Post-mining land use potentials are greatly influenced by mine soil properties. I analyzed and classified coal mine soils in SW VA and mineral sands mine soils in SE VA to aid development of appropriate post-mining land use interpretations. For coal mine soils, long-term pedogenesis was assessed in sandstone (SS) and/or siltstone (SiS) spoils with and without surface amendments. For mineral sands mined lands, I evaluated their spatial variability with respect to underlying relic mining influences and rowcrop productivity. Coal mine subsoils densified as root-limiting layers formed that were not observed initially and all soils had weak pedogenic development (^Bw; cambic horizons), particularly SS derived soils. Initial rock spoil type strongly influenced coal mine soils over time (i.e., SS had coarser textures and lower subsoil pH vs. SiS). However, most soil chemical properties (e.g., pH, EC, CEC) became similar in ^A horizons over time. Fe-oxides increased, and extractable-P decreased with weathering, raising concerns for long-term P-availability. Organic amendments applied to rock spoil surfaces sustained higher total-N (sawdust and biosolids) and extractable P (biosolids). Soil carbon sequestration rates did not differ among rock types or amendments (0.16 to 0.28 Mg ha yr-1). Further, mineral sands mine soils were limited by densic contacts and short-range variability of important properties (texture) appeared related to underlying relic mining features (pits and berms). Yields in reclaimed soils were more variable than in adjacent undisturbed farmland, but mean yields were only slightly reduced for soybean in 2020. Coloration and Fe-oxide spectral indices had weak to moderate negative correlations with yield. Berm positions supported better soybean growth (three out of five sites), while pit positions were redder/darker (one out of five sites). Current Soil Taxonomy conveys anthropogenic origins at the family (e.g., spolic) and subgroup (e.g., Anthroportic) levels. Existing taxa and proposed Artesols order criteria both acknowledge effective soil depth x compaction limitations (Anthrodensic subgroup), but Artesols more effectively recognizes pedogenesis (Inceptic subgroup) and acknowledges mine soils at the highest level. The biggest management limitation for both mine soil types is root-limiting compaction; thus, future efforts should focus on defining depth ranges and taxonomic interpretations for densic contacts. / Doctor of Philosophy / Surface mining results in drastic disturbances to the original soil, land, and water features. Actual impacts vary due to local site conditions and methods used for mineral extraction and reclamation. Advancing reclamation science requires an understanding of the resulting mine soil properties and how they vary spatially and develop over time. This research program involved two very different mining scenarios and resultant mine soil types in Virginia that were both evaluated in terms of soil properties, taxonomic placements, and land use interpretations. First, I assessed Appalachian coal mine soils in southwestern Virginia following 34 years of soil development in sandstone (SS) and/or siltstone (SiS) derived overburden with and without surface amendments. Over time, rocky mine spoils transformed into weakly developed soil profiles, commonly with four to five total distinct layers (horizons), along with apparent "self-compacted" layers at depth. SS soils were coarser textured with somewhat better subsoil structure, while SiS soils were finer textured and had higher subsoil pH. However, many chemical properties were similar in the soil surface. Organic amendments and topsoil return imparted only subtle differences over time. A secondary objective was to assess mineral sands mine soils, which originate from recombined Coastal Plain sediments. Due to the nature of their wet deposition during final reclamation, these mine soils exhibited high variability across local landforms. Soil profiles over former berm positions were composed mostly of sandier materials, while pit positions had more variable materials and features. Reclaimed rowcrop yields were moderately correlated with bare soil remotely sensed variables. Soils in pit positions were redder in color due to higher clay. While yields were variable, especially in drier years, berms appeared to support better soybean growth, but results were inconsistent across fields. For both mine soil types, root-limiting compaction is their biggest impediment to productive use. Forestry is the predominant post-mining land use on former coal mines, while rowcrop production is becoming more common on former minerals sands mines. Since these two different post-mining environments present unique challenges for correctly interpreting their post-disturbance land-uses, it is important to convey their special properties (e.g., densic contacts) and limitations in their classification.

Doctor of Philosophy / Department of Biological and Agricultural Engineering / Ronaldo Maghirang / Emission of greenhouse gases (GHGs), including nitrous oxide (N2O), methane (CH4), and carbon dioxide (CO2), from open beef cattle feedlots is becoming an environmental concern; however, scientific information on emissions and abatement measures for feedlots is limited. This research was conducted to quantify GHG emissions from feedlots and evaluate abatement measures for mitigating emissions. Specific objectives were to: (1) measure N2O emissions from the pens in a commercial cattle feedlot; (2) evaluate the effectiveness of surface amendments in mitigating GHG emissions from feedlot manure; (3) evaluate the effects of water application on GHG emissions from feedlot manure; and (4) compare the photo-acoustic infrared multi-gas analyzer (PIMA) and gas chromatograph (GC) in measuring concentrations of N2O and CO2 emitted from feedlot manure. Field measurements on a commercial beef cattle feedlot using static flux chambers combined with GC indicated that N2O emission fluxes varied significantly with pen surface condition. The moist/muddy surface had the largest median emission flux; the dry and compacted, dry and loose, and flooded surfaces had significantly lower median emission fluxes. Pen surface amendments (i.e., organic residues, biochar, and activated carbon) were applied on feedlot manure samples in glass containers and evaluated for their effectiveness in mitigating GHG emissions. Emission fluxes were measured with the PIMA. For dry manure, all amendments showed significant reduction in N2O and CO2 emission fluxes compared with the control (i.e., no amendment). For moist manure, biochar significantly reduced GHG emissions at days 10 and 15 after application; the other amendments had limited effects on GHG emissions. The effect of water application on GHG emissions from feedlot manure was evaluated. Manure samples (with and without water application) were placed in glass containers and analyzed for GHG emission using a PIMA. For the dry manure, GHG emissions were negligible. Application of water on the manure samples resulted in short-term peaks of GHG emissions a few minutes after water application. Comparison of the GC and PIMA showed that they were significantly correlated but differed in measured concentrations of N2O and CO2. The PIMA showed generally lower N2O concentrations and higher CO2 concentrations than the GC.