Thesis (M.S.- Hydrology)--University of Arizona. / Includes bibliographical references (leaves 190-198).

Thesis (M.S.)--Ohio State University, 1955. / Includes bibliographical references (leaves 41-42). Available online via OhioLINK's ETD Center

Thesis (M.S. - Soil and Water Science)--University of Arizona, 1984. / Includes bibliographical references (leaves 63-66).

Thesis (M.S.)--Virginia Polytechnic Institute, 1951. / Vita. Includes bibliographical references (leaves 56-58). Also available via the Internet.

Thesis (Ph. D.)--University of Minnesota, 1924. / Biographical sketch. "Literature cited": leaves 85-88.

Thesis (Ph. D.)--University of Minnesota, 1924. / Biographical sketch. "Literature cited": leaves 85-88.

A major uncertainty in soil carbon studies is how inputs of fresh plant-derived carbon affect the turnover of existing soil organic matter (SOM) by so-called priming effects. Priming may occur directly as a result of nutrient mining by existing microbial communities, or indirectly via microbial population adjustments. Soil type and conditions may also influence the intensity and direction of priming effects. However the mechanisms are poorly understood. The objectives of this study were (1) to investigate how additions of labile C4 substrate affected SOM turnover in two contrasting unplanted C3 soils (clayey fertile from Temple Balsall, Warwickshire (TB) and sandy acid from Shuttleworth, Bedfordshire (SH) using13 C isotope shifts; (2) to investigate the influence of rhizodeposition from plant roots on SOM turnover in the same two soils planted with a C4 grass; (3) to assess an automated field system for measuring soil temperature, moisture and photosynthesis sensitivities of SOM turnover in the same two soils over diurnal to seasonal time scales. I used a combination of laboratory incubation, glasshouse and field experiments. In the soil incubation experiment, I made daily applications of either a maize root extract or sucrose to soil microcosms at rates simulating grassland rhizodeposition, and followed soil respiration (Rs) and its δ13 C over 19 days. I inferred the extent of priming from the δ13 C of Rs and the δ13 C of substrate and soil end-members. There were positive priming effects in both soils in response to the two substrates. In the SH soil there were no differences in priming effects between the substrates. However in the TB soil, sucrose produced greater priming effects than maize root extract, and priming effects with sucrose increased over time whereas with maize root extract declined after the first week. I explain these effects in terms of the greater fertility of the TB soil and resulting greater microbial nitrogen mineralization induced by priming. Because the maize root extract contained some nitrogen, over time microbial nitrogen requirements were satisfied without priming whereas with sucrose the nitrogen demand increased over time. In the glasshouse experiment, I planted C4 Kikuyu grass (Pennisetum clandestinum) in pots with the same two soils. The extent of rhizodeposition by the plants was altered by intermittently clipping the grass in half the pots (there were also unplanted controls) and priming effects were inferred from the δ13 C of Rs and the δ13 C of plant and soil end-members. Unclipped plants in both soils generated positive priming effects, while clipping reduced priming in TB soil and produced negligible PEs in SH soil. Microbial nutrient mining of SOM again explained the observed PEs in this experiment. Photosynthesis was a major driver of priming effects in the planted systems. In the third experiment, I found that the tested automated chamber system provided reliable measurements of Rs and net ecosystem exchange (NEE), and it was possible to draw relations for the dependency of Rs and NEE on key environmental drivers. Collectively, the results contribute to a better understanding of the mechanisms of priming effects and highlight possibilities for further research. The methods developed here will allow high temporal and spatial resolution measurements of Rs and NEE under field conditions, using stable isotope methods to separate fluxes into plant- and soil-derived components. Keywords: Soil respiration, soil moisture, soil temperature, Isotope ratio, maize root, flux chamber, climate change, organic matter, rhizodeposition.

