Thesis (M.S.) -- Middle East Technical University, 2005. / Keywords: steam power cycle, combined cycle, single pressure HRSG, dual pressure HRSG, supplementary firing.

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M.Phil. / The aim of this study is to achieve a greater output by scrutinizing the present way of coordinating the efforts Qf Steam Industries in South Africa to achieve a sustainable industrial development by using energy source efficiently and effectively. Furthermore into the study we look at obstacles that prevents and those that leads to maximum utilization of energy management measures, and also highlights the effects of implementing cheap available energy source in South Africa...

The problem of the forced film condensation heat transfer of pure steam and steam-air mixture flowing downward a tier of horizontal cylinders is investigated numerically and experimentally. Liquid and vapor-air mixture boundary layers were solved by an implicit finite difference scheme. The effects of the free stream non-condensable gas (air) concentration, free stream velocity (Reynolds number), cylinder diameter, temperature difference and angle of inclination on the condensation heat transfer are analyzed. Inline and staggered tubes arrangements are considered. The mathematical model takes into account the effect of staggering of the cylinders and how condensation is affected at the lower cylinders when condensate does not fall on to the center line of the cylinders. An experimental setup was also manufactured and mounted at METU workshop. A set of experiments were conducted to observe the condensation heat transfer phenomenon and to verify the theoretical results. Condensation heat transfer results are available in ranges from (U&amp / #61605 / = 1 - 30 m/s) for free stream velocity, (m1,&amp / #61605 / = 0.01 -0.8) for free stream air mass fraction, (d = 12.7 -50.8 mm) for cylinder diameter and (T&amp / #61605 / -Tw =10-40 K) for temperature difference. Results show that / a remarked reduction in the vapor side heat transfer coefficient is noticed when very small amounts of air mass fractions present in the vapor. In addition, it decreases by increasing in the cylinder diameter and the temperature difference. On the other hand, it increases by increasing the free stream velocity (Reynolds number). Average heat transfer coefficient at the middle and the bottom cylinders increases by increasing the angle of inclination, whereas, no significant change is observed for that of the upper cylinder. Although some discrepancies are noticed, the present study results are inline and in a reasonable agreement with the theory and experiment in the literature. Down the bank, a rapid decrease in the vapor side heat transfer coefficient is noticed. It may be resulted from the combined effects of inundation, decrease in the vapor velocity and increase in the non-condensable gas (air) at the bottom cylinders in the bank. Differences between the present study results and the theoretical and the experimental data may be resulted from the errors in the numerical schemes used. These errors include truncation and round off errors, approximations in the numerical differentiation for interfacial fluxes at the vapor-liquid interface, constant properties assumption and approximations in the initial profiles. Mixing and re-circulation in the steam-air mixture at the lower tubes may be the other reasons for these deviations.

EFFECTS OF OFF-CENTER ANGLE ON THE HEAT TRANSFER COEFFICIENT ON VERTiCAL TIER OF MULTIPLE SPHERICAL SURFACES Kaya, Ebubekir M.S., Department of Mechanical Engineering Supervisor: Assoc. Prof. Dr. Cemil Yamali December 2004, 112 pages The purpose of this study is to investigate the laminar film condensation phenomenon of steam on a vertical tier of multiple spherical surfaces by using both analytical and experimental methods. The analytical heat transfer results were obtained by following the Nusselt type of analysis and represented graphically. In addition, in order to observe the real behavior of the film condensation, an experimental setup was manufactured and experiments were done. In analytical section / mass flow rate, (mean) velocity, film thickness, local heat flux and local heat transfer coefficient values were obtained and plotted as depending on angular position. Moreover, mean heat flux and mean heat transfer coefficient variations were presented with respect to diameter of the sphere and sub-cooling. On the other hand, for the experimental section, heat flux and mean heat transfer coefficient values were obtained and expressed as depending on sub-cooling. To see the effects of off-center angle, setup was inclined for different angles and experiments were repeated for each inclination angle. At the end of the study, mean heat transfer coefficients belong to analytical and experimental studies were compared to each other as well as to the literature.

