Thesis (Ph. D.)--University of Wisconsin--Madison, 1975. / Typescript. Vita. Description based on print version record. Includes bibliographical references.

Thesis (Ph.D.) - University of St Andrews, March 2008.

Thesis (Ph. D.)--Johns Hopkins University, 1928. / Biography.

Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Biology, 1981. / Supervised by Holger W. Jannasch. Vita. Includes bibliographical references (leaves 359-373).

Thesis (Ph.D.)--University of Missouri-Columbia, 2004. / Typescript. Vita. Includes bibliographical references. Also available on the Internet.

Thesis (Ph.D.)--Hong Kong University of Science and Technology, 2006. / Includes bibliographical references (leaves 116-133). Also available in electronic version.

É difundido na literatura especializada que o uso de misturas de biodiesel e diesel de petróleo reduz as emissões dos compostos de enxofre. Esses compostos são responsáveis por inúmeras enfermidades respiratórias, além de provocar danos ao catalisador automotivo, contribuindo desta forma para a emissão de outros poluentes. Neste trabalho fez-se uma identificação dos compostos de enxofre, antes da queima no motor, presentes no diesel e em misturas de biodiesel/diesel de diferentes fontes. A metodologia empregada foi a cromatografia de fase gasosa e inicialmente empregou-se um detector de ionização por chama de hidrogênio para ajuste das condições operacionais, por ser um detector considerado universal e capaz de identificar tanto os majoritários hidrocarbonetos como os compostos de enxofre. Em seguida aplicou-se os parâmetros operacionais obtidos a um cromatógrafo à gás acoplado a um detector seletivo para enxofre, o SCD (sulphur chemiluminescence detector) para a identificação apenas dos compostos de enxofre. Após a obtenção dos dados teóricos em laboratório, foi realizada a análise de compostos mercaptídicos produzidas pelas emissões de um ônibus do Rio de Janeiro abastecido com diesel puro e misturas diesel/biodiesel nas proporções (v/v) 2% (B2), 5% (B5), 10% (B10), and 20% (B20). Os resultados indicaram uma redução dos compostos de enxofre proporcional à adição do biodiesel tanto na teoria quanto na prática / The mixing of biodiesel and petroleum diesel is being widely used as an attempt to reduce the emissions of sulfur compounds. These compounds are responsible for pollution, causing several diseases, as some breath problems. Sulfur compounds cause car catalyst poisoning and deactivation of processing, contributing with undesirable emissions of other toxic compounds. The goal of this work was to identify sulfur compounds in diesel and in some biodiesel mixtures of different sources. Gas chromatography system coupled with FID (flame ionization detector) was the methodology initially employed, for adjustment of the operational conditions, since FID is a low selectivity detector capable of identifying sulfur compounds and the majority of hydrocarbons. For the sulfur identification, a selective detector for sulfur compounds was employed (SCD - sulfur chemiluminescence detector). After the initial tests realized in the lab, analyses were carried out in a typical Brazilian urban bus fleet, to quantify the presence of mercaptans. The bus was fueled with pure diesel and with different biodiesel blends (v v) of 2% (B2), 5% (B5), 10% ( B10) and 20% (B20). The samples were collected from a real bus in use. Obtained results showed that the addition of biodiesel decreases proportionally the presence of sulfur compounds

