Petroleum migration pathways through a basin are determined by the three-dimensional distribution of discontinuous sealing surfaces, which are usually parallel to bedding. The petroleum migrates below the sealing surface taking the structurally most advantageous route. The three-dimensional distribution of migration pathways within the petroleum system can be modelled on a personal computer using a program based on the parameters developed during the research summarised in this thesis. Application of the model to the Paris, Williston, West of Shetlands and Wessex Basins demonstrates that a good correlation can be made between predicted pathways and discovered accumulations using simple models. Migration pathways form a dense network overlying hydrocarbon generating areas in the central parts of basins. Towards the basin margins they commonly become increasingly focused into discrete pathways by the sealing-surface morphologies. The Paris and Williston Basin research showed how relatively minor structuring of geological strata can result in a significant focusing of pathways. Eventually these pathways may reach the surface as shown by seepages. Research in the Wessex Basin revealed that reverse modelling of pathways from seeps assists in the prediction of the location of leaking accumulations. Deflection of the pathways from the structurally most advantageous route below the sealing surface may be caused by lateral sealing barriers due to facies variation in the carrier rock below the seal, fault juxtaposition, or cross-formational seals such as salt intrusions. Deflection of pathways also occurs where there are hydrodynamic conditions in response to topography-driven groundwater flow.

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In the northern Gulf of Mexico, seafloor hydrocarbon fluid and gas seepage is an ubiquitous process on the continental margin. Although seafloor seepage and seep-related features (mud volcanoes, carbonate formation) have been studied for many years, little is known about their mechanisms of formation and the relationship of sub-surface structure to current seep activity. In this study, we examined three seafloor seeps in the Garden Banks and Mississippi Canyon areas using exploration and reprocessed 3D multi-channel seismic (MCS) data augmented with side-scan sonar (Garden Banks site) to characterize hydrocarbon seep activity and develop an understanding of the processes that led to their formation. Side-scan sonar data provided high resolution coverage of the seafloor while the exploration seismic data were used to image near and deep sub-surface features. Additionally, the 3D amplitude extraction maps were useful in delineating amplitude anomalies often associated with seep related activity. The reprocessed 3D seismic data were used to map in greater detail near seafloor features and amplitude anomalies. Using remote sensing geophysical data, we were effectively able to map sub-surface features such as salt topography, seep-related faults and geophysical indicators of hydrocarbons and correlate them with seafloor amplitude anomalies and fault traces in order to characterize seep activity level. The southern mud volcano in the Garden Banks site is characterized as an established high flux seep vent owing to signs of active seepage and sediment flows as well as the build-up of hard grounds. The northern mud volcano in the area, with greater hard ground build-up and fewer signs of active seepage represents an established low flux seep vent. In the Mississippi Canyon area, the data suggest that the seep mound can be characterized as a mature high flux vent due to the extensive build-up of hard ground, evidence of gas hydrates and signs of active seepage and sediment flows. The mechanisms of formation are similar between the two study sites. Upwelling salt appears to have fractured the sub-surface leading to the formation of fault induced depressions. Mapping of geophysical indicators of hydrocarbons implies that hydrocarbon migration is occurring along bedding planes to the fault systems underlying the depressions. Here they appear to migrate vertically to the seafloor creating the topographic features and seafloor amplitude anomalies that characterize the seeps

