Vortex reconnections and interactions play a fundamental role in the dynamics of fluids and turbulent flows, both in the classical and quantum regime. Studying vortices in a clean system like ultracold gases can therefore help, as a bottom-up approach, to understand the physics in a wider context, including superfluid helium, polariton condensates, fluid dynamics and turbulence, neutron stars and cosmological models. So far vortex-vortex interaction was studied in Bose-Einstein condensates either in rotating systems with the observation of regular Abrikosov lattices or in flat condensates across the Berezinskii-Kosterlitz-Thouless transition. In both cases the geometrical constraints allowed to study just a planar interaction among aligned or anti-aligned vortices. The present study instead is carried out in an axisymmetric cigar-shaped Bose-Einstein condensate. Vortices in prolate structures are also known as solitonic vortices. This geometry is especially suitable for investigating vortex interactions. Indeed vortices are oriented perpendicularly to the condensate axis to minimize their length, hence energy, and, because of the cylindrical symmetry, the orientation of a vortex in the radial plane has no constraints. These facts permit interactions to occur with different incoming relative angles between the vortex lines and with different relative velocities. The strong confinement, acting along the radial axis, enhances also interesting effects due to the boundaries.

In the context of the electrification of the chemical industry, this thesis sets itself the goal of studying two promising plasma reactors: a nanosecond repetitively pulsed (NRP) discharge and a microwave discharge. The NRP reactor has been investigated for the dissociation of CO2. The microwave discharge has been used for studies of vibrational energy loading into N2 , as a first step towards the non-thermal synthesis of NO for fertilizer production. The complicated system that a non-equilibrium plasma represents requires sophisticated diagnostics. Such diagnostics have to be species specific and provide spatial and time resolved information about the quantities of interest, such as temperature (vibrational and rotational), product concentration and energy deposition. Given these require ments, diagnostics based upon the use of pulsed lasers are usually employed to study systems where fast kinetics are at play. The diagnostics of choice are Laser Induced Fluorescence (LIF) and vibrational Raman scattering.

This work shows that it is possible to fabricate phosphate-based planar wave-guides activated by rare earth ions both by sol-gel and RF-sputtering techniques. The objective of this thesis has been to evaluate various methodologies for fab-rication Phosphorous-based planar waveguides. In this context sol-gel and RF-sputtering techniques for planar waveguides fabrication has been investigated. RF-process has been optimized. In case of sol-gel technique a further thermo-dynamical study is required. Each of technique has drawbacks, in sol-gel method the principal question is related to the kinetics of the reaction, since it is too fast, to better control of the reaction rates, and better adjustment of the technological films fabrication, which effects on spectroscopic properties of the waveguiding systems: losses, refractive index. In case of RF-sputtering is no-ticeable that the refractive index is low, and the losses are less than 0.2 dB/cm, however the multicomponent target material increase the complexity of the structure.

The study presented in this thesis is focused on the investigation of Arsenic ultra-shallow distributions in Si for applications as source-drain extension dopant in CMOS technology. Using the Ultra-low energy SIMS measurements the evolution of arsenic shallow distribution was investigated with reference to the metastable electrical activation and the successive deactivation under moderate thermal treatment (550-700°C). Three different approaches to form As USJ were investigated to understand their physical mechanisms to verify their possible application in next generation microelectronics devices. First two activation approaches were based on low energy beamline ion implanted material. The first one is the low temperature (550°C) solid-phase epitaxial re-growth and the second activation approach is a sub-melt laser annealing at different temperatures. A range of deactivation studies was performed using these two classes of material with more attention given to the laser annealed ones. Plasma ion immersion implantation together with the LA was considered as the third approach of arsenic ultra-shallow junction formation. Samples created by AsH3+ plasma were investigated with respect to arsenic distribution, silicon oxide thickness and arsenic local order using SIMS, INAA, and EXAFS analysis.

