This thesis describes the thermal design and thermal testing of the development model radiative cooler for the Composite Infra-Red Spectrometer (CIRS) due for launch on the Cassini spacecraft in 1997. The radiative cooler is used to cool the instrument's Focal Plane Assembly (FPA) to approximately 80K. The FPA holds two arrays of HgCdTe detectors for the mid infra-red spectrometer of the instrument which covers the wavelength range 7μm to 17μm. The FPA is mounted from the optics on a titanium alloy tripod and is cooled conductively by the radiator via a flexible link and a cold finger. A range of thermal models of the system have been developed ranging from a simple, analytical model to a finite difference numerical model. A calorimeter was designed to perform heat leak measurements on samples of Multi- Layer Insulation (MLI) blankets to determine the number and type of shields required for the MLI blanket covering the back of the cooler radiator. A test facility incorporating a vacuum system, a space simulator target, and a simulator for the CIRS instrument was designed and constructed for testing the assembled cooler. Various configurations of the Development Model (DM) CIRS cooler were tested as components became available and the results obtained compared to the thermal model predictions. It was found that the cooler will attain a temperature of 80K in operation, but with less excess cooling power than predicted by the thermal models.

The oxidation and ignition behaviour of the four major sulfide minerals present in the nickel concentrates smelted at the Kalgoorlie Nickel Smelter (KNS) has been established. These minerals are pyrite (FeS2), pyrrhotite (Fe1-nS, where n = 0 to 0.125), pentlandite ((FeNi)9S8) and violarite ( Ni2FeS4 ).The characteristic behaviour of these sulfides has been examined using Thermogravimetry-Differential Thermal Analysis (TG-DTA) under normal oxidation conditions ( l0ºC/min, air atmosphere). By increasing the heating rate to 40ºC/min and using an oxygen atmosphere, the tendency of the sulfides to ignite was established. Ignition was characterised by a highly exothermic reaction which occurred in association with a rapid mass loss over a short time span. Significant overheating of the samples beyond the temperature of the surroundings was observed. Pyrite, pyrrhotite and violarite all exhibited ignition behaviour while pentlandite did not.Using Isothermal Thermogravimetry (TG) the sulfides were subjected to shock heating conditions (heating rate = 3000-5000ºC/min, oxygen atmosphere) analogous to those which exist in an industrial flash smelter. The order of reactivity of the sulfides agreed with that observed during TG-DTA ignition trials. Even under these more intensely oxidising conditions pentlandite did not ignite. The effect of particle size on the ignition temperature was determined, larger particles igniting at a higher temperature. The magnitude of this effect varied according to the characteristics of the minerals.Products collected during Isothermal TG were examined by optical microscopy, Scanning Electron Microscopy (SEM) and Electron Probe Microanalysis (EPMA). Using these techniques it was possible to establish the morphology of the products and hence, to propose mechanisms for the reaction of the four sulfide minerals under ignition conditions.In order to ++ / simulate the thermal environment which exists in the KNS, a pilot scale model of the reaction shaft was used. Nickel sulfide concentrates of varying mineralogy and particle size distribution were smelted under various conditions. The effect of larger particle size and increasing oxygen partial pressure on the reactivity of these concentrates was established.The products were quenched at the base of the shaft and collected for examination by optical microscopy, SEM and EPMA. Products ranged from unreacted to completely oxidised particles. The morphology and composition of these species were identified. Approximately 30 particles in each of 26 samples were examined with a view to establishing the frequency of occurrence of the particular product types in concentrates of differing mineralogy and particle size. This allowed proposals to be made regarding the fate of the individual sulfide minerals during ignition in the pilot scale flash reactor.

Thesis (Ph.D.)--Tufts University, 2002. / Adviser: Peggy Cebe. Submitted to the Dept. of Physics. Includes bibliographical references. Access restricted to members of the Tufts University community. Also available via the World Wide Web;

Thesis (M. App. Sc.)--Carleton University, 2001. / Includes bibliographical references (p. 162-166.). Also available in electronic format on the Internet.

Thesis (M.Sc.) - Carleton University, 2002. / Includes bibliographical references. Also available in electronic format on the Internet.

Thesis (M. App. Sc.)--Carleton University, 2004. / Includes bibliographical references (p. 118-120). Also available in electronic format on the Internet.

Thesis (M.App.Sc.) - Carleton University, 2005. / Includes bibliographical references (p. 271-272). Also available in electronic format on the Internet.

Thesis (M.App.Sc.) - Carleton University, 2006. / Includes bibliographical references (p. 167-170). Also available in electronic format on the Internet.

Thesis (Ph. D.)--University of Missouri-Columbia, 1997. / Typescript. Vita. Includes bibliographical references (leaves 168-186). Also available on the Internet.

Thesis (Ph. D.)--University of Missouri-Columbia, 1997. / Typescript. Vita. Includes bibliographical references (leaves 168-186). Also available on the Internet.