Thermoelectric (TE) devices can undergo degradation from reactions in corrosive environments and at higher operating temperatures by sublimation and oxidation. To prevent the degradation, we have applied two high temperature polymers (HTPs) as coatings for TE materials. Sintering temperatures were from 250°C to 400°C. We explain why dip coating is better technique in our study and had two potential HTPs for tests. By applying TGA (thermogravimetric analysis), we were able to figure out which HTPs have better thermal resistivity. Besides, TGA also help us to find proper curing cycles for HTPs. EDS and SEM results show that the coatings prevent oxidation and sublimation of TE materials. We also shorten HTP curing cycle time and lower the energy costs.

Doctoral thesis deals with parameters of LED light sources and their static and dynamic changes due to variable operational conditions. Firstly there is briefly described the history of light emitting diodes, that brought LED from unintentional observation of luminescence to light source, which is generally used through the whole area of lighting techniques. Thesis focuses on light parameters analysis, which are specific for semiconductor light sources and their mutual relations. These relations in compliance with understanding the principles of light emission in semiconductor light sources enable establishing of basic connections and effects usable for LED behaviour model. Mutual relations of LED parameters and influencing factors are verified by measurement of chosen testing samples. For deeper understanding of diode parameter influencing mechanisms there are analysed current degradation models including degradation of partial components. On the basis of these facts there is created a model of LED luminaire operating with LED parameters together with cooling system that represent the integral part of the luminaire. Impact of supply drivers is also studied, because they are necessary for LED operation. Designed model supports the area of static changes of light parameters, as well as the dynamic changes of output parameters. Presented model is verified by testing measurements at basic operational states and partially outside of the common operational limits. There are also presented the possibilities of real use of the model that involve the evaluation of designed luminaire for specific light sources, searching for optimal operational limits, optimization of luminaire heatsink or using public lighting systems for regulation of electricity grid load fluctuations.