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Made available in DSpace on 2014-10-09T12:43:12Z (GMT). No. of bitstreams: 0 / Made available in DSpace on 2014-10-09T13:56:31Z (GMT). No. of bitstreams: 1 06442.pdf: 6689802 bytes, checksum: 46ba1e2b896e77a4288d24e80ac804ff (MD5) / Dissertacao (Mestrado) / IPEN/D / Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP

In this work the development of a Self-Powered System-On-Chip is explored by examining two components of process development in different perspectives. On one side, an energy component is approached from a biochemical standpoint where a Microbial Fuel Cell (MFC) is built with standard microfabrication techniques, displaying a novel electrode based on Carbon Nanotubes (CNTs). The fabrication process involves the formation of a micrometric chamber that hosts an enhanced CNT-based anode. Preliminary results are promising, showing a high current density (113.6mA/m2) compared with other similar cells. Nevertheless many improvements can be done to the main design and further characterization of the anode will give a more complete understanding and bring the device closer to a practical implementation. On a second point of view, nano-patterning through silicon nitride spacer width control is developed, aimed at producing alternative sub-100nm device fabrication with the potential of further scaling thanks to nanowire based structures. These nanostructures are formed from a nano-pattern template, by using a bottom-up fabrication scheme. Uniformity and scalability of the process are demonstrated and its potential described. An estimated area of 0.120μm2 for a 6T-SRAM (Static Random Access Memory) bitcell (6 devices) can be achieved. In summary, by using a novel sustainable energy component and scalable nano-patterning for logic and computing module, this work has successfully collected the essential base knowledge and joined two different elements that synergistically will contribute for the future implementation of a Self-Powered System-on-Chip.

Mobile devices for the personalized detection of health and environmental hazards are becoming the basis for futuristic sensing technologies. In recent decades, air and environmental pollution levels have risen globally. Therefore, environmental protection must be strengthened by developing sensors that detect pollutants. The monitoring of these pollutants with high spatial coverage requires inexpensive electronic gas sensors and self sustainable sensing systems that can be deployed everywhere. This dissertation reports on technological developments to provide solutions for inexpensive, compact, power efficient, and easily deployable toxic gas sensors and integrated systems using semiconducting metal-oxide thin-film transistors (TFTs). The first part of the dissertation introduces the fabrication and characterization of an amorphous indium gallium zinc oxide (IGZO) TFT as a toxic gas sensor. In contrast to existing metal-oxide gas sensors, which are active either with light activation or at high temperature, the developed IGZO TFT sensors are operable at room temperature and require only visible light activation to revive them after exposure to NO2. IGZO TFT sensors exhibited remarkable selectivity and sensitivity to low concentrations of nitrogen dioxide (NO2). The second part of the dissertation introduces the design and realization of the IGZO-based fully integrated gas detectors. Unlike existing gas-sensing systems, which have discrete hardware for signal conditioning, read-out, and data acquisition, the developed integrated detectors constitute thesemodules integrated using IGZO TFT technology. The integrated detectors detect ambient NO2 gas and generate a digital output that is proportional to the ambient gas concentrations. Two types of integrated gas detectors were developed that differ in their mode of operation and circuitry design. These detectors are scalable and pave the way for portable systems to realize various gas-sensing applications, including smart cities and sustainable ecosystems. The success of personalized monitoring devices relies on the following factors: minimum power consumption, selectivity, and stability under extreme conditions that determine overall performance. One of the best solutions to minimize power consumption in these devices is to have a complementary energy-harvesting feature. Hence, the dissertation concludes with the design of self-powered sensors, which are IGZO sensors with self-powering capabilities. Self-powered sensors are p-n heterojunction sensors, developed using IGZO and hybrid-perovskites.

The Internet of Things (IoT) is an infrastructure of physical objects connected via the Internet that can exchange data to achieve efficient resource management. Billions of devices must be self-powered and low-cost considering the massive scale of the IoT. Thus, there is a need for low-cost ambient energy harvesters to power IoT devices. It is a challenging task since ambient energy might be unpredictable, intermittent and insufficient. For example, solar energy has limitations such as intermittence and unpredictability despite utilizing the highest power availability and relatively mature technology. Designing a multi-source energy harvester (MSEH) based on continuous and ubiquitous ambient energy sources might alleviate these issues by providing versatility and robustness of power supply. However, combining several energy harvesters into one module must be done synergistically to ensure miniaturization, compactness and more collected energy. Also, additive manufacturing techniques must be used to achieve low-cost harvesters and mass manufacturability. This dissertation presents two different kind of ambient energy harvesters, namely radio frequency energy harvester (RFEH) and thermal energy harvester (TEH). Each harvester is individually optimized and then synergistically combined into a MSEH. First, RFEH is designed for triple-band harvesting (GSM900, GSM1800, 3G2100) using the antenna-on-package concept and fabricated through 3D and screen printing. TEH collects energy from temperature fluctuations of ambient environment through a combination of thermoelectric generators and phase change materials. It is adapted specifically for the desert conditions of Saudi Arabia. Later, TEH and RFEH are combined to realize MSEH. Smart integration is achieved by designing a dual-function component, heatsink antenna, that serves as a receiving antenna of RFEH and a heatsink of TEH. The heatsink antenna has been optimized for both antenna radiation performance and heat transfer performance. Field tests showed that the MSEH can collect 3680μWh energy per day and the outputs of TEH and RFEH have increased 4 and 3 times compared to the independent TEH and RFEH respectively. To validate the utility of the MSEH, a temperature/humidity sensor has been successfully powered by the MSEH. Overall, sensor’s data can be wirelessly transmitted with time intervals of 3.5s, highlighting the effectiveness of the synergistic MSEH.

