<p> The Paleocene-Eocene Thermal Maximum (PETM) was followed by a lesser hyperthermal event, called ETM2, at &sim;53.7 Ma (Zachos et al., 2010). The carbon isotope excursion and global temperature increases for ETM2 were approximately half those of the PETM (Stap et al., 2010). The paleohydrologic response to this event in the continental interior of western North America is less well understood than the response to PETM warming. Although ETM2 is better known from marine than continental strata, the hyperthermal has been identified from outcrops of the alluvial Willwood Formation from the Deer Creek and Gilmore Hill sections of the McCullough Peaks area in the Bighorn Basin, Wyoming (Abels et al., 2012). The presence of ETM2 in Willwood Formation strata provides a rare opportunity to examine local continental climactic and sedimentary response to this hyperthermal. </p><p> Core drilled at Gilmore Hill was described and analyzed geochemically. The core consists of paleosols formed on mudrocks that are interbedded with siltstones and sandstones. Carbon isotope analysis of carbonate nodules from paleosols in the core shows that the top of the core, below a prominent yellow sandstone, most likely records the very beginning of the carbon isotope excursion that marks ETM2 (Maibauer and Bowen, unpublished data).The rest of the CIE was likely either not recorded due to sandstone deposition or removed by erosion prior to the deposition of the sandstone. </p><p> Analysis of bulk oxides in the paleosols using the methods of Sheldon et al. (2002) and Nordt and Driese (2010b) provides quantitative estimates of precipitation through the core section. The estimates reveal drying over the &sim;15m leading up to ETM2. Red and brown paleosols, attributed to generally dry conditions, dominate the entire section below the onset of ETM2 and confirm drier conditions. In contrast, thick purple paleosols are associated with ETM2 at the Deer Creek site and suggest wetter conditions during most of the ETM2 interval. The prominent yellow sandstone at the top of the Gilmore Hill core was probably deposited during those wetter climate conditions. </p><p> The core displays distinct changes in stratigraphic architecture: the bottom &sim;100m is mudrock-dominated and the top &sim;100m is sandstone dominated. Several PETM studies have suggested that sediment coarsening in continental basins in the US and Spain developed in response to precipitation changes associated with global warming. Analysis of the Gilmore Hill core's stratigraphic architecture in conjunction with carbon isotope and precipitation data shows that the prominent sandstone in the position of ETM2 was not caused by climate change. The sandstone is the uppermost part of the sandstone-rich interval whose base underlies ETM2 by more than 50m. This study shows that the shift from mudrock- to sandstone-dominated stratigraphy at Gilmore Hill, and possibly throughout the McCullough Peaks area, was not caused by climactic change associated with ETM2. While studies of PETM sections have suggested that the hyperthermal caused sediment coarsening in several different basins including the Bighorn Basin (e.g., Schmitz and Pujalte, 2007; Smith et al., 2008b; Foreman et al., 2012), this study suggests that the lesser magnitude ETM2 did not cross the necessary threshold to provoke a sedimentological response in the Bighorn Basin.</p>

<p> Petrography and phase equilibria involving the minerals trona (Na₂CO₃&bull;NaHCO₃&bull;2H₂O), nahcolite (NaHCO₃), and shortite (Na₂CO₃&bull;2CaCO₃) from the Eocene Green River Formation provide information on the paleoenvironments that controlled their formation during deposition and diagenesis. Shortite and trona are exclusive to the Wilkins Peak Member (WPM) of the Bridger Basin (BB), WY, whereas nahcolite is the primary Na-carbonate mineral in the contemporaneous Parachute Creek Member of the Piceance Creek Basin (PCB), CO. Trona from the BB and nahcolite from the PCB are stratigraphically associated with oil shale, suggesting deposition in perennial, density stratified saline lakes. Preserved primary textures of trona and nahcolite show that they formed at the air-water interface as microcrystalline chemical muds, which supports the hypothesis that precipitation occurred in contact with the early Eocene atmosphere. New experiments (temperature vs. <i>p</i>CO₂) in the NaHCO₃ -Na₂CO₃-CO₂-H₂O system show that nahcolite forms at a minimal <i>p</i>CO₂ concentration of ~ 680 ppm at 19.5 &deg;C, 1 atm, which is lower than the <i>p</i>CO₂ determined by Eugster (1966) (1330 ppm and 1125 ppm with NaCl added). These new results anchor the minimum <i> p</i>CO₂ of the early Eocene atmosphere at ~ 680 ppm. </p><p> Shortite formed diagenetically during burial in the BB as displacive crystals, fracture fills, and pseudomorphous replacements of a precursor Na-Ca-carbonate in carbonate mudstone and oil shale. Experimental results on the thermal stability of shortite in the Na₂CO₃-CaCO₃-H₂O system show that it forms at temperatures > 55 &deg;C, 1 atm, and 1.1m Na₂CO3 via the reaction: Na₂CO₃&bull;CaCO₃&bull;2H₂O_(pirssonite) + CaCO_3(calcite) = Na₂CO₃&bull;2CaCO_3(shortite) + 2H₂O. The large area over which shortite occurs in the WPM indicates saline pore fluids existed in the buried lacustrine sediments and that, at times, giant Na-CO₃-rich saline alkaline lakes existed in the BB during WPM time. The thermal stability of shortite, coupled with vitrinite reflectance data and inferred regional geothermal gradients, establish that the WPM was buried to depths of ~ 1,500 m and experienced post WPM erosion of ~ 800 m.</p>

The recent, rapid decline in Arctic summer sea ice extent has prompted questions as to the rates and magnitude of previous sea ice decline and the affect of this physical change on ice-related ecosystems. However, satellite data of sea ice only extends back to 1978, and mapped observations of sea ice prior to the 1970s are sparse at best. Inventories of boreal ecosystems are likewise hampered by a paucity of investigations spanning more than the past few decades. Paleoclimate records of sea ice and related primary productivity are thus integral to understanding how sea ice responds to a changing climate. Here I examine modern sedimentation, decadal-scale climate change in the recent past, and centennial- to millennial-scale changes of the past 400 ka using both qualitative and quantitative diatom data in concert with sedimentology and organic geochemistry. Diatom taxonomy and corresponding ecological affinities are compiled in this study and updated for the Bering Sea region and then used as recorders of past climate changes. In recent decades, the Pacific Decadal Oscillation and the strength of the Aleutian Low are reflected by subtle changes in sediment diatom assemblages at the Bering Sea shelf-slope break. Farther back in time, the super-interglacial, marine isotope stage (MIS) 11 (428 to 390 ka), began in Beringia with extreme productivity due to flooding of the Bering Land Bridge. A moisture-driven advance of Beringian glaciers occurred while eustatic sea level was high, and insolation and seasonality both decreased at the global peak of MIS 11. Atlantic/Pacific teleconnections during MIS 11 include a reversal in Bering Strait throughflow at 410 ka and a relationship between North Atlantic Deep Water Formation and Bering Sea productivity. Finally, concentrations of the biomarker-based sea ice proxy, IP25, are compared to sea ice concentration across the Bering and Chukchi seas. Changes in the concentration of IP25 in the sediments may be driven by the length of time that the epontic diatom bloom lasts. When combined with a sediment-based proxy for sea surface temperatures, IP 25 can be used to reconstruct spring ice concentration.