In South Africa one of the strongest influences on domestic indoor air quality is the type of energy used for heating, cooking and other household purposes. Emissions from fuel combustion, along with housing factors, can result in respiratory infections, a leading cause of death in the country. In this study I examine the relationships between energy types, patterns of use, housing conditions such as improper ventilation and overcrowding, indoor air quality and respiratory health in poorer communities of Msunduzi Municipality, South Africa. These variables were examined using an ecohealth perspective through the integration of data concerning individual time-activity budgets, housing materials and structure, energy sources used for heating, cooking and lighting, respiratory symptoms and continuous real time monitoring of indoor air pollutants (particulate matter (PM), carbon dioxide (CO2), carbon monoxide (CO) and sulphur dioxide (SO2)). A total of 20 dwellings, displaying large variability in housing structure and energy patterns, were sampled for 24 hours (hr) over a period of 60 days. The mean 24-hr average indoor concentrations measured were as follows: PM2.5= 16 ± 11 µg/m3, PM10= 78 ± 46 µg/m3, CO= 5 ± 6 ppm and SO2= 0.18 ± 0.27 ppm. Mean indoor concentrations measured were significantly greater than mean outdoor concentrations (p<0.0001 (PM2.5), p=0.017 (PM10), p<0.0001 (CO), p<0.0001 (SO2)). Although PM concentrations increased with the use of increasingly inefficient-burning fuel types (gas < paraffin < wood), no significant differences in the means were found across these fuel types. It is thought that the high degree of variability among dwellings and the small sample size in this study obscured any statistically significant relationships. No significant differences in mean concentrations were found across different housing types either. Indoor exposures were, on average, highest among very young children (ages 0-5) and elders (ages 51+). All age groups reported experiencing high levels of respiratory symptoms, with the elder group (ages 51+) reporting the highest percentages for each symptom. This study will be used to inform local governments and NGOs of local indoor air pollution and exposure risks, so that policy and resources can be allocated accordingly to improve physical environments. / Thesis (Master, Environmental Studies) -- Queen's University, 2007-09-27 08:52:05.443

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The effects of added potassium, K, magnesium, Mg and sulfur, S on corn grain and silage yields were investigated in the field for two years. / Due to high nutrient soil, K, Mg and S had no effects on corn grain and silage yields. However, there were trends observed in the treatment effects that were significant. Added K at 240 kg K$ sb2$O/ha increased grain yield over zero kg K$ sb2$O/ha in 1983 and Mg at 60 kg/ha increased grain yield over 30 kg/ha in 1984. In silage, 240 kg K$ sb2$O/ha increased yield over 120 and zero kg K$ sb2$O/ha in 1984. Although there was no K by Mg interaction, there was a need for added Mg to achieve higher yields. / The cumulative effect of fertilizer S at 50 kg/ha significantly reduced silage yield in 1984 over zero S treatment indicating that fertilizer S was unnecessary for corn growth by reason of high levels of soil S and sufficient S provided from precipitation and air dry deposition. S had no interaction with K and Mg because there was no need for fertilizer S to increase yields. / The antagonistic association between K and Mg was seen at the seedling, tasseling and silking stages. / There was an indication of a K by S interaction which was expressed at different stages of growth, but this effect was not evident for dry matter yields.

Seed-placed phosphorus (P) and sulphur (S) fertilizers can reduce canola plant stands. Field studies were conducted to determine the effect of various sources and rates of seed-placed P and S fertilizers on canola plant stand, early season biomass accumulation and seed yield. Conventional granular P and S blends increased the risk of seedling damage, but increased the frequency of yield response. Liquid fertilizers were similar in seedling damage but generally less effective in increasing seed yield compared to granular fertilizers. Novel fertilizers were more seed-safe but less reliable than conventional sources in increasing seed yield. A growth room experiment was conducted to determine the effect of soils from different landscape positions on the toxicity of seed-placed ammonium sulphate (AS) and monoammonium phosphate (MAP). Canola emergence was reduced and delayed by seed-placed MAP and AS. Ammonium sulphate in particular has a high risk of NH3 toxicity on calcareous hilltop soils

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Seed-placed phosphorus (P) and sulphur (S) fertilizers can reduce canola plant stands. Field studies were conducted to determine the effect of various sources and rates of seed-placed P and S fertilizers on canola plant stand, early season biomass accumulation and seed yield. Conventional granular P and S blends increased the risk of seedling damage, but increased the frequency of yield response. Liquid fertilizers were similar in seedling damage but generally less effective in increasing seed yield compared to granular fertilizers. Novel fertilizers were more seed-safe but less reliable than conventional sources in increasing seed yield. A growth room experiment was conducted to determine the effect of soils from different landscape positions on the toxicity of seed-placed ammonium sulphate (AS) and monoammonium phosphate (MAP). Canola emergence was reduced and delayed by seed-placed MAP and AS. Ammonium sulphate in particular has a high risk of NH3 toxicity on calcareous hilltop soils