This work presents an investigation of a piezoelectric sensor based energy harvesting system, which collects energy from the surrounding environment. Increasing costs and scarcity of fossil fuels is a great concern today for supplying power to electronic devices. Furthermore, generating electricity by ordinary methods is a complicated process. Disposal of chemical batteries and cables is polluting the nature every day. Due to these reasons, research on energy harvesting from renewable resources has become mandatory in order to achieve improved methods and strategies of generating and storing electricity. Many low power devices being used in everyday life can be powered by harvesting energy from natural energy resources. Power overhead and power energy efficiency is of prime concern in electronic circuits. In this work, an energy harvester is modeled and simulated in Simscape™ for the functional analysis and comparison of achieved outcomes with previous work. Results demonstrate that the harvester produces power in the 0 μW to 100 μW range, which is an adequate amount to provide supply to low power devices. Power efficiency calculations also demonstrate that the implemented harvester is capable of generating and storing power for low power pervasive applications.

The triboelectric nanogenerator (TENG) has attracted global attention in the fields of power sources and self-powered sensors. By coupling the omnipresent triboelectrification effect and the electrical induction effect, the TENGs can transduce ambient mechanical energy into electrical energy. Such energy could be consumed instantaneously or stored for later use. In this way, they could be deployed distributedly to be compatible power sources in the era of the internet of things (IoTs), completing the powering structure that is currently relying on power plants. Also, the electrical signals can reflect the environment changes around the TENGs. Thus, the TENGs can serve as self-powered sensors in the IoTs. In this work, we adopted two approaches for TENG fabrication: the thermal drawing method (TDP) and 3D printing. With TDP, we have fabricated scalable fiber-based triboelectric nanogenerators (FTENG), which have been woven into textiles by an industrial loom for wearable use. This fabrication process can supply FTENG on a large scale and fast speed, bridging the gap between the TENG and weaving industry. With 3D printing, we have fabricated TENGs that are compatible with the shape of arbitrary substrates. They have been used as biocompatible sensors: human-skin-compatible TENG has been used to recognize silent speech in real-time by sensing the chin movement; the porcine-kidney-shaped fiber mesh has been used to monitor the perfusion rate of the organ. These works have extended the territory of TENGs and can be critical components in the IoTs. / Ph.D. / Portable electronic devices have become important components in our daily lives, and we are entering the era of the Internet of Things (IoTs), where everyday objects can be interconnected by the internet. While electricity is essential to all of these devices, the traditional power sources are commonly heavy and bulky and need to be recharged or directly connected to the immobile power plants. Researchers have been working to address this mismatch between the device and power systems. The triboelectric nanogenerators (TENG) are good candidates because they can harvest energy in the ambient environment. The users can use them to generate electricity by merely making the rubbing motion. In this work, we report two fabrication methods of the fiber-based triboelectric nanogenerators (FTENG). With the thermal drawing process, we have fabricated sub-kilometer-long FTENG and wove it with the regular cotton yarn into textiles. The wearable power source is human friendly as it does not induce any extra weight load for the user. Besides, we have demonstrated that such long fibers can work as self-powered distributed sensors, such as a Morse code generator. With 3D printing, we have fabricated FTENG-based devices that conform to the working substrates, which can be any shape. We have employed them as biofriendly sensors to translate the chin movement during speaking to language and to monitor the perfusion rate of a pig kidney. The FTENGs have offered excellent comfortability to the users and can play a vital role in reframing the power structure to be compatible with IoTs.

