Normal shock problems in high enthalpy flows are of special interests to aerodynamicists and fluid dynamicists. When the shock Mach number become hypersonic and increasing further, the gas passing through the shock is compressed resulting in increase in temperature and pressure. As the Mach number increases the internal degrees of freedom of the diatomic molecules are activated to an increasing extent when it crosses the shock resulting dissociation especially for high enthalpy flows. Hence dissociation of diatomic molecules must be taken into account in the determination of some of the aerodynamic parameters. This thermal and chemical process can be divided into three types such as nearly frozen, non-equilibrium and nearly non-equilibrium depending on the rates of reaction and excitation. For typical re-entry conditions of spacecrafts into a planets atmosphere, dissociation reactions of the molecules is dominant in the stagnation flow. Further in the stagnation region of the flow field one of the most important parameter that characterizes the flow field is the shock stand-off distance. This parameter is often employed for validation purposes of numerical methods as well as for non-reactive and reactive gases. For high Mach number flows the shock is very close to the body hence experimental determination of shock stand-off distance is very difficult and there would be relatively large errors. Therefore the theoretical determination of this parameter is of great significance in the discussion of this physical phenomenon. There are some works which presents how the dissociation behind shock affects the shock stand-off distance. Thus the dissociation behind the shock is a very important process which has great impact in aerodynamic flight and design. In this present work we studied how dissociation of diatoms occur behind a normal shock. Treanor and Marrone (1962) proposed CVD(coupled vibration-dissociation) model for diatoms by assuming diatom as a harmonic oscillator with a cut-off level. But actually diatoms are not harmonic oscillator, because spectroscopic data of energy level spacing is not like harmonic oscillator. For this reason, Treanor, Rich, and Rehm(1968) used anharmonic oscillator model for diatoms to study vibrational relaxation. Taking the anharmonicity of diatom, Philip Morse(1929) gave a formula for potential energy levels for diatoms, which is known to express the experimental values quite accurately. Unlike the energy levels of the harmonic oscillator potential, which are evenly spaced , the Morse potential level spacing decreases as the energy approaches the dissociation energy and then it is continuous. So it is quite accurate to take Morse oscillator theory for diatomic dissociation instead of harmonic oscillator with a cut-off level. We have used Morse oscillator theory to derive a dissociation-recombination reaction rate equation for diatom. To derive the rate equation we have used the transition probability between different vibrational energy levels . The rate equation is numerically solved to get the different flow variables behind the shock. The result of the present work has been compared with some of the previous work. Some of the flow variables are well matching with the previous work and some has discrepancy near the shock but well matching after few distance from the shock. We have also studied under what conditions the post shock flow shows self-similar behavior in its scaling relations. It is shown that as far as there is no dissociation, we could expect to obtain self-similar solutions. However, when there is dissociation, the non-equillibrium nature of the phenomenon disrupts the self-similar nature of the flow.

Sequences coding for three related 16 kd heat shock proteins (hsps) of the nematode Caenorhabditis elegans were isolated and characterized. The extensive accumulation of hsp16 mRNA during heat stress facilitated the identification of two cDNAs, CEHS48 and CEHS41, which encoded hsp16 variants. These plasmids were selected by their ability to hybridize to mRNA which directed the synthesis of hspl6 in vitro, and were further characterized by sequence analysis. Two-dimensional gel electrophoresis of hspl6 synthesized in vitro from mRNA selected by hybridization to either of the cDNAs under conditions of low stringency revealed the existence of at least five electrophoretic variants with significantly different isoelectric points. The above cDNAs were used as specific probes to isolate recombinant bacteriophage containing C. elegans genomic DNA. Overlapping phage clones were used to define a region of approximately 30 kilobases. The genes coding for hsp16-48, previously identified by cDNA cloning, and for another 16 kd hsp designated hspl6-l were characterized by DNA sequencing. These two genes were arranged in a head-to-head orientation. Both the coding and flanking regions of these genes were located within a 1.9 kb region which was duplicated exactly to form a perfect 3.8 kb inverted repeat structure. This structure ended in unusual G + C-rich sequences 24 bp in length. The identity of the two arms of the inverted repeat at the nucleotide sequence level implied that the duplication event may have occurred relatively recently in evolution. Alternatively, gene conversion between the two modules could have maintained homology between the two gene pairs. Comparison of the hsp16-48 gene with its corresponding cDNA revealed the presence of a single, short intron. An intron of comparable length and in an analogous position was also found in the hsp16-1 gene. The introns separated variable and conserved regions within the amino acid sequences of the encoded heat shock proteins. A domain of approximatey 80 amino acids is contained within the conserved second exon and is homologous to a similar region in the small hsps of Drosophila, Xenopus, soybean and man as well as the a-crystallin protein of the vertebrate lens. Each hsp16 gene contained a TATA box upstream of the start of transcription. Promoter sequences, which have been shown to be required for heat inducibility in various systems, were located upstream of either TATA box Northern blot analysis showed that the hsp16-48 and hsp16-1 genes are expressed at levels approximately 20 - 40 fold lower than two closely related genes, hsp16-41 and hsp16-2, upon temperature elevation. / Medicine, Faculty of / Biochemistry and Molecular Biology, Department of / Graduate