This study introduces an evaluation of the downstream utilization of oxygen produced by the hybrid sulfur process (HYS). Both technical and economic aspects were considered in the production of primarily synthesis gas and hydrogen. Both products could increase the economic potential of the hybrid sulfur process. Based on an assumed 500MWt pebble bed modular nuclear reactor, the volume of hydrogen and oxygen produced by the scaled down HYS was found to be 121 and 959 ton per day respectively. The partial oxidation plant (POX) could produce approximately 1840 ton synthesis gas per day based on the oxygen obtained from the HYS. The capital cost of the POX plant is in the order of $104 million (US dollars, Base year 2008). Compared to the capital cost of the HYS, this seems to be a relatively small additional investment. The production cost varied from a best case scenario $9.21 to a worst case scenario of $19.36 per GJ synthesis gas. The profitability analysis conducted showed favourable results, indicating that under the assumed conditions, and with 20 years of operation, a NPV of $87 mil. and an IRR of 19.5% could be obtained, for the assumed base case. The economic sensitivity analysis conducted, provided insight into the upper and lower limitations of favourable operation. The second product that could be produced was hydrogen. With the addition of a water gas shift and a pressure swing adsorption process to the POX, it was found that an additional 221 ton of hydrogen per day could be produced. The hydrogen could be produced in the best case at $2.34/kg and in the worst case at $3.76/kg. The investment required would be in the order of $50 million. The profitability analysis for the base case analysis predicts an NPV of $206 million and a high IRR of 23.0% under the assumed conditions. On financial grounds it therefore seemed that the hydrogen production process was favourable. The thermal efficiency of the synthesis gas production section was calculated and was in good agreement with that obtained from literature. The hydrogen production section’s thermal efficiency was compared to that of steam methane reforming of natural gas (SMR) and it was found that the efficiencies were comparable but the SMR process was superior. The hydrogen production capacity of the HYS process was increased by a factor of 1.83. This implied that for every 1 kg of hydrogen produced by the HYS an additional 1.83 kg was produced by the proposed process addition. This lowers the cost of hydrogen produced by the HYS from $6.83 to the range of approximately $3.93 - $4.85/kg. In the event of a global hydrogen economy, traditional production methods could very well be supplemented with new and innovative methods. The integration of the wellknown methods incorporated with the new nuclear based methods of hydrogen production and chemical synthesis could facilitate the smooth transition from fossil fuel based to environmentally friendly methods. This study presents one possible integration method of nuclear based hydrogen production and conventional processing methods. This process is technically possible, efficient and economically feasible. / Thesis (M.Ing. (Nuclear Engineering))--North-West University, Potchefstroom Campus, 2009.

The gradual depletion of and dependence on fossil fuels, air pollution and global warming have all accelerated the development of alternative energy systems which use hydrogen as an energy carrier. The hybrid sulphur cycle (HyS) is the foremost electrothermochemical process that can produce hydrogen as the energy carrier. The HyS cycle consists of two units, namely the sulphuric acid decomposition reactor and the sulphur dioxide electrolyser (SDE). The SDE is responsible for the SO2 electrooxidation to sulphuric acid and protons at the anode and the electro–reduction of protons to hydrogen at the cathode. This research study focuses on the kinetic data collected from the prepared catalysts for SO2 electro–oxidation at the anode. Platinum dispersed on carbon, niobium pentoxide, tantalum pentoxide and zirconium dioxide as electrocatalysts were prepared using sodium borohydride as a reducing agent. These electrocatalysts were characterized using transmission electron microscopy and x–ray diffraction. Cyclic voltammetry was used to study the electrochemical active surface area (EAS) and the results showed that Pt/ZrO2–C had a higher EAS area than Pt/Ta2O5–C, Pt/Nb2O5–C and Pt/C. The high EAS of Pt/ZrO2–C can be explained by the low crystal size however after a series of linear polarisation scans Pt/ZrO2–C experiences a much greater area loss than all the other catalysts. Linear polarisation scans for each of the catalysts revealed that the influence of increased temperature and sulphuric acid concentration were showed improved results. Levich and Koutecky–Levich plots revealed that the SO2 oxidation is a multistep reaction on all the prepared catalysts and that there are regions which are kinetic and diffusion controlled and diffusion–only controlled. Pt/Ta2O5–C catalysts exhibited superior catalytic activity and stability compared Pt/Nb2O5–C, Pt/ZrO2–C and Pt/C. The Pt/ZrO2–C exhibited the most inferior catalytic activity and stability. / Thesis (M.Sc. (Chemistry))--North-West University, Potchefstroom Campus, 2011.