As its title announces, the general aim of this doctoral thesis is to investigate the growth and use of nanostructured materials in order to make them suitable for sensoristics. Sensors applications have become very important in the last years because of a new sensibility towards pollution of the urban world and its effects on human health. Only very recently people and countries discovered the importance of environment preservation and monitoring. After a period of fast and uncontrolled industrial progress, we are now aware of this danger. Thus we need to monitor the environment and the changes which are happening directly or indirectly because of human presence. During the last decades, solid-state gas sensors have played an important role in environmental monitoring and chemical process control. The strong investigation which followed, made clear that the field of science and sensor technology cannot search for new sensor materials which are ideal, because different applications (e.g. different transformations of energy and different goals for sensors) require different materials. However materials are important drivers in sensor technology. The combination of the right materials (new or existing) to the right application can result in smarter, cheaper, or more reliable sensors. In order to give a contribution to this important evolving situation, during these three years the PhD candidate investigated two of the most important areas related to nanostructured materials used in sensing applications. On one side, the recent interesting field of metal oxide nanowires has been studied, both in terms of fundamentals (growth mechanism and structural properties) and sensor properties towards different gases. On the other side, the less exploited (in terms of sensor devices) field of organic thin films has been investigated, in terms of growth and fundamental properties (charge carriers mobility) which are required to use them as sensors. While nanostructured metal oxides are already in use in commercial sensors (usually in the form of porous thick or thin films), organic materials are still in a prototypal phase, and need further investigation in order to be effectively used. This different evolution step is reflected also in the present thesis: in which zinc and tin oxide nanowires are characterized as gas sensing devices, while molecular materials are only optimized towards a better order and a higher carrier mobility, which is one of the bottlenecks towards a higher response. For this reason, the chapters concerning metal oxide nanowires will give a wide picture, from their growth mechanism to their structure until their use (in different architectures) in sensing applications. Oxide nanowires have been used as passive (resistive) sensors (they have been used also as active sensors, but such data are still under analysis) both in order to develop new real sensors, and to better understand the sensing mechanism behind the high response of such nanostructured materials. Their nanoscale dimensions, comparable to the depletion layer, makes them almost ideal intrinsic on-off devices, and this can be exploited to fabricate a new generation of sensors characterized by a huge response. The problems of metal oxide sensors are however their poor selectivity and high working temperature. In this direction goes the investigation of the molecular materials. Concerning the organic complement in this thesis, the aim of the experimental work was the optimization of the overall field effect mobility of carriers (holes) along the whole device, which means several microns (tens of microns, due to the impossibility to use standard lithography techniques on organic delicate materials). This meant the minimization of grain boundaries, that are one of the steps hindering the charge carrier mobility, and even the recently found domain boundaries. Exploiting the high kinetic energy achievable by SuMBD, we found that it is partially transformed in surface mobility, increasing the order of the fundamental building blocks inside each monolayer, and decreasing the grain and domain boundary density (because of wider and less fractal grains). At the end of the thesis we will show a first combination of the two families of materials, just as a sample of what the exploitation of the best features of each family (high response for metal oxides and good selectivity for organic materials) can provide.

In this thesis we investigate the properties of impurities immersed in a dilute Bose gas at zero temperature using quantum Monte-Carlo methods. The interactions between bosons are modeled by a hard sphere potential with scattering length a, whereas the interactions between the impurity and the bosons are modeled by a short-range, square-well potential where both the sign and the strength of the scattering length b can be varied by adjusting the well depth. We calculate the binding energy, the effective mass and the pair correlation functions of a impurity along the attractive and the repulsive polaron branch. In particular, at the unitary limit of the impurity-bosons interaction, we find that the binding energy is much larger than the chemical potential of the bath signaling that many bosons dress the impurity thereby lowering its energy and increasing its effective mass. We characterize this state by calculating the bosons-boson pair correlation function and by investigating the dependence of the binding energy on the gas parameter of the bosonic bath. We also investigate the ground-state properties of M impurities in a Bose gas at T=0. In particular, the energy and the phase diagram by using both quantum Monte-Carlo and mean field methods.