Carbon Dioxide (CO₂) sequestration requires that the injected CO₂ be permanently trapped in the subsurface and not leak from the target location. To accomplish this, it is important to understand the main mechanisms associated with CO₂ flow and transport in the subsurface once CO₂ is injected. In this work CO₂ seeps at the Crystal Geyser site were studied using modeling and simulation to determine how CO₂ geochemically reacts with formation brines and how these interactions impact the migration of CO₂. Furthermore different scenarios for CO₂ migration and seepage along the Grand Wash fault are studied and the possible outcomes for these different scenarios are documented. The GEM (Generalized Equation-of-State Model) from CMG Ltd. was used to perform the simulation studies. A 2-D model was built without geochemical reactions to mainly study the mechanism associated with dissolution of CO₂ gas. The process of CO₂ release from the brine as the fluid mixture flows up along the fault was modeled. Then, 3-D models with geochemical reactions were built for CO₂ migration corresponding to two different sources of CO₂ - deep crustal ₂ and CO₂-dissolved in groundwater. In both these cases, CO₂ reacted with the aqueous components and minerals of the formation and caused carbonate mineralization. In the case of deep crustal CO₂ source, there were vertical patterns of calcite mineralization simulated along the fault that indicated that calcite mineralization might be localized to isolated vertical flow paths due to vertical channeling of CO₂ from the crust. In the case of CO₂-dissolved groundwater flowing along the sandstone layers, calcite mineralization is spread over the entire fault surface. In this case, the groundwater flow is interrupted by the fault and there is vertical flow along the fault until a permeable sandstone layer is encountered on the other side of the fault. This vertical migration of CO₂-saturated brine causes a release in pressure and subsequent ex-solution of CO₂. As a result, modeling allowed us to establish difference in surface expression of CO₂ leakage due to two different CO₂ migrations scenarios along the fault and helped develop a scheme for selecting appropriate model for CO₂ leakage based on surface observation of travertine mounds. A key observation at the Crystal Geyser site is the lateral migration of CO₂ seep sites over time. These migrations have been confirmed by isotope studies. In this modeling study, the mechanism for migration of seep sites was studied. A model for permeability reduction due to precipitation of calcite was developed. It is shown using percolation calculations that flow re-routing due to permeability alterations can result in lateral migration of CO₂ seeps at rates comparable to those established by isotope dating. / text

Rising carbon dioxide (CO2) concentrations in the atmosphere will increase the average pCO2 level in the world oceans, which will have a knock-on effect on the marine ecosystem. Coastal seagrass communities one of the most productive marine ecosystems are predicted to benefit from the increase in CO2 levels, but long-term effects of elevated CO2 on seagrass communities are less understood. Population reconstruction techniques was used to investigate the population dynamics of Cymodocea nodosa meadows, exposed to long term elevated CO2 at volcanic seeps off Greece and Italy. Effect of elevated CO2 was noticed on the growth, morphometry, density, biomass and age structure at CO2 seeps. Above to below ground biomass ratio of C. nodosa were higher at CO2 seeps than at reference sites. The plastochrome interval were similar at all CO2 seeps. The shoot age and shoot longevity of plants were lower at seeps than reference sites. The present recruitment (sampled year) of the seagrass were higher than long-term average recruitment of the communities near the seeps. Carbon to nitrogen ratios (%DW) of C. nodosa were higher in leaves at seeps. Annual leaf production was higher near the seeps. This study suggests increased production of C. nodosa under elevated CO2 levels, but other co-factors such as nutrients, trace metal toxicity must also be taken into consideration while predicting effects of future CO2 concentrations. Volcanic CO2 seeps are now being used as natural analogues for ocean acidification studies although these areas can be affected by trace element input and may alter ecosystem responses to gradient in carbonate chemistry. Here Fe and a range of trace elements (Cd, Co, Cu, Hg, Mn, Pb, Ni and Zn) were analysed from sediments and from the roots, rhizomes and leaves of seagrass at six CO2 seeps and reference sites off Greece and Italy. There were higher metal levels in sediment and seagrasses at all CO2 seeps than reference sites. Sediment Quality Guideline Quotient, a commonly used pollution index, indicated that some of the metals (Cd, Cu, Hg, Ni) were in high enough concentrations