A laboratory testing program was conducted on cement-treated soil mixtures fabricated to represent materials produced by the wet method of deep mixing. The testing program focused on investigating the influences that variations in laboratory testing conditions and in the mix design have on measured property values. A base soil was fabricated from commercially available soil components to produce a very soft lean clay that is relatively easy to mix and can be replicated for future research. The mix designs included a range of water-to-cement ratios of the slurries and a range of cement factors to produce a range of mixture consistencies and a range of unconfined compressive strengths after curing. Unconfined compressive strength (UCS) tests and unconsolidated-undrained (UU) triaxial compression tests were conducted. Secant modulus of elasticity were determined from bottom platen displacements, deformations between bottom platen and cross bar, and from LVDT's placed directly on the cement-treated soil specimens. Five end-face treatment methods were used for the specimens: sawing-and-hand-trimming, machine grinding, sulfur capping, neoprene pads, and gypsum capping. Key findings of this research include the following: (1) The end-face treatment method does not have a significant effect on the unconfined compressive strength and secant modulus; (2) a relationship of UCS with curing time, total-water-to-cement ratio, and dry density of the mixture; (3) the secant modulus determined by bottom platen displacements is significantly affected by slack and deformations in the load frame; (4) the secant modulus determined by local strain measurements was about 630 time the UCS; (5) typical values of Poisson's ratio range from about 0.05 to 0.25 for stress levels equal to half the UCS and about 0.15 to 0.35 at the UCS; (6) Confinement increased the strength at high strains from less than 20% the UCS to about 60% the UCS. In addition to testing the cured mixtures, the consistency of the mixtures were measured right after mixing using a laboratory miniature vane. A combination of the UCS relationship along with the mixture consistency may provide useful information for deep mixing contractors. / MS

This diploma thesis maps pupils' understanding about a functional principle of using commands along with testing conditions (IF, IF - THEN, REPEAT - UNTIL, etc.) when creating algorithms. The main aim of the thesis is to design and implement a set of lessons and a teaching approach based on a theory about learning of algorithmic concepts at primary education for pupils (aged in 9-11) with the intention of verifying a functionality of designed teaching procedures and their possible impacts on pupils' understanding. Data was collected through continuous monitoring of pupils' behavioural characteristics, progress and solution of chosen tasks, video recordings of task solving within the suggested unplugged activities, using a virtual tool Code.org for monitoring of a pupils' progress, audio recordings of interview with pupils, and photographs capturing a creation of own blocks of commands set up by a transcription from pupils' mother language into a machine language (programming language) have all been used for a verification process of the designed teaching approach. By combining the acquired data sets, adjustments of these procedures have been made in order to eliminate the most frequent problems that pupils have encountered during teaching. The case study findings revealed that it is important for...

The current work focused on defining the material science options to fabricate novel, high performing ethylene/ethane (C₂H₄/C₂H₆) separation carbon molecular sieve (CMS) dense film membranes. Three polymer precursors: Matrimid®, 6FDA-DAM and 6FDA:BPDA-DAM were used as precursors to the CMS membranes. CMS performances were tailored by way of tuning pyrolysis conditions such as the pyrolysis temperature, heating rate, pyrolysis atmosphere etc. The CMS dense film membranes showed attractive C₂H₄/C₂H₆ separation performance far exceeding the polymeric membrane performances. Semi-quantitative diffusion size pore distributions were constructed by studying the transport performance of a range of different penetrant gases as molecular sized probes of the CMS pore structure. This, in conjunction with separation performance data, provided critical insights into the structure-performance relationships of the CMS materials. The effects of testing conditions, i.e. the testing temperature, pressure and feed composition on C₂H₄/C₂H₆ separation performance of CMS dense films were also analyzed. These studies were useful not just in predicting the membrane behavior from a practical stand-point, but also in a fundamental understanding of the nature of CMS membrane separation. The study helped clarify why CMS membranes outperform polymeric membrane performance, as well as allowed comparison between CMS derived from different precursors and processing conditions. The effects on C₂H₄/C₂H₆ separation in the presence of binary gas mixture were also assessed to get a more realistic measure of the CMS performance resulting from competition and bulk flow effects. The current work thus establishes a framework for guiding research ultimately aimed at providing a convenient, potentially scalable hollow fiber membrane formation technology for C₂H₄/C₂H₆ separation