In this thesis I present the construction of a new apparatus aimed at studying two-component Bose-Einstein condensates (BECs) in the presence of a Rabi coupling, where the two components correspond to internal states of sodium atoms. The coherent mixture, in the miscible regime, also exhibits a metastable excitation consisting in a domain wall of relative phase connecting vortices of different components. Due to the peculiar energy dependence of such a configuration, an attractive force, independent of the vortex distance, is expected, making this system a candidate for mimicking features of quark confinement in QCD. The surface tension of the domain wall structure can be experimentally controlled via the strength of the coupling, allowing to study the system dynamics in different regimes. These include a predicted regime in which, for sufficient high coupling strength, the domain wall breaks and new vortex couples nucleate, providing by itself an interesting experimental realization of spin counterflow dynamical instabilities in a superfluid system, as well as a phenomenon analogous to string breaking in QCD. The choice of sodium as atomic species is motivated by its collisional properties that allow to obtain a perfect spatial superposition between the two miscible components |F = ±1⟩ if trapped by a spin-independent potential, avoiding the known phenomenon of ’buoyancy’. Studying the dynamics of such systems for sufficiently long times, with a mixture subject to Zeeman differential energy shifts, requires a specific effort to remove magnetic field fluctuations: a rough estimate suggests that in order to maintain the system coherence for a sufficiently long time to study its dynamics, magnetic field fluctuations should be reduced by at least three orders of magnitude compared to typical values observed in laboratory environment. Such attenuations can be obtained by means of multiple layers of μ-metal, that is incompatible with the use of ordinary magnetic traps, characterized by large magnetic field gradients on the atoms, due to residual magnetization and saturation of the shielding material. To avoid such effects it is required to either evaporatively cool atoms into an optical dipole trap loaded from a molasses stage, or a hybrid approach by means of which atoms are transferred to a low-gradient quadrupole trap superimposed to the optical trap. Producing BECs with such protocols greatly benefits from an efficient optical molasses cooling stage to prepare the sample in the best conditions of temperature and density before loading atoms into the trap. With this regard, the main limitation of ordinary laser cooling techniques is their reliance on absorption and spontaneous emission cycles, which limits the lowest temperature and highest density that can be reached as a consequence of residual heating effects and photon-reabsorption. An important resource to cope with these limits are dark states. In a broader sense a dark state is a state which does not interact with the exciting light field, and an atom in such a state would be neither subject to the beneficial cooling effects nor to the detrimental effects of light scattering. It is possible, however, to exploit the phenomenon of electromagnetically induced transparency (EIT) to induce a velocity-selective cooling mechanism for which slower atoms, that do not need further cooling, are trapped in a dark state corresponding to a coherent superposition of atomic levels whose excitation probabilities interfere destructively, while the cooling mechanism still applies to the fastest atoms. Among these techniques, gray molasses cooling allows to reach temperatures as low as a few recoil temperatures, while retaining atomic densities useful to reach quantum degeneracy in the subsequent stages of the experiment. In order to exploit this technique, an additional laser source had to be implemented during my thesis. To realize a gray molasses on the sample only |F⟩ → |F − 1⟩ or |F⟩ → |F⟩ transitions can be chosen, requiring blue-detuned laser, in contrast to ordinary (sub)Doppler laser cooling techniques. Both these requirements rule out the use of the D2 transition used for ordinary laser cooling techniques, due to its finely-spaced hyperfine structure. On the other hand, the D1 transition is characterized by a broader level spacing in the hyperfine structure and the absence of higher energy states on the blue side of the |F = 2⟩ → |F' = 2⟩ transition. As part of the work for this thesis, I successfully implemented and characterized gray molasses cooling on the D1 optical line of sodium. The buildup of the new apparatus includes the assembly of a new laser source for laser trapping and cooling on the D2 line, the assembly of the optical table devoted to the frequency and amplitude control of all the laser beams involved in the optical laser cooling procedures as well as the electronic control system. Design and assembly of the UHV and baking procedures for the stainless steel vacuum chamber are also described as well as the laser cooling techniques employed to load the atoms in a Dark-Spot MOT. Regarding the production of BEC, various strategies were attempted for different dipole beam configurations. Dipole traps typically suffer from the tradeoff between capture volume and trap depth at a given power, while hybrid traps usually take advantage of a magnetic trap stage that would not be compatible with the μ-metal shielding. Preliminary attempts to reach quantum degeneracy after directly loading the dipole trap from molasses were unsuccessful due to spurious effects. An alternative approach based on a magnetic-shield compatible hybrid trap protocol, in the absence of magnetic trap compression, was successfully implemented.