É difundido na literatura especializada que o uso de misturas de biodiesel e diesel de petróleo reduz as emissões dos compostos de enxofre. Esses compostos são responsáveis por inúmeras enfermidades respiratórias, além de provocar danos ao catalisador automotivo, contribuindo desta forma para a emissão de outros poluentes. Neste trabalho fez-se uma identificação dos compostos de enxofre, antes da queima no motor, presentes no diesel e em misturas de biodiesel/diesel de diferentes fontes. A metodologia empregada foi a cromatografia de fase gasosa e inicialmente empregou-se um detector de ionização por chama de hidrogênio para ajuste das condições operacionais, por ser um detector considerado universal e capaz de identificar tanto os majoritários hidrocarbonetos como os compostos de enxofre. Em seguida aplicou-se os parâmetros operacionais obtidos a um cromatógrafo à gás acoplado a um detector seletivo para enxofre, o SCD (sulphur chemiluminescence detector) para a identificação apenas dos compostos de enxofre. Após a obtenção dos dados teóricos em laboratório, foi realizada a análise de compostos mercaptídicos produzidas pelas emissões de um ônibus do Rio de Janeiro abastecido com diesel puro e misturas diesel/biodiesel nas proporções (v/v) 2% (B2), 5% (B5), 10% (B10), and 20% (B20). Os resultados indicaram uma redução dos compostos de enxofre proporcional à adição do biodiesel tanto na teoria quanto na prática / The mixing of biodiesel and petroleum diesel is being widely used as an attempt to reduce the emissions of sulfur compounds. These compounds are responsible for pollution, causing several diseases, as some breath problems. Sulfur compounds cause car catalyst poisoning and deactivation of processing, contributing with undesirable emissions of other toxic compounds. The goal of this work was to identify sulfur compounds in diesel and in some biodiesel mixtures of different sources. Gas chromatography system coupled with FID (flame ionization detector) was the methodology initially employed, for adjustment of the operational conditions, since FID is a low selectivity detector capable of identifying sulfur compounds and the majority of hydrocarbons. For the sulfur identification, a selective detector for sulfur compounds was employed (SCD - sulfur chemiluminescence detector). After the initial tests realized in the lab, analyses were carried out in a typical Brazilian urban bus fleet, to quantify the presence of mercaptans. The bus was fueled with pure diesel and with different biodiesel blends (v v) of 2% (B2), 5% (B5), 10% ( B10) and 20% (B20). The samples were collected from a real bus in use. Obtained results showed that the addition of biodiesel decreases proportionally the presence of sulfur compounds

The effects of sulfur dispersing agents (SDAs) in the oxygen pressure leaching of nickel concentrate at medium temperature were investigated. Liquid sulfur-aqueous solution interfacial tensions and liquid sulfur-sulfide mineral contact angles were measured at 140ºC, 690 kPa overpressure by nitrogen, and 1.0 mol/L NiSO₄. The effects of SDAs including lignosulfonate, Quebracho, o-phenylenediamine (OPD), and humic acid were evaluated by the calculation of the work of adhesion in the liquid sulfur-sulfide mineral-aqueous solution systems. It was found that the sulfide mineral surface is sulfophobic at pH from 4.1 to 4.5 due to the hydrolysis of nickel (II) ions to nickel hydroxide and the deposition of nickel hydroxide on the mineral surface. These findings apply to four different sulfide mineral systems, including pentlandite, nickeliferous pyrrhotite, pyrrhotite, and chalcopyrite. Lignosulfonate, Quebracho, and humic acid were found to significantly reduce the work of adhesion indicating they should be effective SDAs. OPD is ineffective in changing the work of adhesion of sulfur on the mineral sulfides indicating that it is not a good candidate for sulfur dispersion. The adsorption behavior of SDAs, including lignosulfonate, Quebracho, OPD, and humic acid on elemental sulfur and on nickel sulfide concentrate was investigated. Lignosulfonate, Quebracho, and humic acid were characterized by their infrared spectra. The charge changes on elemental sulfur surface were characterized by the measurement of the electrokinetic sonic amplitude (ESA) in the absence or presence of SDAs. The adsorption of lignosulfonate on molten sulfur surface was calculated by the Gibbs Equation. The adsorption of lignosulfonate, Quebracho, and humic acid on the nickel concentrate was investigated at ambient temperature. The adsorption of lignosulfonate, Quebracho, and humic acid on the nickel concentrate was found to be monolayer adsorption, which was fitted to the Langmuir adsorption isotherm. Electrostatic interaction and ion-binding are the possible mechanisms for the adsorption of lignosulfonate and humic acid on the nickel concentrate. Quebracho is adsorbed on the nickel concentrate through hydroxyl and sulfonate groups. OPD cannot adsorb on the molten sulfur surface. OPD undergoes chemical change in aqueous solution in the presence of ferric at ambient temperature. Oxygen pressure leaching experiments were performed at 140 or 150ºC under 690 kPa oxygen overpressure. The particle size of the nickel concentrate was found to be an important factor in leaching. During the leaching of nickel concentrate with P₈₀ of 48 µm, the SDAs were believed to be fully degraded before nickel was fully extracted. At most 66% nickel was extracted in the presence of 20 kg/t OPD. Fine grinding (P₈₀ of 10 µm) was sufficient for 99% nickel recovery at low pulp density while at high pulp density, the nickel extraction increased from 95% to 99% with addition of SDAs. Based on the leaching results on a nickel concentrate sample (-44 µm), OPD had the effect of increasing the nickel extraction to about 99%, followed by Quebracho (83%), lignosulfonate (72%), and humic acid (61%). It is suggested that the oxidation product of OPD is effective in solving the sulfur wetting problem in leaching. 97% nickel was recovered in the presence of 5 g/L chloride ion. Chloride ion has an effect to enhance the performance of lignosulfonate under leaching conditions. / Applied Science, Faculty of / Materials Engineering, Department of / Graduate

