Master of Science / Geology / Matthew W. Totten / Mississippian chert reservoirs, also known as chat reservoirs among the mid-continent in Kansas and northern Oklahoma, produce an abundant amount of hydrocarbons. Since the 1920s, chat reservoirs in Kansas have yielded over 380 million bbl of oil and 2.3 tcf of natural gas. The largest Mississippian field in south-central Kansas is the Spivey-Grabs, which spans Kingman and Harper Counties. Development of the Spivey-Grabs Mississippian reservoir, and continued production within the field, has been compromised by compartmentalization within the field, resulting in unpredictable producing rates. Previous research has investigated the differences of the fluids within the separate compartments (Evans, 2011; Kwasny, 2015), and identified the existence of at least two oil types of differing viscosity (Kwasny, 2015). The objective of this research was to determine whether the compartmentalization of the reservoir is controlled by the different lithologic characteristics between the various compartments. This was accomplished by examining drill cuttings under binocular microscope, under a petrographic microscope using digital imaging software, and under the high magnification of a scanning electron microscope. Calculated rock porosity from ImageJ software showed variation among the wells selected for this study; but the porosity variation does not correlate with differences in fluid viscosity that was previously observed, i.e. heavy and light viscosity oils (Kwasny, 2015). Heavy oils were seen in wells that had both higher and lower porosity values, and the same is true for the distribution of light oils. This suggested that fluid viscosity is the major controlling factor in compartmentalization in the Spivey-Grabs and not rock properties.

Master of Science / Department of Geology / Matthew Totten / Oil production in Kansas has a long history with plays being found on all sides of the state. The source of Kansas’s hydrocarbons has been traditionally thought to be outside the state due to low thermal maturity and the shallow burial of potential source rocks within Kansas. This research addresses the question regarding the source of the oil in Kansas, at least within a small geographic area of roughly 146mi[superscript]2. The Spivey-Grabs-Basil Field has been one of the more successful fields within the state of Kansas since the 1960’s. This field is compartmentalized and offers a natural laboratory in which to conduct the field’s first formal oil-source rock correlation since oils are locked into place. While the main focus of this research relies heavily on pyrolysis and GCMS for biomarker analysis, it also investigates the possibility of using rare earth element (REE) concentrations as a possible fingerprint of organic matter within a source bed. TOC values of the Chattanooga shale samples from the Spivey-Grabs-Basil filed range from 0.75 and 3.95 wt. %, well within productive capacity. Pyrograms show both the potential for additional production, and the likely previous expulsion of hydrocarbons. Biomarker concentration percentages between C[subscript]27, C[subscript]28, and C[subscript]29 steranes, as well as pentacyclic terpane ratios compared between crude oil from the Spivey-Grabs-Basil and the Chattanooga shale show a definite genetic relationship. REE values of the organic fraction of the Chattanooga inversely correlate with those of the crude oils, suggesting fractionation during oil generation. After comparison of results with the Woodford shale in Oklahoma, the conclusion of this study is that the Chattanooga shale which underlies the Spivey-Grabs-Basil oil field of southern Kansas is the probable source rock which generated the oil now being produced.

Master of Science / Geology / Matthew W. Totten / The most common practice of typing crude oils utilizes biomarkers to gain insight on the history of the oil. This practice only considers the organic chemistry of the oil, and does not consider the trace element concentrations within the oil. Rare earth element and other trace element concentrations in crude oil might provide further insight into the oil’s source and origin. This study analyzed REE and other trace metal concentrations of crude oil in the Spivey-Grabs field of south-central Kansas through analysis by ICP-MS and ICP-AES that, coupled with visual physical characteristics of oil and FT-IR analysis, could explain the reported “compartmentalization” of the field and provide insight on the origin of the oils. Analysis of physical characteristics of the crude oils suggested the presence of two types of oil, of differing viscosities, in the field. FT-IR confirmed the presence of these two oil types based on functional groups present in the oils. The existence of a high viscosity oil could potentially explain the compartmentalization behavior in the field. PAAS-normalized REE distribution patterns showed a general LREE enrichment, a positive cerium and negative europium anomaly, and a MREE and HREE depletion, but higher viscosity oils showed additional MREE and HREE enrichment. K/Rb values ranged from 2,864 to 44,118, with oils from mixed-viscosity wells having lower ratios overall. K/Rb values of Spivey-Grabs crude oils more closely resembled those of the Lansing-Kansas City formation than the K/Rb values of the Woodford shale and Mississippian formation of the Anadarko basin. Comparing the rare earth element distribution patterns and K/Rb values from this study to those of the Woodford shale suggests the Spivey-Grabs oil originated from a local source and not from the Woodford shale.