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Characterization of the surface acidity of passivated iron particles by flow microcalorimetryAndrews, Marilyn Mockus, 1958- January 1987 (has links)
The characteristics of passivated iron particles have been examined with flow microcalorimetry to determine the acidic nature of the surface sites. The molar heat of adsorption of pyridine from hexane was measured with a FMC and a differential refractive index detector, at 23 and 40°C. The adsorption data were found to obey the assumptions of the Freundlich isotherm. The adsorption densities at different temperatures were used to calculate the isosteric heat of adsorption. The molar heat of adsorption of triethylamine from hexane was also measured and combined with the data for pyridine in order to calculate the Drago constants for the iron particles. A static adsorption method was used for the adsorption of pyridine from hexane onto the iron particles, for comparison with the dynamic method. The heat of wetting for the iron particles, with hexane, has also been measured. The iron particles were examined with X-ray diffraction. Mossbauer spectroscopy, XPS, SEM, TEM, and electrophoresis to characterize the surface layer. These techniques have revealed that the iron particles are coated with ferric oxide and this surface is amphoteric in aqueous solutions.
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The transient modification of secondary ion yield during oxidationMoore, Vic January 1992 (has links)
No description available.
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Quantum and classical dynamics at the gas-surface interfaceCorriol, CeÌcile January 2003 (has links)
No description available.
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The interaction of hydrogen with the (111) and (110) planes of silverHealey, Finola January 1995 (has links)
No description available.
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A surface enhanced raman spectroscopic study of the electrode/electrolyte interfaceLowry, R. B. January 1988 (has links)
No description available.
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Adsorption studies of simple molecules on metalic, bimetalic and semiconductor interfacesRowe, S. J. January 1988 (has links)
No description available.
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Investigation of the autoignition of N-hexane and acetaldehyde in a parallel plate reactorBradley, G. January 1984 (has links)
No description available.
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Studies of cadmium halides on Cu(111) and InSb(001)Ithnin, Roslinda January 1997 (has links)
No description available.
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Vibrational spectroscopic studies of adsorbates on metal and silicon single crystal surfacesHorn, Andrew B. January 1989 (has links)
No description available.
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The study of chromatographic interactions using model reversed-phase chromatography surfacesPower, Gillian Mary January 1999 (has links)
No description available.
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