A Dissertation submitted to the Faculty of science, University of the Witwatersrand, Johannesburg, for the Degree of Doctor of Philosophy / The Late Proterozoic Damara Oroqen (750-450 Ma} in Namibia forms part of the Pan-African mobile belt system which dissects southern Africa. The Khomas Trough in the inland branch of the orogen comprises thick multiply deformed metagraywackes and pelites of the Kuisab Formation. (Abbreviation abstract). / Andrew Chakane 2019

A thesis submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the degree of Doctor of Philosophy. Johannesburg, 2015. / The Palaeoproterozoic Baoulé-Mossi domain of the West African Craton in northeastern Burkina Faso hosts numerous gold deposits such as Essakane and Tarpako. Integrated strato-tectonic, geophysical, geochemical, geochronological, regional stratigraphic framework and metallogenic studies of the Oudalan-Gorouol volcano-sedimentary Belt and the Gorom-Gorom Granitoid Terrane have provided new insight into the geotectonic evolution of the northeastern part of Burkina Faso. This work outlines the structural context and architecture necessary for forming these deposits. In this work, a new strato-tectonic model is proposed for the area by integrating field data and geophysical, geochemical, and geochronological data. The integrated data highlights and characterizes the setting of the Essakane gold mine and gold camp relative to the location of other regional gold deposits, metamorphosed Birimian Supergroup, intrusive rocks and shear zones. Structural, geochemical and geochronological analyses have helped to clarify the geological evolution of the Oudalan-Gorouol volcano-sedimentary Belt and the Gorom-Gorom Granitoid Terrane during the Tangaean (D1) and Eburnean (D2) orogenies through to the Wabo Tampelse Event (D3). Further to these, zircon U-Pb geochronology data have demonstrated that the Oudalan-Gorouol volcano-sedimentary Belt and the Gorom-Gorom Granitoid Terrane represent some of the oldest outcropping geology in the Palaeoproterozoic Baoulé-Mossi domain recognised to date. The geochronology and geology suggest that the basement or a pre- Birimian crust to the Birimian Supergroup may be found in the northeast of Burkina Faso. The Eburnean Orogeny in northeastern Burkina Faso is preceded by two phases of deformation (D1-x and D1), and two phases of magmatism. The first, D1-x, is associated with the emplacement of the Dori Batholith at the onset of D1 (2164 – 2141 Ma). D1 ductile-brittle deformation formed F1 folds and discrete high-strain mylonite zones that deformed the Oudalan- Gorouol volcano-sedimentary Belt and the Gorom-Gorom Granitoid Terrane during a southwestdirected palaeo-principal compressive stress. The pre-Birimian to Birimian supracrustal rocks and intrusions were regionally metamorphosed during D1 to greenschist to amphibolite facies with development of mineral assemblage of quartz-chlorite-muscovite ± chloritoid to biotite-potash feldspar ± hornblende. D1 is also associated with volcanic arc type calc-alkaline magmatism, producing TTGs enriched in heavy rare earth elements. The Eburnean Orogeny (2130 – 1980 Ma) is characterised by northwest-southeast shortening; it was followed by north-northwest - south-southeast shortening with development of northeast trending sinistral strike-slip faults and shears. D2 brittle-(ductile) deformation is manifested by refolding of F1 by northeast-trending F2, and development of a pervasive northeast-trending S2 to S2-C foliation. Metamorphic grade attained greenschist facies during D2, with development of mineral assemblage of quartz-chlorite-muscovite ± actinolite. The Wabo Tampelse (D3) deformation event is brittle in character and does not significantly affect the regional geological architecture in the study area.

