Ni50.6Ti49.4 single and Ni52Ti48 polycrystalline shape memory alloy samples were subjected to aging under a uniaxial stress, to form a single Ni4Ti3 precipitate variant and to investigate the effects of single versus multi-variant coherent precipitates on the shape memory characteristics including two-way shape memory effect (TWSME). Shape memory and superelasticity properties along with the effects of stress and temperature on the transformation temperatures, strain, hysteresis, dimensional stability, and R-phase formation were investigated. This was accomplished through the use of isobaric thermal cycling and superelasticity experiments and various microscopy techniques that included transmission electron microscopy (TEM), scanning electron microscopy, and optical microcopy. The results showed that it is feasible to use constrained aging to bias R-phase martensite variants upon cooling from austenite without any external stress, however, accomplishing this with B19’martensite was much harder as complete TWSME was only found in the Ni50.6Ti49.4 single crystalline sample oriented along the [112] direction. The onset of irrecoverable strain corresponded to the R-phase temperature hysteresis increase in the single crystalline samples regardless of the aging conditions. Through TEM analysis it was discovered that [112] and [114] twins were found in austenite due to plastic deformation of martensite during the superelasticity experiments. Since [112] twins are theoretically impossible to form in austenite, and since martensite was plastically deformed, [112] austenite twins were attributed to the transformation of compound twins in martensite, in particular [113] martensite twins formed during the plastic deformation of martensite, into austenite twins. In the Ni52Ti48 polycrystalline samples, a compressive R-phase variant was biased through constrained aging under 100 and 200 MPa uniaxial tensile stresses at 400°C and 450°C. Aging, in all conditions, produced a high density of Ni4Ti3 precipitates that was most likely responsible for the small transformation strain observed, less that 2%, upon transformation to martensite. In the future, samples with compositions between 50.8 and 51.5 Ni atomic percent, in addition to altered solution and aging heat treatments as compared to those used in this study should be investigated as it is believed that samples with these compositions will yield better and consistent TWSME responses through constrained aging.

Ni-Mn-Ga is a ferromagnetic shape memory alloy that can be used for future sensors and actuators. It has been shown that magnetic field can induce phase transformation and consequently large strain in stoichiometric Ni2MnGa. Since then considerable progress has been made in understanding the underlying science of shape memory and ferromagnetic shape memory in bulk materials. Ni-Mn-Ga thin films, however is a relatively under explored area. Ferromagnetic shape memory alloy thin films are conceived as the future MEMS sensor and actuator materials. With a 9.5 percent strain rate reported from magnetic reorientation, Ni-Mn-Ga thin films hold great promise as actuator materials. Thin films come with a number of advantages and challenges as compared to their bulk counterparts. While properties like mechanical strength, uniformity are much better in thin film form, high stress and constraint from the substrate pose a significant challenge for reorientation and shape memory behavior. In either case, it is very important to understand their behavior and examine their properties. This thesis is an effort to contribute to the literature of Ni-Mn-Ga thin films as ferromagnetic shape memory alloys. The focus of this project is to develop a recipe for fabricating NiMnGa thin films with desired composition and microstructure and hence unique properties for future MEMS actuator materials and characterize their properties to aid better understanding of their behavior. In this project NiMnGa thin films have been fabricated using magnetron sputtering on a variety of substrates. Magnetron sputtering technique allows us to tailor the composition of films which is crucial for controlling the phase transformation properties of NiMnGa films. The composition is tailored by varying several deposition parameters. Microstructure of the films has been investigated by X-ray diffraction (XRD) and transmission electron microscopy (TEM) techniques. Mechanical properties of as-deposited films have been probed using nano-indentation technique. The chemistry of sputtered films is determined quantitatively by wavelength dispersive X-ray spectroscopy (WDS). Phase transformation is studied by using a combination of differential scanning calorimetry (DSC), in-situ heating in TEM and in-situ XRD instruments. Magnetic properties of films are examined using superconducting quantum interface device (SQUID).

Thesis (Ph.D.)--City University of Hong Kong, 2009. / "Submitted to Department of Mathematics in partial fulfillment of the requirements for the degree of Doctor of Philosophy." Includes bibliographical references (leaves [214]-224)

Thesis (Ph. D.)--University of Washington, 2000. / Vita. Includes bibliographical references (leaves 249-257).

No description available.

An electro-mechanical device was developed to provide mechanical stimulation to cell populations for the purpose of studying how mechanical signals affect cell activity. The system can dynamically deform cubes of hydrogel seeded with cells by applying combinations of normal and shear forces to the faces of the hydrogel cube using plastic pads attached to the cube. The compact device was fabricated using rapid prototyping methods with ABS plastic and uses shape memory alloy actuator wires to generate the necessary forces. The actuator wires can be independently activated in sequence to create stimulation routines involving compression, tension and shear forces. All of the components can be sterilized and are corrosion resistant so they are not affected by the high humidity environment of a tissue incubator where cell stimulation studies are performed. The system fits inside a standard plastic lab container measuring 7 cm tall by 4 cm in diameter to maintain sterile conditions and hold the liquid culture medium required by the cells. During operation the hydrogel cube and the contact pads are submerged in the culture medium. The shape memory alloy actuators have been modeled in a two step process: 1) the electrothermal model, relating input electrical current to the wire temperature due to resistive heating and 2) the thermomechanical model relating the wire temperature to the wire strain and actuator stroke due to the shape memory effect. Testing was completed to validate the models and calibrate the shape memory alloy actuators. There was good agreement between the model predictions and the experimental results. For experiments with a hydrogel cube with sides measuring 1 cm, the system was capable of compressing the hydrogel cube up to 8 %, and generating shear strains of up to 7%. Tensile strains were much smaller at 0.9%. The dynamic deformations were applied at a frequency of 0.5 Hz. / Thesis (Master, Mechanical and Materials Engineering) -- Queen's University, 2008-08-12 10:23:15.672

No description available.

The development of active 'smart materials', which are materials that can change their physical properties when subject to an external stimulus such as a thermal, mechanical or magnetic energy, are expected to significantly enhance technology developments in future years. These new materials can be integrated into existing technologies to increase efficiency, performance, durability and size reduction.

Thesis (Ph.D.)--University of Central Florida, 2007. / Adviser: Raj Vaidyanathan. Includes bibliographical references (p. 115-120). Also available in print.

Thesis (M.S.V.)--University of Toledo, 2004. / Typescript. "A thesis [submitted] as partial fulfillment of the requirements of the Master of Science degree in Civil Engineering." Includes bibliographical references (leaves 63-64).