<p>A satellite in orbit about a planet needs some means of attitude control in order to, for instance, get as much sun into its solar-panels as possible. It is easy to understand that, for example, a spy satellite has to point at a certain direction without the slightest trembling to get a photo of a certain point on the earth. This type of mission must not exceed an error in attitude of more then about 1/3600 degrees. But, since high accuracy equals high cost, it is also easy to understand why a research satellite measuring solar particles (or radiation) in space does not need high accuracy at all. A research vessel of this sort can probably do with less accuracy then 1 degree. </p><p>The first part of this report tries to explain some major aspects of satellite space-flight. It continues to focus on the market for small satellites, i.e. satellites weighing less than 500 kg. The second part of this final thesis work deals with the development of a program that simulates the movement of a satellite about a large celestial body. The program, called AOSP, consists of user-definable packages. Sensors and estimation filters are used to predict the satellites current position, velocity, attitude and angular velocity. The purpose of the program, which is written in MATLAB, is to easily determine the pointing accuracy of a satellite when using different sensors and actuators.</p>

Thesis (Ph. D.)--University of Missouri-Columbia, 2000. / Typescript. Vita. Includes bibliographical references (leaves 209-222). Also available on the Internet.

Thesis (doctoral)--Freie Universität, Berlin, 2004. / EAN: 9786610701315 (electronic bk.). Title from e-book title screen (viewed Oct. 15, 2007). Description based on print version record. Includes bibliographical references (p. [143]-155).

The thermal degradation of polyvinyl chloride (PVC) is a significant processing challenge which can lead to deleterious mechanical and optical properties in a wide range of products. Synergetic studies on PVC model compounds and blends of bulk PVC provide unique insights into the thermal degradation and stabilization pathways in the presence of common additives. Model PVC compounds were selected to replicate specific defects (e.g., allylic, vicinal and tertiary) and tacticity (i.e., utilizing stereochemistry to investigate tacticity) commonly found in PVC. Model studies were conducted neat (solvent-free) with metal carboxylates. Experimental results highlight that the allylic and tertiary defects are more reactive than pristine PVC and isotactic sites are more reactive than their syndiotactic counterparts. Zinc stearate was found to act not in the role of substituent, but as a Lewis acid by facilitating dehydrochlorination of labile chlorides. This prevents the accumulation of hydrogen chloride and autocatalytic chain unzipping. In contrast, calcium stearate delayed the formation of zinc chloride, a much stronger Lewis acid than zinc stearate, through an ion exchange process to form calcium chloride. Thermal weight loss studies using blends of bulk PVC proved critical in transferring mechanistic insights into the context of a polymeric matrix. Post-combustion carbon capture has traditionally involved the use of aqueous alkanol amine solutions. The regeneration of such systems, however, can be costly and energy intensive. We have developed an alternative system utilizing silylated alkylamines to reversibly capture CO2 under near ambient conditions. The silyl amines developed capture CO2 through chemical reaction to form reversible ionic liquids (RevIL). RevILs utilize no added water and are tunable by molecular design allowing us to influence industrially relevant carbon capture properties such as viscosity, temperature of reversal, and enthalpy of regeneration, while maximizing overall CO2 capture capacity. We demonstrate a strong structure-property relationship among the silyl amines where minor structural modifications lead to significant changes in the bulk properties of the RevIL. Amine containing substrates are important building blocks for a variety of biological and pharmaceutical compounds. However, application of the otherwise versatile Suzuki reaction to these substrates has proved challenging due to either ligation of the amine to the palladium or to electronic effects slowing the oxidative addition step. Conventional methods to overcome these challenges involve protection-deprotection strategies or the use of designer ligands to facilitate reaction. We have shown that application of CO2 pressure and adjusting the water content of the reaction system facilitate the Suzuki coupling of 4-amino-2-halopyridines in high yield with the simple Pd(TPP)2Cl2 catalyst. The protocol was expanded to 2-halopyridines. The results of these investigations will be discussed.

This historic preservation report focuses on the Gaines-Oliphint house in Sabine County, Texas. The first part of the report establishes the geographic and historic context of the home. Next, the report concentrates on establishing significance of the Gaines- Oliphint house based on the National Register’s criteria through both an association with a significant person in history and architectural characteristics representative of a particular time and style. Finally, the report outlines a preliminary conditions assessment of the Gaines-Oliphint house followed by recommendations for stabilization, preservation and restoration of the home. / text

Video data has increased dramatically in recent years due to the prevalence of handheld cameras. Such videos, however, are usually shakier compared to videos shot by tripod-mounted cameras or cameras with mechanical stabilizers. In addition, most handheld cameras use CMOS sensors. In a CMOS sensor camera, different rows in a frame are read/reset sequentially from top to bottom. When there is fast relative motion between the scene and the video camera, a frame can be distorted because each row was captured under a different 3D-to-2D projection. This kind of distortion is known as rolling shutter effect. Digital video stabilization and rolling shutter rectification seek to remove the unwanted frame-to-frame jitter and rolling shutter effect, in order to generate visually stable and pleasant videos. In general, we need to (1) estimate the camera motion, (2) regenerate camera motion, and (3) synthesize new frames. This dissertation aims at improving the first two steps of video stabilization and rolling shutter rectification. It has been shown that the inertial sensors in handheld devices can provide more accurate and robust motion estimation compared to vision-based methods. This dissertation proposes an online camera-gyroscope calibration method for sensor fusion while a user is capturing video. The proposed method uses an implicit extended Kalman filter and is based on multiple-view geometry in a rolling shutter camera model. It is able to estimate the needed calibration parameters online with all kinds of camera motion. Given the camera motion estimated from inertial sensors after the pro- posed calibration method, this dissertation first proposes an offline motion smoothing algorithm based on a 3D rotational camera motion model. The offline motion smoothing is formulated as a geodesic-convex regression problem on the manifold of rotation matrix sequences. The formulated problem is solved by an efficient two-metric projection algorithm on the manifold. The geodesic-distance-based smoothness metric better exploits the manifold structure of sequences of rotation matrices. Then this dissertation proposes two online motion smoothing algorithms that are also based on a 3D rotational camera motion model. The first algorithm extends IIR filtering from Euclidean space to the nonlinear manifold of 3D rotation matrices. The second algorithm uses unscented Kalman filtering on a constant angular velocity model. Both offline and online motion smoothing algorithms are constrained to guarantee that no black borders intrude into the stabilized frames. / text

Not available / text

published_or_final_version / abstract / toc / Civil Engineering / Master / Master of Philosophy

published_or_final_version / abstract / toc / Applied Geosciences / Master / Master of Science

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