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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Phase Behavior of Multiresponsive Microgel Dispersions

Debord, Saet Byul 01 December 2005 (has links)
We present the phase behavior of soft sphere colloidal dispersions. The pH responsive and thermoresponsive microgels, poly(N-isopropylacrylamide-co-acrylic acid) (pNIPAm-co-AAc), were used as a new building block of colloidal crystals. The phase behavior of microgel dispersions was studied by different methods such as optical microscopy, particle trajectories, mean squared displacement (MSD) vs. lag time plots and radial distribution function. The results show that the phase of the sample relies on the particle concentration for dispersions of the same pH. As the pH approaches the pKa of microgels, the microgel dispersions show unusual crystalline phase at lower effective volume fraction than hard sphere melting transition. Also, at this pH regime, the microgel dispersions undergo slow and spatially heterogeneous crystal growth. The cooperative multi-body type attractive forces were proposed to explain the unusual stability at low effective volume fraction. Ion-dipole interactions were proposed to be the origin of the attractive forces. The melting point of bulk crystals at this pH regime is much higher than the volume phase transition temperature of the building block. These results are supportive of the attractive forces hypothesis.

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