Shock waves in reactive media possess very rich dynamics: from formation of cells in multiple dimensions to oscillating shock fronts in one-dimension. Because of the extreme complexity of the equations of combustion theory, most of the current understanding of unstable detonation waves relies on extensive numerical simulations of the reactive compressible Euler/Navier-Stokes equations. Attempts at a simplified theory have been made in the past, most of which are very successful in describing steady detonation waves. In this work we focus on obtaining simplified theories capable of capturing not only the steady, but also the unsteady behavior of detonation waves. The first part of this thesis is focused on qualitative theories of detonation, where ad hoc models are proposed and analyzed. We show that equations as simple as a forced Burgers equation can capture most of the complex phenomena observed in detonations. In the second part of this thesis we focus on rational theories, and derive a weakly nonlinear model of multi-dimensional detonations. We also show, by analysis and numerical simulations, that the asymptotic equations provide good quantitative predictions.

When a shock interacts with a bubble having a different density than the environment or medium, the interaction causes compression and deformation of the bubble and generation of a vortex pair. Later, secondary vortices appear causing enhanced mixing. The enhanced mixing induced by the shock bubble interactions is particularly of interest in supersonic combustion and detonation. The Wavelet Adaptive Multi-resolution Representation (WAMR) method is particularly suitable for challenging continuum physics problems like shock bubble interaction, which has strong multi-scale character. This method provides an efficient strategy to create a dynamically adaptive spatial grid and to obtain a verified solution. Since the wavelet amplitude provides a first-hand estimate of the local error at each point, the method is able to efficiently capture a wide spectrum of spatial scales by dynamically changing the adaptive grid. Highly resolved computations are done only in the regions where abrupt transition occurs. In this work a detailed investigation of Shock Bubble Interaction (SBI) is carried out using shocks having Mach numbers from 1.2 to 3 for helium, nitrogen and krypton bubbles. Simulations carried out using WAMR method were used to analyze the effects of Mach number and density contrast on the shape, location and velocity of the bubble as well as vorticity and pressure in the flow field.

Increasingly stringent legislations call for more efficient and cleaner combustion technology as well as sustainable fuels. Chemical kinetic models are required in designing and optimizing novel engine concepts as well as selecting appropriate renewable fuels. Among the many reactions controlling fuel reactivity, OH + Fuel elementary reaction is one of the most important reactions that plays a critical role from low to high temperatures. In this thesis, OH + Fuel elementary reactions are studied for a wide spectrum of conventional and renewable fuels. The overall rate coefficients are measured in a shock tube using OH time-history profiles recorded with a UV laser diagnostic. Alkanes constitute important components of gasoline and diesel. Overall rate coefficients are measured for a series of large branched alkanes and the rate rules are derived based on the next-nearest-neighbor classification method. The strength of this method lies in the ability to predict the rate coefficients for large and/or highly-branched alkanes, where both experiments and theoretical calculations are hard to reach. Next, OH reactions with bio-derived fuels, methanol and cyclic-ketones, are studied. For OH + methanol reaction, site-specific contributions from different C-H bonds are quantified using deuterium kinetic isotopic effect, and the measured rate coefficients are found to improve the general behavior of a detailed methanol kinetic model. Reactions of cyclic ketones with OH radicals are found to exhibit similar reactivity as those of similar carbon length acyclic ketones + OH reactions. Acetaldehyde is one of the most abundant hazardous byproducts in the combustion of various fuels. Similar to methanol, OH + acetaldehyde reaction is 4 studied at the site-specific level and the importance of competing reaction channels are quantified at high temperatures. Finally, reactions of OH + cyclohexadienes and OH + trimethylbenzenes, relevant for the fate of polycyclic aromatics hydrocarbons, are investigated. A highly complex temperature dependence is observed for these molecules, a six-parameter Arrhenius expression is needed to describe the overall reactivity. The work reported in this thesis provides elementary reaction data that are highly valuable for increasing the fidelity and accuracy of predictive chemical kinetic models.