Atomistic simulations based on Molecular Dynamics (MD) were used to model the lattice distortions in metallic nano-polycrystalline microstructures, with the purpose of supporting the analysis of the X-ray powder diffraction patterns with a better, atomic level understanding of the studied system. Complex microstructures were generated with a new modified Voronoi tessellation method which provides a direct relation between generation parameters and statistical properties of the resulting model. MD was used to equilibrate the system: the corresponding strain field was described both in the core and in surface regions of the different crystalline domains. New methods were developed to calculate the strain tensor at the atomic scale. Line Profile Analysis (LPA) was employed to retrieve the microstructure information (size and strain effects) from the powder diffraction patterns: a general algorithm with an atomic level resolution was developed to consider the size effects of crystalline domains of any arbitrary shape. The study provided a new point of view on the role of the grain boundary regions in nano-polycrystalline aggregates, exploring the interference effects between different domains and between grain boundary and crystalline regions. Usual concepts of solid mechanics were brought in the atomistic models to describe the strain effects on the powder diffraction pattern. To this purpose the new concept of Directional - Pair Distribution Function (D-PDF) was developed. D-PDFs calculated from equilibrated atomistic simulations provide a representation of the strain field which is directly comparable with the results of traditional LPA (e.g. Williamson-Hall plot and Warren-Averbach method). The D-PDF opens a new chapter in powder diffraction as new insights and a more sound interpretation of the results are made possible with this new approach to diffraction LPA.