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Sedimentological analyses, including detailed facies characterization and lateral profiling, demonstrate deposition in a bedload-dominated fluvial system for the quartzose sandstones of Lee Formation. Internal (architectural) elements of the sandstones consist primarily of truncated channel-fIll sequences. Individual channel elements, up to 20 meters thick, contain a complex hierarchy of bedform deposits. The principal internal component of channels were downstream-accreting (mid-channel?) macroforms; channel elements frequently contain deposits of more than one macroform. Reconstruction of the macroforms reveals accretion primarily by superposed bedforms that migrated down a low-angle front. Steeper, giant foresets, transitional along flow with the low-angle facies, indicate that the macroform episodically developed a steep slipface. Uppermost channels within the Rockcastle Member contain macroform elements with components of lateral accretion, interpreted as deposits of alternate bank-attached macroforms. Also recognized within channel-fill deposits are minor-channel, sandy-bedform, gravity-flow (attributed to bank slumping), and channel-bottom elements. The latter element is contained within a facies sequence that suggests rising- to flood- to waning-stage deposition. In general, deposition was probably during relatively high stage; little evidence of low-stage flow was recognized. Subordinate fine-grained facies are interpreted as levee and overbank deposits. Strongly unimodal paleocurrents, lack of facies that suggest low-stage reworking and paucity of lateral-accretion features indicate deposition in a single-channel, low-sinuousity, system (i.e., a low braiding index). Fluvial architecture similar to that found in the Lee Formation has been previously explained by deposition in multi-channel, braided-river systems. However, the internal architecture of sandstone members is also consistent with a single-channel origin. Individual channels were temporarily confined, during which time the passage of several macroforms aggraded the channel. Position of the channel in the alluvial plain was largely controlled by avulsion of the river from fully aggraded channel belts to other areas of the plain. Calculations reveal that avulsion of a single-channel system across a wide alluvial plain is a plausible mechanism for building the sheet-like sandstone bodies of the Lee Formation. Spatial arrangement of individual sandstone members of the Lee Formation was probably controlled by tectonic processes. Episodic thrust-loading in the orogenic belt to the east and subsequent flexure of the crust in the foreland basin caused a step-wise progression of the river system towards the west. Petrographic, sedimentologic and stratigraphic data indicate that source area and climate functioned as the primary controls on the mature composition of sandstones in the Lee Formation. Source areas were composed primarily of quartz-rich sedimentary rocks and were located chiefly to the northeast/north. A east/southeast source area supplied subordinate and low-grade metamorphic rock fragments. Intense weathering, associated with humid tropical climates, acted upon the detritus throughout the sedimentation cycle. Less important controls on composition were tectonics and transport/depositional processes that extended exposure of the sediments to the severe climatic conditions. Quartzose sandstones of the Lee Formation reflect lower rates of tectonic subsidence and greater recycling of sand-sized grains during transportation and temporary deposition on the alluvial plain, relative to lithic time equivalents to the east. / Ph. D.

Treatment of Rainbow Trout (Oncorhynchus mykiss) Raceway Effluent Using Baffled Sedimentation and Artificial Substrates. The treatment performance of a 6 m wide by 67 m long by 0.8 m deep, baffled sedimentation basin receiving rainbow trout <i>(Oncorhynchus mykiss)</i> raceway effluent was evaluated with and without the installation of artificial substrates (Aquamats®). Treatment efficiency was also determined using normal rearing condition effluent loading versus cleaning and harvesting events. Total suspended solids (TSS) removal for the total basin averaged 79% and 71% during normal rearing conditions, as compared to 92% and 79% during cleaning and harvesting operations, when the Aquamats® were installed versus removed, respectively. Total phosphorus (TP) removal by the total basin, with and without Aquamats®, was 20% and 23% during normal rearing conditions as compared to 55% and 65% under cleaning and harvesting conditions, respectively. Higher TP removal during cleaning operations was attributed to sedimentation of particulate fractions. Dissolved nutrient removal (ortho-phosphate (OP), total ammonia nitrogen (TAN), nitrate, nitrite, and total organic carbon (TOC)) was