to have adverse biological effects, such as Cu at Ischia site and Hg at Vulcano. Higher accumulation of elements from sediments in roots and leaves at CO2 seeps were found from Bio Sediment Accumulation Factor index. There were higher levels of Cu, Fe, Mn and Zn in leaves and rhizomes for P. oceanica and higher levels of Cd, Co, Cu, Fe and Zn in C. nodosa compartments at CO2 seeps. Fe and Mn were found with positive correlation within sediment-roots and sediment-rhizomes, whereas Cd, Co and Pb were found with positive correlation in compartments of C. nodosa. In P. oceanica positive correlation were only observed for Cd within sediment-roots and plant compartments. Low pH and ocean acidification increased the concentration of elements at CO2 seeps than reference sites. Thus, caution is needed, when using volcanic seep systems as analogue for the effects of rising CO2, as metals can reach levels that are toxic to seagrass, masking any potential benefits of increased levels of carbon dioxide for seagrass productivity. Net community production (NCP) and community respiration (CR) were measured under air exposed and CO2 enriched conditions for intertidal Z. noltei meadows and unvegetated sediment communities during emersion in summer and winter seasons. Community production and respiration were measured in-situ using benthic chambers. CO2 flux under air and CO2 enriched conditions were measured over a series of short term incubations (30min) using an infra-red gas analyser. Incident photosynthetic active radiation (PAR) was recorded during the incubations covering the daily and seasonal variation. Linear regression model was used to test the effects of irradiance on net community production. NCP of Z. noltei community were higher under CO2 enriched conditions than air exposed conditions in both summer and winter seasons. There was no effect of CO2 on the CR rate of Z. noltei community in summer season. NCP of sediment community were higher in summer season and winter season under CO2 enriched conditions. Sediment CR rates were higher in winter than summer season. The light compensation point of Z. noltei and sediment community were lower in both seasons under CO2 enriched conditions. Seasonal budget of community production was higher in Z. noltei than sediment communities. A clear effect of PAR was noticed on the net community production of both communities. Higher PAR intensities resulted in higher NCP under CO2 enriched conditions for both communities. CO2 enrichment will have a positive effect on the intertidal communities during emersion.

Ocean acidification may cause biodiversity loss, alter ecosystems and impact food security, yet uncertainty over ecological responses to ocean acidification remains considerable. Most work on the impact of ocean acidification on foraminifera has been short-term laboratory experiments on single species. To expand this, benthic foraminiferal assemblages were examined across shallow water CO2 gradients in the Gulf of California, off the islands of Ischia and Vulcano in Italy and off Papua New Guinea. Living assemblages from the Gulf of California did not appear to show a response across a pH range of 7.55 – 7.88, although the species assemblage was impoverished in all locations and the dead assemblage was less diverse at the lowest pH sites where there was evidence of post mortem dissolution. At Vulcano, the small macroalga, Padina pavonica, did not protect calcareous foraminifera from the adverse effects of ocean acidification. Calcareous taxa disappeared from the assemblage and were replaced by agglutinated foraminifera as mean pH reduced from 8.19 to 7.71. Settlement of benthic foraminifera onto artificial collectors off Vulcano was adversely affected in the acidified water, with few species as pCO2 increased and evidence of post-mortem dissolution. The foraminiferal tests, collected off Papua New Guinea, had lower δ11B as mean pH decreased from 7.99 – 7.82 for small (250 – 500 µm) Amphistegina lessonii, but not for A. lessonii or Calcarina spengleri >500 µm. In the larger foraminifera, photosynthetic activity by symbionts may begin to dominate the boron isotopic signature. Overall, the responses of foraminiferal assemblages to ocean acidification are complex, but there was an overall reduction in species diversity in infaunal, epifaunal and epiphytic assemblages as pCO2 increased. This raises serious concerns for the survival of shallow water calcareous benthic foraminifera as the oceans continue to acidify, with implications for benthic ecosystems and inorganic carbon cycling.

