We studied the migration of nonmagnetic, submicrometer polystyrene beads submerged in a magnetic fluid in the presence of nonuniform magnetic fields as a potential method for size-based separation of submicrometer, nonmagnetic species. Since the polystyrene beads are much larger than the magnetic fluid nanoparticles, the magnetic fluid was treated as a one-component continuum with respect to the beads. We found that the polystyrene beads will migrate in the direction of decreasing magnetic fields and will focus over a region where the magnetic field or its gradient vanishes, as predicted by our model. The concentration profiles predicted by our model, which has no adjustable or fitted parameters, agree reasonably well with the experimental data both qualitatively and quantitatively. / Singapore-MIT Alliance (SMA)

Children are a susceptible group to environment pollution. The environment, in which they spend the most time, is the home, the second is the school. Therefore, the indoor environment of a school affects their health, wellbeing and even school results. The present work investigated concentrations of air pollutant, aerosol particles, in the specialized classrooms (computer lab, arts and biology/chemistry) in an elementary school, Prague. Direct reading instruments measuring mass concentration of four aerosol fractions and number concentration of submicrometer particles were used for measurement. Measurements were carried out for four weekdays in each month from November 2011 to July 2012. It was found that mass concentrations of submicrometer particles were dependent on outdoor concentrations, in contrast to supermicrometer particles which were affected mainly by physical activities of students and outdoor concentration had a minimal effect. Increased number concentrations of submicrometer particles were observed only during children presence, concentrations were probably induced by student activities during lessons. Seasons also influenced mass concentrations, when the highest indoor and outdoor concentrations were recorded in a spring/autumn season. Classroom location affected submicrometer...

The understanding of human exposure to indoor particles of all sizes is important to enable exposure control and reduction, but especially for smaller particles since the smaller particles have a higher probability of penetration into the deeper parts of the respiratory tract and also contain higher levels of trace elements and toxins. Due to the limited understanding of the relationship between particle size and the health effects they cause, as well as instrument limitations, the available information on submicrometer (d < 1.0 µm) particles indoors, both in terms of mass and number concentrations, is still relatively limited. This PhD project was conducted as part of the South-East Queensland Air Quality program and Queensland Housing Study aimed at providing a better understanding of ambient particle concentrations within the indoor environment with a focus on exposure assessment and control. This PhD project was designed to investigate comprehensively the sources and sinks of indoor aerosol particles and the relationship between indoor and outdoor aerosol particles, particle and gaseous pollutant, as well as the association between indoor air pollutants and house characteristics by using, analysing and interpreting existing experimental data which were collected before this project commenced, as well as data from additional experiments which were designed and conducted for the purpose of this project. The focus of this research was on submicrometer particles with a diameter between 0.007 - 0.808 µm. The main outcome of this project may be summarised as following: * A comprehensive review of particle concentration levels and size distributions characteristics in the residential and non-industrial workplace environments was conducted. This review included only those studies in which more general trends were investigated, or could be concluded based on information provided in the papers. This review included four parts: 1) outdoor particles and their effect on indoor environments; 2) the relationship between indoor and outdoor concentration levels in the absence of indoor sources for naturally ventilated buildings; 3) indoor sources of particles: contribution to indoor concentration levels and the effect on I/O ratios for naturally ventilated buildings; and 4) indoor/outdoor relationship in mechanically ventilated buildings. * The relationship between indoor and outdoor airborne particles was investigated for sixteen residential houses in Brisbane, Australia, in the absence of operating indoor sources. Comparison of the ratios of indoor to outdoor particle concentrations revealed that while temporary values of the ratio vary in a broad range from 0.2 to 2.5 for both lower and higher ventilation conditions, average values of the ratios were very close to one regardless of ventilation conditions and of particle size range. The ratios were in the range from 0.78 to 1.07 for submicrometer particles, from 0.95 to 1.0 for supermicrometer particles and from 1.01 to 1.08 for PM2.5 fraction. Comparison of the time series of indoor to outdoor particle concentrations showed a clear positive relationship existing for many houses under normal ventilation conditions (estimated to be about and above 2 h-1), but not under minimum ventilation conditions (estimated to be about and below 1 h-1). These results suggest that for normal ventilation conditions and in the absence of operating indoor sources, outdoor particle concentrations could be used to predict instantaneous indoor particle concentrations but not for minium ventilation, unless air exchange rate is known, thus allowing for estimation of the "delay constant". * Diurnal variation of indoor submicrometer particle number and particle mass (approximation of PM2.5) concentrations was investigated in fifteen of the houses. The results show that there were clear diurnal variations in both particle number and approximation of PM2.5 concentrations, for all the investigated houses. The pattern of diurnal variations varied from house to house, however, there was always a close relationship between the concentration and human indoor activities. The average number and mass concentrations