A combined cycle gas/steam power plant combines a gas turbine (topping cycle) with a steam power plant (bottoming cycle) through the use of a heat recovery steam generator. It uses the hot exhaust of the gas turbine to produce steam which is used to generate additional power in the steam power plant. The aim of this study is to establish the different bottoming cycle performances in terms of the main parameters of heat recovery steam generator and steam cycle for a chosen gas turbine cycle. First of all / for a single steam power cycle, effect of main cycle parameters on cycle performance are analyzed based on first law of thermodynamics. Also, case of existence of a reheater section in a steam cycle is evaluated. For a given gas turbine cycle, three different bottoming cycle configurations are chosen and parametric analysis are carried out based on energy analysis to see the effects of main cycle parameters on cycle performance. These are single pressure cycle, single pressure cycle with supplementary firing and dual pressure cycle. Also, effect of adding a single reheat to single pressure HRSG is evaluated. In single pressure cycle, HRSG generates steam at one pressure level. In dual pressure cycle, HRSG generates steam at two different pressure levels. i.e. high pressure and low pressure. In single pressure cycle with supplementary firing excess oxygen in exhaust gas is fired before entering HRSG by additional fuel input. So, temperature of exhaust gas entering the HRSG rises. Second law analysis is performed to able to see exergy distribution throughout the bottoming plant / furthermore second law efficiency values are obtained for single and dual pressure bottoming cycle configurations as well as basic steam power cycle with and without reheat. It is shown that maximum lost work due to irreversibility is in HRSG for a bottoming cycle in a single pressure gas / steam combined power plant and in boiler for a steam cycle alone. Comparing this with the single pressure cycle shows how the dual pressure cycle makes better use of the exhaust gas in the HRSG that dual pressure combined cycle has highest efficiency values and lost work due to irreversibility in -most significant component- HRSG can be lowered. And also it is shown that by extending the idea of reheat the moisture content is reduced and improvement in the performance is possible for high main steam pressures. Another observation is that supplementary firing increases the steam turbine output compared to the cycle without supplementary firing. The efficiency rises slightly for HP steam pressures higher than 14 MPa at HRSG exit, because the increased steam production also results in increased mass flows removing more energy from the exhaust gas.

M.Tech. / Essential oils are volatile oils, generally odorous, which occur in certain plants or specified parts of plants, and are recovered by accepted procedures, such that the nature and composition of the product is, as nearly as practicable, unchanged by such procedures (ISO, 1968). The principal uses are as: flavouring agent, medicinal and aromatherapy application. Today, the essential oils are sought-after for innumerable applications starting from markers for plant identifications to bases for semi-synthesis of highly complex molecules. The extraction of highly delicate essential oils from plants remains a crucial step in all these applications. By using steam to mediate the extraction, it is possible to maintain mild conditions and effect superior extraction. In the current work, an integrated procedure for steam extraction followed by volatiles sampling and analysis from the leaves of the Eucalyptus tree was explored. There are two problems to overcome in the extraction from solid plant materials: that of releasing the essential oils from solid matrix and letting it diffuse out successfully in a manner that can be scaled-up to industrial volumes. Towards this end, the effect of different parameters, such as temperature, pressure and extraction time on the extraction yield was investigated and the experimental results show that all of these temperatures (90 °C, 97°C, and 99°C), were significant parameters affecting yield. Increase in yield was observed as pressure was increased and the use of high pressure (150 kPa) in steam extraction units permits much more rapid and complete distillation of essential oils over atmospheric pressure. The yield was calculated from the relation between the essential oil mass extracted and the raw material mass used in the extraction. The volatiles, Eucalyptus oil in vapour form released from the leaves were condensed and analyzed using Gas chromatography, and eight major components were found to be contained in this species. A mathematical model based on diffusion of essential oil from the leaves was developed. Using a numerical method, the best diffusion coefficient was established for different operating conditions by comparing the model concentration of oil remaining in the leaves with the experimental amount of oil recovered; hence minimizing the sum of squared errors. It was found that one cannot simply assume that the oil leached and recovered was the same as that originally present in the leaves. The initial mass of oil was determined by fitting the diffusion model to the data. An Arrhenius model was used to account for the effect of temperature. The resulting expression for the diffusion coefficient as a function of temperature can now be used to model the large scale extraction of the essential oils from Eucalyptus leaves.