Research Doctorate - Doctor of Philosophy (PhD) / Amidst growing concerns about global warming, efforts to reduce atmospheric CO2 concentrations (i.e. C sequestration) have received widespread attention. One approach to C sequestration is to increase the amount of C stored in terrestrial ecosystems, through improved land management. Terrestrial ecosystems represent a critical element of the C interchange system, however a lack of understanding of the C cycle at regional and sub-regional scales means that they represent a source of primary uncertainty in the overall C budget. This thesis aims to address this deficiency by developing an understanding of catchment-scale processes critical for accurate quantification of C in the landscape. An investigation into the spatial and temporal dynamics of soil organic carbon (SOC) was conducted for a 150ha temperate grassland catchment in the Upper Hunter Valley, New South Wales, Australia. The major factors controlling the movement, storage, and loss of SOC were investigated, including climate, vegetation cover, soil redistribution processes, topography, land use, and soil type. This study falls into four broad areas. In the first part of this study the spatio-temporal dynamics of soil moisture and temperature at the catchment scale are assessed for a range of soil depths. Data recorded from a network of monitoring sites located throughout the study catchment was compared with independently derived soil moisture and temperature data sets. The data indicates that soil moisture and temperature in surface soil layers were highly dynamic, in their response to rainfall and incoming solar radiation, respectively. Deeper soil layers however were less dynamic, with longer lag times observed with increasing soil depth, as topography, soil type, and landscape position were the dominant controlling factors. Climate related variables are important factors affecting plant growth and net primary productivity. The second part of the study quantified spatial and temporal vegetation patterns using both field-based measurements of above-ground biomass and remotely sensed vegetation indices from the MODIS and Landsat TM 5 platforms. A strong and statistically significant relationship was found between climate variables and MODIS derived NDVI, leading to the development of a predictive vegetation cover model using ground-based soil moisture, soil temperature, and sunshine hours data. The ability of remotely sensed data to capture vegetation spatial patterns was found to be limited, while it was found to be a good predictor of temporal above-ground biomass trends, enabling net primary productivity to be quantified over the three-year study period. In the third part of the thesis soil redistribution patterns and erosion rates were quantified using the caesium-137 method and empirical and physically-based modelling approaches. The impact of soil redistribution processes on SOC distribution was investigated, and the amount of erosion derived SOC loss quantified. A significant proportion of SOC stored within the catchment was found below a soil depth of 0.30m, which is the depth of sampling set out in the IPCC and Australian Greenhouse Office guidelines for carbon accounting. Soil depth was identified as a key factor controlling the spatial distribution of SOC, which is in turn determined by position in the landscape (i.e. topography). The fourth and final part of the study describes how data on erosion derived SOC loss were used in conjunction with net primary productivity estimates, to establish a SOC balance. This involved mapping the spatial distribution of SOC using a high resolution digital elevation model of the catchment, in conjunction with soil depth measurements, and quantifying the total SOC store of the catchment. It was observed that temporal changes in SOC were minimal over the limited three-year study period, however, the continuity of catchment management practices over the previous decades suggest that steady-state conditions have perhaps been reached. The study concludes that the key to increasing the amount of SOC and enhancing carbon sequestration in the soil, is to increase the amount of SOC stored at depth within the soil profile, where factors such as soil moisture and temperature, which control decomposition rates, are less dynamic in space and time, and where SOC concentrations will be less vulnerable to changes occurring at the surface in response to global warming and climate change.

Ce travail de thèse propose une méthodologie d’instrumentation reposant sur plusieurs outils hydrologiques, géophysiques et géochimiques afin de quantifier l’apport nival dans les débits du Lignon. Cette instrumentation consiste en un suivi des échanges aux différents compartiments/interfaces hydrologiques que forment l’atmosphère, la neige, le sol et les cours d’eau au cours des saisons. La neige, et surtout l’équivalent en eau liquide qu’elle représente, est fondamentale pour la compréhension du fonctionnement des sources du Lignon, situées à l’aval direct d’une congère de grand volume. Ce volume d’eau est stocké durant la saison froide pour être restitué lors de la fonte printanière. Cette restitution est loin d’être homogène dans le Haut Lignon, en raison de la forte variabilité spatio-temporelle des paramètres qui la pilotent.L’infiltration de l’eau alors produite est une étape clef dans le comportement hydrologique du Lignon au printemps. La structure du sol à proximité des sources explique également la forte dépendance des sources du Lignon par rapport aux précipitations neigeuses. Cette dépendance est particulièrement visible lors de la fonte de la neige, qui modifie à très court terme les débits aux sources. Cette relation neige-pluie-débit met en évidence une alimentation superficielle pluvio-neigeuse prépondérante par rapport aux débits issus d’eau plus profonde, mais variable au cours de l’année.La méthode d’instrumentation employée, adaptée à l’hydrologie locale employée, permet de corroborer les résultats obtenus avec une précision appréciable, tout en ouvrant de nouvelles perspectives d’application à d’autres bassins versants d’altitude. / This work proposes a methodology for an instrumentation based on several hydrological, geophysical and geochemical tools, to quantify the contribution of snowmelting proportions in the Lignon. This instrumentation is a monitoring of the different compartments / hydrological interfaces made up by atmosphere, snow, soil and rivers throughout the seasons.Snow, and especially the snow water equivalent, is fundamental to a better hydrological understanding of the sources of the Lignon, located directly downstream of a large snowdrift. This amount of water is stored during the cold season, to be returned during the spring melting. This return is heterogeneous in the top of the Lignon, due to the high spatial and temporal variability of parameters leading the melting.The infiltration of water therefore produced is a key step in the hydrological behavior of the Lignon during the spring time, which can be potentially more affected by the freezing of the ground, which significantly increases surface runoff.Soil structure near sources also explains the strong dependence of the sources of the Lignon towards snowfalls and rains. This dependence is especially noticeable at the snow melting that changes with very short term the flows at the sources.This snow-rainfall-runoff relationship highlights a predominant rain-snow surface supply, in comparison with the deeper water flows, and variable during the year.This instrumentation method, adapted to the local scale hydrology, allows corroborating the results obtained with a good accuracy, while opening new opportunities for application to other altitude watersheds.