In this work, MEMS inertial switches intended to be triggered at multiple acceleration thresholds in two directions were implemented and proven effective. The switches consume virtually no power in their open switching state. Multiple acceleration thresholds can be beneficial in triggering different actions for different acceleration events. Low power consumption can aid in their use for portable applications such as in cycling helmets. The developed designs rely mainly on a suspended shuttle mass, which is used to implement one of two methods of actuation. The first relies on simple contact between the moving shuttle mass and a flexible electrode. In the second, the pull-in instability is induced by applying a voltage between a cantilever and an electrode, and then having the shuttle mass force the cantilever moving towards the electrode as it moves under the applied acceleration. Ten designs varying in their actuation method, suspension design, intended acceleration thresholds, and dimensions were modeled using a finite element model, fabricated, through the SOIMUMPs process, and then electrically and mechanically tested. Mechanical testing has been conducted using Drop-table tests and mechanical shakers. The simple contact devices were proven effective through shock test results showing triggering at two acceleration thresholds in two directions. Initial results also were promising for the pull-in based devices showing switching by moving their shuttle mass with a probe while applying appropriate voltage and observing under a microscope.

An aim of the given thesis is creating of a computational model of strain-stress behaviour of shock absorbers made of plastic and hyperelastic material. First step is get ecquaint with theory of large strains, theory of hyperelasticity and plasticity. Next step is get ecquaint with options of commercial programs based on MKP. Based on this knowledge, models of simple shock absorber are made. With created models, crash tests are simulated and property of shock absorbers are compared.

This Diploma thesis deals with the design of facilities for measuring characteristics of the cars shock absorbers. It describes damped vibration, construction design of shock absorbers and their diagnostics methods followed by description of shock absorbers characteristics and the design of linear motor driven device.

De nos jours, la sécurité des installations publiques, industrielles ou militaires est une problématique majeure. Les phénomènes de détonations en champ libre sont bien connus et documentés. Néanmoins les modèles et les lois mises en place ne s’appliquent pas dans le cas d’explosions confinées.Les travaux présentés dans ce mémoire de thèse portent sur l’étude de la propagation des ondes de choc dans des géométries simples et fermées. Différents paramètres ont été étudiés tels que l’influence du volume, de la position d’amorçage ou encore de la taille de l’évent.Les essais réalisés à petite échelle, dans deux maquettes expérimentales ont permis de mettre en place des lois prédictives portant sur les principaux paramètres de l’onde de choc incidente et réfléchie que sont la surpression maximale, le temps d’arrivée ainsi que l’impulsion.Ces lois ont ensuite été implémentées dans un code de calculs permettant d’automatiser la recherche des réflexions et des différents paramètres associés dans des configurations géométriques simples. / Nowadays, the security of public, industrial or military area is a major concern. Free-field blast are well known and documented. Nevertheless, the models and laws developed do not apply in case of confined explosions. The study focuses on the propagation of shock waves in simple closed geometries. Various parameters have been studied such as the volume, the charge position or the size of vents. The small scales experiments carried out in two experimental models, made it possible to set up predictive laws on the main parameters of the incident and reflective shock wave, such as the maximum overpressure, the arrival time and the impulse.These laws were then implemented in a calculation program to automate the search of reflections and associated parameters in simple geometric setup.

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