In the design phase of any building industry, appropriate material selection is critical for the entire project. A poor choice of material may affect the quality of the project, lead to high cost during the long term operation and maintenance phases, and even endangering humans and the environment. Since the inception of the United States Green Building Council (USGBC) in 1993, ¡°green¡± buildings have become a hot topic and people have become concerned about how sustainable their buildings are. In order to determine the level of sustainability in buildings, the Leadership in Energy and Environmental Design (LEED) has developed a rating system that has been established now as the common denominator in the industry. However, the LEED rating system simplifies, or even ignores, explicit considerations for Lifecycle Assessment (LCA) in determining the selection of building materials. This lack of explicit consideration for LCA does not permit a full assessment in determining how truly sustainable the chosen materials are. This research analyzes the factors impacting the selection of the green materials and reviews the current standards used in green material. It proposes a more comprehensive rating method for the green material selection illustrating its applicability through a case study analysis based on new WPI Sports and Recreation Center. It is expected that this study would contribute to a better understanding of the sustainable materials selection and can improve help to improving their long term performance in buildings.

The embodied environmental and socioeconomic impacts of building construction are rarely considered within industry. Renewable and certified resources will continue to provide a viable low impact supply chain for construction, yet the use of such low impact building materials (LIBM) remains a small proportion of the current market. Structural engineers should be encouraged to use LIBM and consider the impacts of building construction, and so the research aim was to create an informed and responsible approach for structural engineers to reduce the embodied impacts of their projects. The limited amount of academic literature on the consideration of embodied impacts within construction and the use of LIBM prompted a two-phase research methodology. The first Problem Exploration phase developed a rich understanding of the current context of embodied impacts within construction through an analysis of data gathered from an online questionnaire and semi-structured interviews. The findings identified three key aspects to consider when developing an Embodied Impact Reduction Approach (EIRA); the alignment of the project-life cycle with influence, the limitation of time and costs, and the importance of support and education within the approach created. The second Action phase developed EIRA using the findings and supplementary data gathered from focus groups, which highlighted that EIRA should be flexible so as to be relevant to the breadth of projects that BuroHappold Engineering, who partially sponsored the research, work on. EIRA runs parallel to the RIBA Plan of Work, adapting to the different objectives, level of detail and information available at each project stage. Three components were developed; the Material Design Sheets, Carbon Calculator, and the Option Appraisal Support Technique (tOAST). tOAST was implemented on five projects to test its applicability, which identified that greater understanding of embodied impacts plus their relative importance to each other is required. Another key issue was the availability of appropriate embodied environmental data.

Orientador: Jorge Luís Akasaki / Resumo: Aglomerantes ativados alcalinamente (AAA) são obtidos da combinação de um precursor solido (geralmente um aluminosilicato) e uma solução alcalina de alta concentração. As vantagens de utilizar este novo tipo de aglomerante comparado ao cimento Portland, um aglomerante convencional, são as menores emissões de CO2, menor consumo de energia e a possibilidade de utilizar matérias prima renováveis e/ou resíduos. Neste sentido, este trabalho apresenta um novo resíduo da indústria da cada de açúcar: a folha de cana de açúcar. A folha apresenta um poder calorífico interessante; portanto, ela pode ser utilizada como biomassa para produzir energia através um processo de queima. Depois deste procedimento, é gerado um novo resíduo: a cinza de folha de cana de açúcar (CF). Esta cinza não apresenta uma destinação correta, então este trabalho tem como intenção utilizar esta cinza como material prima em AAA. A CF foi avaliada de duas formas: como precursor solido e como matéria prima para produzir a solução alcalina. No primeiro modo, a CF foi utilizada em sistemas combinados com a escória de alto forno (EAF) ativado com ambas soluções de NaOH e NaOH/silicato de sódio. No segundo modo, a CF foi utilizada como fonte de sílica para produzir a solução alcalina com o NaOH em AAA baseados em EAF. Os sistemas foram estudados através da resistência a compressão de argamassas e pelo estudo da microestrutura de pastas. Ensaios realizados para avaliar a microestrutura foram a difração de raios-X (DRX)... (Resumo completo, clicar acesso eletrônico abaixo) / Doutor

<p>  </p> <p>In this thesis, cellulose nanofiber (CNF) reinforced polylactic acid (PLA) filaments were produced for 3D printing applications using melt extrusion. The use of CNF reinforcement has the potential to improve the mechanical properties of PLA, making it a more suitable material for various 3D printing applications. To produce the nanocomposites, a master batch with a high concentration of CNFs was premixed with PLA, and then diluted to final concentrations of 1, 3, and 5 wt% during the extrusion process. The dilution was carried out to assess the effects of varying CNF concentrations on the morphology and mechanical properties of the composites. The results showed that the addition of 3 wt.% CNF significantly enhanced the mechanical properties of the PLA composites. Specifically, the tensile strength increased by 77.7%, the compressive strength increased by 62.7%, and the flexural strength increased by 60.2%. These findings demonstrate that the melt extrusion of CNF reinforced PLA filaments is a viable approach for producing nanocomposites with improved mechanical properties for 3D printing applications. In conclusion, the study highlights the potential of CNF reinforcement in improving the mechanical properties of PLA for 3D printing applications. The results can provide valuable information for researchers and industries in the field of 3D printing and materials science, as well as support the development of more advanced and sustainable 3D printing materials.</p>