during indoor activities were (18.2±3.9)×10³ particles cm-³ and (15.5±7.9) µg m-³ respectively, and under non-activity conditions, (12.4±2.7)x10³ particles cm-³ (11.1±2.6) µg m-³, respectively. In general, there was a poor correlation between mass and number concentrations and the correlation coefficients were highly variable from day to day and from house to house. This implies that conclusions cannot be drawn about either one of the number or mass concentration characteristics of indoor particles, based on measurement of the other. The study also showed that it is unlikely that particle concentrations indoors could be represented by measurements conducted at a fixed monitoring station due to the large impact of indoor and local sources. * Emission characteristics of indoor particle sources in fourteen residential houses were quantified. In addition, characterizations of particles resulting from cooking conducted in an identical way in all the houses were measured. All the events of elevated particle concentrations were linked to indoor activities using house occupants diary entries, and catalogued into 21 different types of indoor activities. This enabled quantification of the effect of indoor sources on indoor particle concentrations as well as quantification of emission rates from the sources. For example, the study found that frying, grilling, stove use, toasting, cooking pizza, smoking, candle vaporizing eucalyptus oil and fan heater use, could elevate the indoor submicrometer particle number concentration levels by more than 5 times, while PM2.5 concentrations could be up to 3, 30 and 90 times higher than the background levels during smoking, frying and grilling, respectively. * Indoor particle deposition rates of size classified particles in the size range from 0.015 to 6 µm were quantified. Particle size distribution resulting from cooking, repeated under two different ventilation conditions in 14 houses, as well as changes to particle size distribution as a function of time, were measured using a scanning mobility particle sizer (SMPS), an aerodynamic particle sizer (APS), and a DustTrak. Deposition rates were determined by regression fitting of the measured size-resolved particle number and PM2.5 concentration decay curves, and accounting for air exchange rate. The measured deposition rates were shown to be particle size dependent and they varied from house to house. The lowest deposition rates were found for particles in the size range from 0.2 to 0.3 µm for both minimum (air exchange rate: 0.61±0.45 h-1) and normal (air exchange rate: 3.00±1.23 h-1) ventilation conditions. The results of statistical analysis indicated that ventilation condition (measured in terms of air exchange rate) was an important factor affecting deposition rates for particles in the size range from 0.08 to 1.0 µm, but not for particles smaller than 0.08 µm or larger than 1.0 µm. Particle coagulation was assessed to be negligible compared to the two other processes of removal: ventilation and deposition. This study of particle deposition rates, the largest conducted so far in terms of the number of residential houses investigated, demonstrated trends in deposition rates comparable with studies previously reported, usually for significantly smaller samples of houses (often only one). However, the results compare better with studies which, similarly to this study, investigated cooking as a source of particles (particle sources investigated in other studies included general activity, cleaning, artificial particles, etc). * Residential indoor and outdoor 48 h average levels of nitrogen dioxide (NO2), 48h indoor submicrometer particle number concentration and the approximation of PM2.5 concentrations were measured simultaneously for fourteen houses. Statistical analyses of the correlation between indoor and outdoor pollutants (NO2 and particles) and the association between house characteristics and indoor pollutants were conducted. The average indoor and outdoor NO2 levels were 13.8 ± 6.3 ppb and 16.7 ± 4.2 ppb, respectively. The indoor/outdoor NO2 concentration ratio ranged from 0.4 to 2.3, with a median value of 0.82. Despite statistically significant correlations between outdoor and fixed site NO2 monitoring station concentrations (p = 0.014, p = 0.008), there was no significant correlation between either indoor and outdoor NO2 concentrations (p = 0.428), or between indoor and fixed site NO2 monitoring station concentrations (p = 0.252, p = 0.465,). However, there was a significant correlation between indoor NO2 concentration and indoor submicrometer aerosol particle number concentrations (p = 0.001), as well as between indoor PM2.5 and outdoor NO2 (p = 0.004). These results imply that the outdoor or fixed site monitoring concentration alone is a poor predictor of indoor NO2 concentration. * Analysis of variance indicated that there was no significant association between indoor PM2.5 and any of the house characteristics investigated (p > 0.05). However, associations between indoor submicrometer particle number concentration and some house characteristics (stove type, water heater type, number of cars and condition of paintwork) were significant at the 5% level. Associations between indoor NO2 and some house characteristics (house age, stove type, heating system, water heater type and floor type) were also significant (p < 0.05). The results of these analyses thus strongly suggest that the gas stove, gas heating system and gas water heater system are main indoor sources of indoor submicrometer particle and NO2 concentrations in the studied residential houses. The significant contributions of this PhD project to the knowledge of indoor particle included: 1) improving an understanding of indoor particles behaviour in residential houses, especially for submicrometer particle; 2) improving an understanding of indoor particle source and indoor particle sink characteristics, as well as their effects on indoor particle concentration levels in residential houses; 3) improving an understanding of the relationship between indoor and outdoor particles, the relationship between particle mass and particle number, correlation between indoor NO2 and indoor particles, as well as association between indoor particle, NO2 and house characteristics.