not consistent throughout the basin and did not improve when the Aquamats® were installed. A short contact time and periphyton grazing by isopods may have limited the capacity of the Aquamats®. Calculated retention times with and without Aquamats® for the first half and total basin were 37% and 32% and 27% and 17% less than theoretical values, respectively based on a rhodamine WT dye study. Average surface overflow rates were adjusted accordingly and measured 19.1 m³/m²-day when the Aquamats® were installed, versus 14.8 m³/m²-day when the Aquamats® were removed for the overall basin. These rates are lower than previous recommendations for treating aquaculture effluents, but resulted in with high solids removal and consistently low TSS effluent (average < 2 mg/L) which may be necessary for strict discharge permits. Use of the overall basin minimized the occurrence of TSS measurements > 2 mg/L by 50%. For the first half of the sedimentation basin, the overflow rate averaged 44.1 m³/m²-day with Aquamats® versus 35.8 m³/m²-day without Aquamats®. The majority of effluent treatment occurred within the first half of the basin, which was responsible for 84% and 94% of total TSS removal, 42% and 100% and 61% and 80% of total TP removal during normal and cleaning/harvesting conditions, respectively.> Characterization of Nutrient Leaching Rates from Settled Rainbow Trout <i>(Oncorhynchus mykiss)</i> Sledge The leaching of nutrients from settled rainbow trout <i>(Oncorhynchus mykiss)</i> sludge into overlying water was evaluated over a 7 day period. Nutrient leaching was assessed in a stagnant reaction tank and one agitated by aeration to simulate turbulent conditions in stocked production raceways. Leaching of total phosphorus (TP), ortho-phosphate (OP), total Kjeldahl nitrogen (TKN), total ammonia nitrogen (TAN), and total organic carbon (TOC) occurred rapidly during the first 24 h in both stagnant and agitated conditions. The highest 24 h leaching occurred in the agitated tank, and power regression equations accurately described the varying rates of increasing TP, OP, TAN and TKN. In the stagnant tank, linear increases of TP, OP, TKN and TAN concentrations occurred during the first 24 h. These linear increases continued from day 2-7, but at slower rates than occurred during the first 24 h. Average nutrient leaching rates (mg leached/g sludge-h);(dry weight basis) were calculated based on linear concentration increases. In the agitated tank, nutrient concentrations decreased after 60 h, as aerobic bacterial uptake and/or chemical precipitation was suspected. Therefore, average leaching rates could not be determined. These findings reveal that daily cleanout of settling areas could eliminate the release of TP, OP, TAN, TKN, and TOC from settled solids by 66%, 65%, 39%, 76% and 51%, respectively, as compared to weekly cleanout schedules. Sustained leaching rates indicate nutrient release will likely continue beyond 7 days. This information suggests aggressive and continuous sludge management is most beneficial for maintaining high water quality and regulatory discharge compliance in fish production. / Master of Science

Horizontal subsurface flow (HSSF) constructed wetlands were evaluated for the treatment of flow-through trout farm effluent, phosphorus sorption affinity of gravel-bed media, and influence on Rhodamine WT (RWT) transport. HSSF wetlands coupled with mechanical pretreatment demonstrated significant (p <0.05) removal of total ammonia-nitrogen (TAN), total phosphorus (TP), total organic carbon (TOC), total suspended solids (TSS), five-day biochemical oxygen demand (BOD5), and turbidity. Treatment occurred predominantly within the wetland cells, with minimal removal of studied water quality parameters by means of sedimentation or microscreen filtration (80 ?m mesh). HSSF wetlands removed 69% of influent TSS, 24% of influent TP, and reduced turbidity by 66%. The removal of organic matter within the wetlands, as measured by BOD5, COD, and TOC was 62%, 50%, and 55%, respectively. After receiving effluent from a flow-through trout farm for about one year, the gravel media exhibited moderate removals of soluble phosphorus in batch and column sorption experiments. Partition coefficients (Kd) from batch sorption tests ranged from 45-90 mL/g. Low (60 mL/min) and high (165 mL/min) flow column experiments removed about 50 and 40% of influent PO4-P, respectively. The conservative nature of RWT in subsurface media has been called into question by many authors. Tracer response curves from tests conducted in pilot-scale HSSF wetlands exhibited elongated tails and dual peaks, in addition to mean tracer retention times far exceeding the theoretical value. Laboratory column testing of RWT and the more conservative NaCl tracer supported field data, indicating that RWT was more reactive within the wetland media. / Master of Science