The demand for pollution-free and recyclable engineering materials has been increased as the cost of energy and environmental concerns have risen. Green material design can lead to better environmental quality and sustainability of civil infrastructure. Road construction is one of the largest consumers of natural resources. Beneficial utilization of recycled materials can result in an important opportunity to save the mining and use of virgin materials, to preserve energy, and to save landfill space. Two main research questions addressed in this study are: (1) How much pollution, energy, natural resources, time and money can be salvaged by applying recycling materials to Hot-Mix Asphalt (HMA)?, (2) What are the optimum mix designs for those recycled materials in HMA?, and (3) Can multiple recycled materials be used at the same time to compensate each other*s drawbacks? This study evaluates the structural performance and environmental-economical cost and benefit by substituting one or a combination of three recycled materials in HMA. The three recycled materials are Recycled Asphalt Shingle (RAS), Municipal Solid Waste Incineration (MSWI) Bottom Ash, and Recycled Concrete Aggregate (RCA). Performance evaluation of the HMA including those recycled materials has been performed by a series of laboratory experimental tests while the environmental impact was investigated by the Life Cycle Assessment (LCA). In addition, Life Cycle Cost Analysis (LCCA) method has been employed to evaluate the benefit of the aforementioned recycled materials. In 2008, the Florida Legislature established a new statewide recycling goal of 75% to be achieved by the year 2020. The impact of this research aligns with this policy as it introduces a sustainable HMA that reduces the necessity of virgin aggregate and asphalt binder to 50% and 20%, respectively. In terms of environmental and economic impacts, in comparison with the regular HMA, it generates 25% less greenhouse gas emission, and for a period of 20 years, the cost of construction and maintenance would be 65% less.

Orientador: Jorge Luís Akasaki / Resumo: Nos últimos anos, tem havido um crescente interesse em substituir parcialmente ou totalmente o uso do cimento Portland por materiais com baixo impacto ambiental; logo o estudo de aglomerantes ativados alcalinamente obtidos a partir da mistura de um precursor sólido, rico em aluminossilicato, e uma solução alcalina de alta concentração, tem se mostrado uma alternativa viável, uma vez que o consumo de energia e a emissão de CO2 durante a produção dessas matrizes são reduzidas, e ainda, ocorre a possibilidade de inserção de subprodutos agroindustriais, na matriz desses aglomerantes. Assim a presente tese apresenta um estudo de viabilidade do uso da cinza do bagaço de cana-de-açúcar (CBC), subproduto da indústria sucroalcooleira, na produção de aglomerantes ativados alcalinamente. A CBC foi obtida a partir da queima não controlada do bagaço de cana-de-açúcar e apresentou uma composição química predominantemente constituída de dióxido de silício. A cinza foi submetida a ensaios de caracterização física e química, de modo a avaliar a viabilidade do uso da cinza na produção de matrizes ativadas. Os ensaios de caracterização e de reatividade indicaram que a cinza apresenta grande parte da sua sílica no estado cristalino, além de apresentar baixa solubilidade e reatividade pozolânica. Porém, os ensaios térmicos e mecânicos das argamassas e pastas produzidas com a CBC, demostraram que, a CBC apresenta boa reatividade para períodos de cura prolongados, possibilitando o seu uso em matriz... (Resumo completo, clicar acesso eletrônico abaixo) / Abstract: In recent years, there has been a growing interest in partially or totally replacing the use of Portland cement with materials with low environmental impact; Therefore, the study of alkaline activated binders obtained from the mixture of an aluminosilicate rich solid precursor and a high concentration alkaline solution, proved to be a viable alternative since energy consumption and CO2 emission during production of these matrices are reduced, and also, there is the possibility of insertion of agroindustrial byproducts in the matrix of these binders. Thus, this thesis presents a viability study of the sugarcane bagasse ash (SCBA) use, a by-product of the sugar and alcohol industry, in the production of alkaline activated binders. The SCBA was obtained from the uncontrolled calcination of the sugarcane bagasse and presented a chemical composition predominantly constituted of silicon dioxide. The ash was physically and chemically characterized, in order to assess the viability of the ash use in the production of activated matrices. Characterization and reactivity analysis indicated that ash presents a great part of its silica in the crystalline state, low solubility and pozzolanic reactivity. However, the thermal and mechanical analysis of mortars and pastes produced with SCBA showed that ash presented good reactivity for long curing periods, allowing its use in Portland cement matrices and activated matrices. Two types of systems were analyzed in the activated matrices studies:... (Complete abstract click electronic access below) / Doutor

Food waste and fashion pollution are two of the significant global environmental issues throughout the recent past. In this research, it was investigated the feasibility of making a leather-like material from bread waste using biotechnology as the bridging mechanism. The waste bread collected from the supermarkets were used as the substrate to grow filamentous fungi species Rhizopus Delemar and Fusarium Venenatum. Tanning of fungal protein fibres was successfully performed using vegetable tanning, confirmed using FTIR and SEM images. Furthermore, glycerol and a biobased binder treatment was performed for the wet-laid fungal microfibre sheets produced. Overall, three potential materials were able to produce with tensile strengths ranging from 7.74 ± 0.55 MPa to 6.92 ± 0.51 MPa and the elongation% from 16.81 ± 1.61 to 4.82 ± 0.36. The binder treatment enhanced the hydrophobicity even after the glycerol treatment, an added functional advantage for retaining flexibility even after contact with moisture. The fungal functional material produced with bread waste can be tailored successfully into leather substitutes using an environmentally benign procedure.