xx, 198 p. A print copy of this thesis is available through the UO Libraries. Search the library catalog for the location and call number. / "Bathymodiolus" childressi is a mixotrophic mussel from Gulf of Mexico cold seeps. There is no genetic differentiation of mussels among the seeps, suggesting wide dispersal of their larvae. This dissertation describes larval biology, ecology, and recruitment dynamics for "B." childressi. Cleavage is spiral at a rate of one per 3-9 hours, with blastula larvae hatching by 40 hours at 7-8 à à °C. At 12-14 à à °C, D-shell veligers developed by day 8 without being fed. Egg size and shell morphology indicate planktotrophy, but feeding was not observed. Embryos developed normally from 7-15 à à °C and 35-45 ppt. Although survival of larvae declined with temperature, some survived at 25 à à °C. Larval survivorship was similar at 35 and 45 ppt. Oxygen consumption increased from blastulae to trochophores and was higher for "B." childressi than for shallow-water mussel trochophores. Estimated energy content of "B." childressi eggs was greater than the energy content of shallow-water mussel eggs. An energetic model predicts that the eggs provide sufficient energy for "B." childressi trochophores to migrate into the euphotic zone. In fact, "B." childressi veligers were found in plankton tows of surface waters. The influence of recruitment on fine-scale distributions of adults at the Brine Pool cold seep was examined through manipulative field experiments. The "Bathymodiolus" childressi population at this site has a distinct bimodal size structure that shifts across an environmental gradient. New recruits of "B." childressi are abundant in the inner zone, where methane and oxygen are high and sulfide is low, leading to the inference that larvae settle preferentially there. Experiments were placed in the inner and outer zones and 2-m away from the bed. The number of larvae collected in traps did not differ among the three zones, nor did settlement density. Juveniles survived and grew in all zones, but more caged than uncaged juveniles survived. Mortality of uncaged juveniles was similar in all zones, suggesting that predation does not cause the bimodal distribution. These results suggest that the bi-modal distribution cannot be attributed to settlement preferences or juvenile mortality, but instead to migration or early post-settlement mortality. This dissertation includes my co-authored materials. / Adviser: Craig M. Young

Natural hydrocarbon seeps harbor distinctive geological, chemical, and biological features in the marine environment. This thesis verified remote sensing signatures of seeps using in-situ observation and repeated collections of satellite imagery. Bubble streams in the Gulf of Mexico water column from four natural seep sites on the upper continental slope were imaged by a side-scan sonar, which was operated from a submarine near the seafloor, and by acoustic profilers, which were operated from surface ships. These data were correlated with sea surface slicks imaged by Synthetic Aperture Radar (SAR) on the RADARSAT satellite. Comparing non-oily bubble streams from rapidly venting mud volcanoes with oily bubble streams from shallow deposits of gas hydrate showed that they produced notably different signatures. Non-oily bubbles produced high backscatter on the side-scan sonar records, but were difficult to detect with the acoustic profilers. Oily bubbles from hydrate deposits produced acoustic shadows on the side-scan sonar records. The oily bubbles generated clear signatures extending from the seafloor to the near surface on the acoustic profile records. RADARSAT SAR images verified the presence of surface oil slicks over the hydrate deposits, but not over the mud volcanoes. This indicates that SAR imagery will not be able to capture every oil and gas seep in a region because non-oily bubble streams do not create surface oil slicks. A total of 113 natural oily seep sources were identified based on surface slicks in eleven SAR images collected over the northern continental slope. A persistence analysis verified that SAR is a dependable tool for capturing oil slicks because 93.5% of the slick sources identified in the 2001 images were corroborated with slicks in the 2002 images. The sources ranged in depth from 100 to 2000 m and 79% of the sources were in 900 meters or greater of water. Seventy-six percent of the seep sources were associated with salt less than 1500 m below the seafloor and none of the sources were located in the bottom of salt withdrawal basins. Geographical Information Systems (GIS) proved to be a useful tool in these analyses.

