wt.% LiCl/DMAc solution. Cellulose gels were precipitated and then processed by freeze-drying to maintain the openness of the structure. The density of aerocellulose increased with the initial cellulose concentration and ranged from 116 to 350 kg.m⁻³. Aerocellulose with relatively high mechanical properties were successfully produced. The flexural strength and modulus of the aerocellulose was measured up to 8.1 MPa and 280 MPa, respectively.

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