Yes / Natural rubber (NR) and crosslinked polyethylene (XLPE) waste streams were devulcanized by solid state shear milling (S3M), producing a fine powder that may be more easily reprocessed. Understanding devulcanization and the nature of decrosslinked thermoset materials is of utmost importance for turning these waste steams into functional products. It was found that the devulcanized powders contained significant concentrations of radicals, which may be active in the subsequent revulcanization process. The produced devulcanized powders were converted into recyclable thermoplastic vulcanizates (TPVs) by twin screw extrusion. Reprocessing of these powders into value-added products is an important step in recycling and the use of extrusion allows for high throughput and industrial viability. Herein, we demonstrate that the optimal conditions for reprocessing are dependent upon the particle size of the devulcanized powder. Furthermore, dynamic vulcanization is affected by the nature of these recyclate powders. The successfully prepared TPVs showed similar properties to virgin materials, with a high elongation to failure. Therefore, the conversion of waste rubber into the rubber phase of a TPV shows significant promise in moving towards sustainable products, providing the revulcanization step can be well controlled. / EPSRC and NSFC for their funding of this work through the Joint UK-China Low Carbon Manufacturing Grant, Grant number EP/S018573/1.

Yes / Solid state shear milling (S3M) is reported as a scalable, continuous, polymer-assisted cocrystallization technique. A specially designed milling pan was employed to provide high levels of applied shear, and the addition of a polymeric processing aid enabled generation of high stress fields. Carbamazepine–salicylic acid cocrystals were produced with 5–25 wt % of poly(ethylene oxide) (PEO). A systematic study was carried out to understand the effect of process variables on properties and performance of the cocrystals. S3M offers an important new route for continuous manufacturing of pharmaceutical cocrystals.