Graduation date: 1984

Placement of a sufficient volume of acid in all desired zones is critical for a successful acid stimulation treatment. Particularly in thick, highly heterogeneous carbonate formations, the acid distribution is crucial for optimal stimulation results. A variety of diversion methods are applied in acidizing treatments to evenly place acid along the well, but the effectiveness of these diversion methods is generally only inferred from the rate and pressure behavior during the treatment, and is not known with any certainty. Recently, distributed temperature sensing technology has enabled us to observe dynamic temperature profiles along the wellbore during and immediately following an acid treatment. This technology allows us to monitor and evaluate treatments and diversion methods in real-time and to capture a sequence of temperature profiles at different times during and after acid injection. We developed a transient thermal model for reservoir, coupled with a wormhole penetration model. Then the reservoir model is combined with a vertical well temperature model as the forward model, which can predict the temperature behavior inside formation and wellbore during and after a treatment. We applied the forward model in a synthetic two-layer example, and it shows that the temperature increase caused by the reaction between acid and carbonate rock indicates the acid distribution. An inversion model was also developed to analyze the temperature data measured after treatments to obtain the acid flow profile for a vertical well. The inversion method applied in this work is Markov chain Monte Carlo (MCMC) method, which is a stochastic method to search globally for possible results. We discuss the approach to realize the inversion procedure and to make the inversion more efficient. We also applied the comprehensive thermal model for hypothetical cases and field cases. The results from the inverse model give us quantitative understanding of acid distribution, which helps us to confirm the success of the acid treatment and diversion methods.

High-temperature processing of rice needs close attention due to the susceptibility of rice grains to fissures. The present study was carried out to redress the lack of information on the quality of rice dried at high-temperatures using a range of drying air temperatures from 160 - 200??C and grain moisture contents varying from 27 to 33%wb. A laboratory type high temperature dryer-oven was developed and constructed, and the performance was compared with commercial fluidized-bed and spouted-bed dryers. The new column type treatment plant, targeted at small-scale rice farmers was designed to reduce milling breakages was tested for high-temperature treatments. Short term drying (160 ??? 180 seconds) of high moisture rough rice at high-temperatures such as 160 - 200??C increased head rice yield by 5 - 8% in long grain rice and 7 - 11% in medium grain rice. The head rice yield increase achieved was very close to the highest potential head rice recovery possible for a given sample. The head rice yield increase was mainly due to a hardened surface layer of the rice kernel, formed by two effects, a surface fusion and surface gelatinization during high-temperature treatment. This stress protection layer is only effective for a short period (1 - 2 minutes) at high temperatures. Tempering of treated grains, either by storing in gunny bags or rapid cooling, can secure the grains to some extent from grain breakage. The highest head rice yield increase was obtained by ceasing the high-temperature effect at the grain moisture level of 24 - 25%wb. The colour and appearance of high-temperature treated grains were closer to those of untreated grains with the toughness closer to that of parboiled rice. The setback values of high-temperature treated rice measured by RVA, which is a preferred character by consumers, were closer to aged rice. High-temperature treatments did not affect the cooking qualities except a slight increase in water absorption. The alterations in the grain due to high-temperature treatment are limited to only for 8 - 9% of the total volume (mainly outer region) of the rice grain, preserving more than 90% of the grain with raw-rice quality. Structural changes such as complexing of amylose ??? lipid, amylose -protein and denaturation of protein play a dominant role on quality changes than gelatinization. A new method introduced to measure the degree of gelatinization of pre-gelatinized rice, using hot paste viscosity by rapid visco analyser (RVA), was successful. The peak viscosity parameter in the RVA was more suitable for measuring the chemical changes in high-temperature treated rice. Spouted-bed drying technology is not suitable for high-temperature treatment due to the unfavourable conditions for the formation of a hardened layer under intermittent heating and cooling. Fluidized-bed dryers could be used for high-temperature drying, but is not cost effective for the small-scale farmer level. The novel type treatment plant was successful in reducing the amount of broken grains to almost zero, increasing the head rice yield by 50 - 120kg per 1000kg of rough rice. It was also effective as a germination arrester, inhibiting the germination ability within a very short period such as 30 - 60 seconds. This equipment is more effective as a treatment Plant as it reduces moisture by only 1.5 - 2.0% at highest head rice yield recovery. An empirical model was successfully established (R2 = 0.99) for grain moisture content (db) and drying temperature during high-temperature processing. In model validation process, a good agreement was found between predicted and experimental data. The modelling between head rice yield and high-temperature drying was unsuccessful (R2 = 0.89) mainly due the interference from other factors such as initial moisture stress due to re-wetting and uncontrolled post treatment drying environment conditions. The study revealed some breakthrough for the rice industry in addition to its quantitative evaluation of increase in head rice yield. 1. Ability to produce grains with twice the toughness of milled untreated rice, without losing colour and appearance. 2. Fissured grains, previously weakened due to moisture-stress (considered as a loss), can be successfully recovered by treating this high-temperature technique. Currently there is no method available to increase the head rice yield of this type of fissured grains except parboiling, which is not widely accepted among consumers. 3. Drying at 200??C drying temperature completely destroyed the viability of seeds within 40 -60 seconds, hence providing a remedy for germination problems in wet harvests. 4. Since high-temperature drying needs wet rough rice, early harvesting can be done which will reduce shattering losses. This enable the farmers to use the field for an inter-seasonal crop which can utilise higher residual soil moisture in the paddy fields compared to other crops.

Thesis (M.S. - Soil and Water Science)--University of Arizona, 1984. / Includes bibliographical references (leaves 63-66).

Thesis (M.S. - Hydrology and Water Resources)--University of Arizona, 1989. / Includes bibliographical references (leaves 241-248).

Thesis (M.S.)--Montana State University--Bozeman, 2007. / Typescript. Chairperson, Graduate Committee: Otto Stein. Includes bibliographical references (leaves 41-43).

Thesis (M.S. - Hydrology)--University of Arizona. / Includes bibliographical references (leave 57).

Thesis (MScIng)--University of Stellenbosch, 2007. / Bibliography. Also available via the Internet.

Thesis (M.S.)--Oregon State University, 2008. / Printout. Includes bibliographical references (leaves 52-54). Also available on the World Wide Web.

Thesis (Ph.D) -- McMaster University, 1997. / Includes bibliographical references (p. 157-172). Also available via World Wide Web.