Doctor of Philosophy / Department of Agronomy / Nathan O. Nelson / Augustine K. Obour / Emerging sustainability issues with summer-fallow period has prompted producers to identify fallow replacement crops in wheat (Triticum aestivum) production systems. Camelina [Camelina sativa (L.) Crantz] has been identified as a potential fallow replacement crop in the semiarid Great Plains. Camelina has uses in animal and human nutrition, biofuel production, and bio-based products. Three field experiments were conducted to develop production recommendations for camelina in wheat production systems in the semiarid Great Plains. In the first study, three camelina cultivars were evaluated in mid-March (March 17, 2014; March 18, 2015), early-April (April 3, 2013; April 1, 2014 and 2015), and mid-April (April 16, 2013; April 15, 2014 and 2015) at Hays, KS. Findings from this study showed delaying camelina planting until early- or mid-April resulted in 34% increase in seed yield. Planting date affected oil concentration, saturated fatty acids (SFA), monounsaturated fatty acids (MUFA), polyunsaturated fatty acids (PUFA), and linolenic acid concentration. The concentrations of SFA, MUFA, PUFA, linoleic acid, and linolenic acid were also different among cultivars. A second study was conducted to evaluate the response of camelina to nitrogen (N), and sulfur (S) fertilizer application. Nitrogen rates (0, 22, 45 and 90 kg ha⁻¹), and S rates (0 and 20 kg ha⁻¹) were applied in a randomized complete block design with a split-plot arrangement. The main plots were S application rates and the subplot factor was N rates. Sulfur application did not affect seed yield, oil, protein, or seed nutrient concentration. The agronomic optimum N rate was 49 kg N ha⁻¹, however, the economic optimum N rate ranged from 25 to 31 kg N ha⁻¹ based on current N fertilizer cost, and camelina seed price. Nitrogen application had no effect on SFA, MUFA, and PUFA. Moderate N application increased seed calcium (Ca) concentration, whereas higher N rate increased zinc (Zn), and manganese (Mn) concentration in the seed. There was a general negative relation between N application with copper (Cu), and molybdenum (Mo) in camelina seed. Our study shows that camelina needed to be applied with a minimum of 25 kg N ha⁻¹ for optimum production. A third study investigated effects of crop rotation on crop yield, soil water, soil CO₂ flux, and soil health in wheat-camelina rotation systems. Rotation systems in this study were wheat-fallow (W-F), wheat-sorghum (Sorghum bicolor) -fallow (W-S-F), wheat-spring camelina (W-SC), and wheat-sorghum-spring camelina (W-S-SC). Crop rotation had no effect on sorghum grain yield. However, winter wheat yield decreased by 15% when fallow was replaced by camelina in the rotation system. Camelina yield in W-SC was 2-fold greater than that in W-S-SC. Soil water content in the more intensified rotations were less than rotations with fallow, irrespective of sampling period. Soil pH, phosphorus (P), and total nitrogen (TN) were not different among rotation systems. Nonetheless, soil profile N, soil organic carbon (SOC), microbial biomass carbon and N (MBC and MBN), and potentially mineralizable nitrogen (PMN) were different among rotation systems. Soil particle aggregation increased with increasing cropping intensity. This suggests improved soil structure with cropping intensification.