Natural hydrocarbon seeps harbor distinctive geological, chemical, and biological features in the marine environment. This thesis verified remote sensing signatures of seeps using in-situ observation and repeated collections of satellite imagery. Bubble streams in the Gulf of Mexico water column from four natural seep sites on the upper continental slope were imaged by a side-scan sonar, which was operated from a submarine near the seafloor, and by acoustic profilers, which were operated from surface ships. These data were correlated with sea surface slicks imaged by Synthetic Aperture Radar (SAR) on the RADARSAT satellite. Comparing non-oily bubble streams from rapidly venting mud volcanoes with oily bubble streams from shallow deposits of gas hydrate showed that they produced notably different signatures. Non-oily bubbles produced high backscatter on the side-scan sonar records, but were difficult to detect with the acoustic profilers. Oily bubbles from hydrate deposits produced acoustic shadows on the side-scan sonar records. The oily bubbles generated clear signatures extending from the seafloor to the near surface on the acoustic profile records. RADARSAT SAR images verified the presence of surface oil slicks over the hydrate deposits, but not over the mud volcanoes. This indicates that SAR imagery will not be able to capture every oil and gas seep in a region because non-oily bubble streams do not create surface oil slicks. A total of 113 natural oily seep sources were identified based on surface slicks in eleven SAR images collected over the northern continental slope. A persistence analysis verified that SAR is a dependable tool for capturing oil slicks because 93.5% of the slick sources identified in the 2001 images were corroborated with slicks in the 2002 images. The sources ranged in depth from 100 to 2000 m and 79% of the sources were in 900 meters or greater of water. Seventy-six percent of the seep sources were associated with salt less than 1500 m below the seafloor and none of the sources were located in the bottom of salt withdrawal basins. Geographical Information Systems (GIS) proved to be a useful tool in these analyses.

Cold seep ecosystems in the deep sea are fuelled by chemosynthetic processes based on methane emission to the sediment surface from gas hydrate disassociation, methanogenesis or thermogenic processes. While cold seep ecosystems have been studied in the last three decades worldwide, little is known about New Zealand’s cold seep habitats and associated fauna. A joint German-New Zealand cruise to the Hikurangi Margin in early 2007 enabled biological and sediment sampling to investigate the biological and sedimentological relationships and variability of seeps and their faunal diversity. Multi-disciplinary approaches were employed that included Xray radiography, stratigraphic descriptions, lebensspuren traces analysis, sediment grain size analysis, determination of total organic content, carbonate content and its stable isotopic composition, and analysis of benthic invertebrate assemblages of seep habitats. The results of this study revealed three distinctive habitats and associated fauna based on the sediment characteristics and faunal type. Habitat 1 includes all sites pertaining to Omakere Ridge, a seep-related habitat comprised of layers of very poorly sorted, sandy silt, shell hash and bands of methane-derived authigenic aragonitic carbonate nodules with low total organic content (TOC). Due to the characteristics of the sediments and death assemblages of molluscs, it is inferred that Habitat 1 methane seepage is actively diffusive, waning or dormant. Habitat 2 describes sites that are either non-seep or relic and applies to those at Bear’s Paw and Kaka. Habitat 2 constituted of shell hash overlain with very poorly sandy silt, and low carbonates content and low to medium TOC. Habitat 3 describes non-seep related habitats, and includes all sites of the Wairarapa region and one reference site from Kaka also falls into this category. Sediments for Habitat 3 constituted poorly sorted silt with high TOC and low carbonate content which can be explained by their close proximity to land and converging sea currents. The mineral components of the background siliciclastic sediments for all sites studied originated in the Tertiary mudstone of the East Coast Basin. The characteristics of seep habitats of the Hikurangi Margin were comparable to that of the Northern Hemisphere modern seep counterparts, although the abundance and distributions of seep fauna were low. Results from this research have enhanced our understanding on the spatial and variability of methane fluxes and their affects on the duration of cold seep ecosystems, especially for New Zealand. However, more such studies are essential to increase our understanding of seep sediments and explain disturbance-sediment-benthic invertebrate interactions.