Safety and reliability are one of the key objectives for future Generation IV nuclear energy systems. The neutron flux monitoring system forms an integral part of the safety design of a nuclear reactor and must be able to detect any irregularities during all states of reactor operation. The work in this thesis mainly concerns the detection of in-core perturbations arising from unwanted movements of control rods with in-vessel neutron detectors in a sodium-cooled fast reactor. Feasibility study of self-powered neutron detectors (SPNDs) with platinum emitters as in-core power profile monitors for SFRs at full power is performed. The study shows that an SPND with a platinum emitter generates a prompt current signal induced by neutrons and gammas of the order of 600 nA/m, which is large enough to be measurable. Therefore, it is possible for the SPND to follow local power fluctuations at full power operation. Ex-core and in-core detector locations are investigated with two types of detectors, fission chambers and self-powered neutron detectors (SPNDs) respectively, to study the possibility of detection of the spatial changes in the power profile during two different transient conditions, i.e. inadvertent withdrawal of control rods (IRW) and one stuck rod during reactor shutdown (OSR). It is shown that it is possible to detect the two simulated transients with this set of ex-core and in-core detectors before any melting of the fuel takes place. The detector signal can tolerate a noise level up to 5% during an IRW and up to 1% during an OSR.

Message Authentication Codes (MACs) are valuable tools for ensuring the integrity of messages. MACs may be built around a keyed hash function. Our main motivation was to prove that universal hash functions can be employed as underlying primitives of MACs in order to provide provable security in ultra-low-power applications such as the next generation self-powered sensor networks. The idea of using a universal hash function (NH) was explored in the construction of UMAC. This work presents three variations on NH, namely PH, PR and WH. The first hash function we propose, PH, produces a hash of length 2w and is shown to be 2^(-w)-almost universal. The other two hash functions, i.e. PR and WH, reach optimality and are proven to be universal hash functions with half the hash length of w. In addition, these schemes are simple enough to allow for efficient constructions. To the best of our knowledge the proposed hash functions are the first ones specifically designed for low-power hardware implementations. We achieve drastic power savings of up to 59% and speedup of up to 7.4 times over NH. Note that the speed improvement and the power reduction are accomplished simultaneously. Moreover, we show how the technique of multi- hashing and the Toeplitz approach can be combined to reduce the power and energy consumption even further while maintaining the same security level with a very slight increase in the amount of key material. At low frequencies the power and energy reductions are achieved simultaneously while keeping the hashing time constant. We develope formulae for estimation of leakage and dynamic power consumptions as well as energy consumption based on the frequency and the Toeplitz parameter t. We introduce a powerful method for scaling WH according to specific energy and power consumption requirements. This enables us to optimize the hash function implementation for use in ultra-low-power applications such as "Smart Dust" motes, RFIDs, and Piconet nodes. Our simulation results indicate that the implementation of WH-16 consumes only 2.95 ìW 500 kHz. It can therefore be integrated into a self- powered device. By virtue of their security and implementation features mentioned above, we believe that the proposed universal hash functions fill an important gap in cryptographic hardware applications.

With the rapid progress of nanotechnologies, there are two developing trends for the next generation of sensors: miniaturization and multi-functionality. Device miniaturization requires less power consumption, or even self-powered system. Multi-functional devices are usually based on multi-property coupling effects. Piezoelectric semiconductors have been considered to be potential candidates for self-powered/multi-functional devices due to their piezotronic coupling effect. In this dissertation, ZnO and CdSe nanowire arrays have been synthesized as the piezoelectric semiconductor materials to develop the following self-powered/multi-functional sensors: (1) self-powered gas sensors of ZnO/SnO2, ZnO/In2O3, ZnO/WO3 and CdSe nanowire arrays have been assembled. All these gas sensors are capable of detecting oxidizing gas and reducing gas without any external power supply owing to piezotronic effect which can convert mechanical energies to electrical energy to power the sensors; (2) a self-powered ZnO/ZnSe core/shell nanowire array photodetector has been fabricated. This photodetector is able to detect the entire range of the visible spectrum as well as UV light because of its type II heterostructure. The absolute sensitivity and the percentage change in responsivity of the photodetector were significantly enhanced resulting from the piezo-phototronic effect. The photodetector also exhibited self-powered photodetection behavior; (3) three dimensional nanowire arrays, such as ZnO and ZnO/Co3O4, have been synthesized to investigate piezo-magnetotronic and piezo-photo-magnetotronic effects. Under magnetic field, the magnetic-induced current of ZnO nanowire array decreased as magnetic field increased, and the current difference was magnified by one order of magnitude caused by piezo-magnetotronic effect through applying a stress. In contrast, under UV light illumination, the current response increased with an increment of magnetic field. The current difference was enhanced by at least two orders of magnitude attributed to piezo-photo-magnetotronic effect. Furthermore, ZnO/Co3O4 core/shell structure was employed to further improve the magnetic-induced current difference. This phenomenon projects a potential for multi-functional piezo-magnetotronic and piezo-photo-magnetotronic device development.