Photocatalytic water splitting using solar energy could contribute to the solution of environmental and energy issues related to the hydrogen production. Key research area in this field is the development of photo-catalyst able to provide high energy conversion efficiency. TiO2 has been mostly preferred material as the photo-electrode due to many advantages, mainly related to the cost factor and stability. We have studied on hydrogen production by water splitting in photo-electrochemical cells prepared by using photoanodes made by two different kinds of TiO2: one deposited by RF sputtering and the other one by sol-gel method. Depositions were performed on electrical conducting ITO whose electrical properties plays vital role to reduce the photon energy loss. The photoanodes have been characterised by several techniques to infer on their optical and compositional properties. The observed differences in hydrogen production have been attributed to the peculiarities in absorption properties of the two TiO2 films that in the case of sputter-deposited films are more prone to absorb radiation also because of the produced defects during the deposition process. Metals like Cr and Fe were doped in TiO2 by RF magnetron sputtering and sol-gel methods to increase the efficiency of hydrogen production by water splitting by sensitizing the doped-TiO2 in visible light spectrum. The doping method, dopant concentration, charge transfer from metal dopants to TiO2, and type of dopants used for modification of TiO2 were investigated for their ability to enhance photocatalytic activity. UV-Visible spectra show that the sputter-metaldoped- TiO2 films are much more efficient than the chemically-prepared samples to induce red shift of the absorption edge for absorbing visible light. In addition, we proved that dopant atoms must be located, at low concentration, near the ITO-TiO2 interface to avoid the formation of recombination centers for photo-generated electron-hole pairs. H2 production rate is higher with Fe-doped TiO2 (15.5 μmole/h) than with Cr-doped TiO2 (5.3 μmole/h) because Fe ions trap both electrons and holes thus avoiding recombination. On the other hand, Cr can only trap one type of charge carrier. To increase the light conversion efficiency and reduce the recombination processes of Cr-doped TiO2, a multilayer structure of ITO/Cr-doped-TiO2 (9 at.%) was developed. When the multilayer films were exposed to visible light, we observed that the photocurrent increases as function of the number of bilayers by reaching the maximum with 6-bilayers of ITO/Crdoped-TiO2. The enhanced photocurrent is attributed to: 1) higher absorption of visible light by Cr-doped-TiO2, 2) number of space-charge layers in form of ITO/TiO2 interfaces in multilayer films, and 3) generation of photoelectrons just in/or near to the spacecharge layer by decreasing the Cr-doped-TiO2 layer thickness. The superior photocatalytic efficiency of the 6-bilayers film implies higher hydrogen production rate through water splitting: we obtained indeed 24.4 μmole/h of H2 production rate, a value about two times higher than that of pure TiO2 (12.5 μmole/h). Similar experiment we performed by doing TiO2 with vanadium metal. With 6-ilayers vanadium doped TiO2 film Shows higher hydrogen production rate of about 31.2 μmole/h. This rate is higher than that of CR doped and pure TiO2. A constant H2 generation rate is obtained for long periods of time by all the investigated TiO2 films because of the separate evolution of H2 and O2 gas, thus eliminating the back-reaction effect. Even Ar+ or N+ ion implantation of energy 30 keV was adopted to vary the energy band gap of TiO2 film in order to absorb visible light.The original anatase phase was not changed by implantation. Increase in full visible absorption range was observed for both kinds of ion implanted-TiO2 films which further increases with the ion fluencies, while N+ ion implantation also causes the shift of the absorption edge from UV to visible light range. N+ implanted TiO2 showed narrowing of band gap from 3.2 eV for untreated anatase TiO2 to 2.78 eV for maximum implantation dose. The Ar+ and N+ implantation creates oxygen vacancies related defect energy level in the band gap. In case of N+ implantation, nitrogen also substitutionally replaces the oxygen atoms thus forming an energy level just above the valence band which further interacts with O 2p states resulting in the narrowing of band gap. The black solar absorber material develop over the copper target to absorb concentrated solar radiation and supply heat to the surrounding water. A black copper oxide layer was synthesized over copper substrate by using chemical oxidation treatment. We varied several treatment parameters and optimized the best condition to obtain a black textured layer which has the properties to absorb total solar radiation. The untreated polished copper showed 50 to 60 % reflectance (R) (incidence angle of 15o) and this value decreases to almost zero for whole wavelength range after formation of black copper oxide. The percentage absorption decreases by negligible amount as the angle of incidence increases. The SEM images of the copper oxide layer at high magnification showed a nano-petal like structure which causes the surface texture effect for higher absorption where surface irregularities such as grooves and pores with dimensions similar to the wavelength of the incident radiation simply increase the solar absorptance by multiple reflections. Long time thermal stability and corrosion resistance in hot water was also studied for the copper oxide film. The results revealed that the copper oxide was very stable and showed no changes in optical properties after the test. For the same water heating system a quartz window is used through which the solar radiation is transmitted on the copper target. Thus to acquire high power conversion efficiency it is necessary for quartz window to transmit the entire solar radiation incident on it without much lost due to the reflection on the surface. In general quartz window is able to transmit 90-91 % of the solar radiation while 1-2 % is absorbed and 7-8 % is reflected from the surface. Thus to have nearly complete transmittance it is necessary to cover the surface of quartz window with anti-reflecting (AR) coating: this was the part of my work. We developed single-layer and multi-layer AR coating for single specific wavelength and broad-band wavelength range respectively. Low reflective index material like MgF2 is deposited by e-beam technique to obtain single-layer AR coating. While Al2O3 and ZrO2 layers deposited, by RF-magnetron sputtering, on top of MgF2 forms multi-layer AR coating. The combination of MgF2/ZrO2/Al2O3/MgF2 deposited on both side of quartz showed excellent results with reflectance value of around 0.8% in broad spectral range. The heat exchanger efficiency obtained after using these developed black copper oxide absorber material and AR coating is around 83 % which seems to be significantly higher than the other commercially available water heating system. Concentrating solar power (CSP) systems are utilized to convert sunlight to thermal electric power by using solar absorber. However, the solar absorber are operated at elevated temperature (700-800 oC) and should be spectrally selective to act as perfect absorbers over the solar spectrum (high solar absorptance (α)) and perfect reflectors in the thermal infrared (IR) (low thermal emittance (ε)). Cermet composite solar absorber shows such selective properties at high temperatures. In the present work, we developed Al-AlN based multilayer cermet films by RF magnetron sputtering. We choose combination of Ni/AlxN(1-x)/AlN layers as a solar absorber due to its stability at elevated temperature and high corrosion resistance. In this combination, Ni layer, deposited near to substrate, act as the IR light reflector to provide high thermal emittance. While AlxN(1-x) layer act as an absorber layer for UV-Vis spectrum of solar radiation and transparent AlN layer on top functions as AR coating. To improve absorptance, 3 or 4 layers of AlxN(1-x) film with grading of metal content was synthesized by varying N2 flow during deposition. The optical measurement for these multilayer selective absorber films showed high solar absorptance of 0.92-0.96 and low thermal emittance of around 0.1-0.07. To test the stability of our multilayer coating at high temperature, we annealed these samples at 700 oC with holding time of 2 hrs in air, low vacuum and high vacuum. We observed a slight decrease in solar absorptance value (0.90) for the annealed samples but the results showed that overall performance was not hindered by heat treatment thus proving the thermal stability of our multilayer cermet coating.

In this work we develop Quantum Monte Carlo techniques suitable for exploring both ground state and dynamical properties of interacting many-body systems. We then apply these techniques to the study of excitations in superfluid He4 and to explore the structure of nuclear systems using chiral effective field theory interactions.