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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Cold Fiber Solid Phase Microextraction

Hosseinzadeh Haddadi, Shokouh January 2008 (has links)
A cold fiber solid phase microextraction device was designed and constructed based on the use of a thermoelectric cooler (TEC). A three-stage thermoelectric cooler was used for cooling a copper rod coated with a polydimethylsiloxane (PDMS) hollow fiber, which served as the SPME fiber. The copper rod was mounted on a commercial SPME plunger and exposed to the cold surface of the TEC, which was enclosed in a small aluminum box. A heat sink and a fan dissipated the generated heat at the hot side of the TEC. By applying an appropriate DC voltage to the TEC, the upper part of the copper rod, which was in contact to the cold side of the TEC, was cooled and the hollow fiber reached a lower temperature through heat transfer. A thermocouple was embedded in the cold side of the TEC for indirect measurement of the fiber temperature. A portable cold fiber SPME device was made by using a car battery as the power supply. The cold fiber SPME device with thermoelectric cooling was applied in quantitative analysis of off-flavors in rice. Hexanal, nonanal, and undecanal were chosen as three test analytes in rice. These analytes were identified according to their retention times and analyzed with a GC/FID instrument. Headspace extraction conditions (i.e. extraction temperature and extraction time) were optimized. Standard addition calibration graphs were obtained at the optimized conditions and the concentrations of the three analytes were calculated. The developed method was compared to a conventional solvent extraction method. The applicability of the portable cold fiber SPME with TEC for field sampling was tested. The effect of cooling on extraction recovery and the reproducibility of extraction were examined for extractions from an n-alkane flow through system. It was found that the extraction recoveries were significantly higher when the fiber was cooled. To further investigate the effect of cooling on the sensitivity of SPME in field sampling, the portable cold fiber SPME was used for extraction of volatile components from living wisteria flowers. Both the number of identified compounds and the related peak areas increased for extractions with cold PDMS fiber relative to without cooling and commercial PDMS and PA fibers. The portable cold fiber SPME device was also used for field sampling of volatile components of living lily-of-the-valley flowers and the extracted compounds were analyzed with GC/MS. The desorption kinetics of hydrophobic organic compounds (HOCs) from environmental solid matrices was investigated using cold fiber SPME with CO2 cooling. Polycyclic aromatic hydrocarbons (PAHs) and selected volatile organic compounds (i.e. toluene, ethylbenzene, o-xylene) were used as test analytes. Sand, silica gel, and clay were used as laboratory model solid matrices and were contaminated by the test analytes. Certified sediments were used as naturally contaminated samples. In this approach, the organic compounds, released from contaminated solid samples at different elevated temperatures, were exhaustively extracted with cold fiber SPME over different extraction times. The extraction data were used to obtain desorption and Arrhenius plots. The rate constants of desorption and activation energies of desorption were measured for each contaminant using these plots. The results were comparable to those reported in the literature.
2

Cold Fiber Solid Phase Microextraction

Hosseinzadeh Haddadi, Shokouh January 2008 (has links)
A cold fiber solid phase microextraction device was designed and constructed based on the use of a thermoelectric cooler (TEC). A three-stage thermoelectric cooler was used for cooling a copper rod coated with a polydimethylsiloxane (PDMS) hollow fiber, which served as the SPME fiber. The copper rod was mounted on a commercial SPME plunger and exposed to the cold surface of the TEC, which was enclosed in a small aluminum box. A heat sink and a fan dissipated the generated heat at the hot side of the TEC. By applying an appropriate DC voltage to the TEC, the upper part of the copper rod, which was in contact to the cold side of the TEC, was cooled and the hollow fiber reached a lower temperature through heat transfer. A thermocouple was embedded in the cold side of the TEC for indirect measurement of the fiber temperature. A portable cold fiber SPME device was made by using a car battery as the power supply. The cold fiber SPME device with thermoelectric cooling was applied in quantitative analysis of off-flavors in rice. Hexanal, nonanal, and undecanal were chosen as three test analytes in rice. These analytes were identified according to their retention times and analyzed with a GC/FID instrument. Headspace extraction conditions (i.e. extraction temperature and extraction time) were optimized. Standard addition calibration graphs were obtained at the optimized conditions and the concentrations of the three analytes were calculated. The developed method was compared to a conventional solvent extraction method. The applicability of the portable cold fiber SPME with TEC for field sampling was tested. The effect of cooling on extraction recovery and the reproducibility of extraction were examined for extractions from an n-alkane flow through system. It was found that the extraction recoveries were significantly higher when the fiber was cooled. To further investigate the effect of cooling on the sensitivity of SPME in field sampling, the portable cold fiber SPME was used for extraction of volatile components from living wisteria flowers. Both the number of identified compounds and the related peak areas increased for extractions with cold PDMS fiber relative to without cooling and commercial PDMS and PA fibers. The portable cold fiber SPME device was also used for field sampling of volatile components of living lily-of-the-valley flowers and the extracted compounds were analyzed with GC/MS. The desorption kinetics of hydrophobic organic compounds (HOCs) from environmental solid matrices was investigated using cold fiber SPME with CO2 cooling. Polycyclic aromatic hydrocarbons (PAHs) and selected volatile organic compounds (i.e. toluene, ethylbenzene, o-xylene) were used as test analytes. Sand, silica gel, and clay were used as laboratory model solid matrices and were contaminated by the test analytes. Certified sediments were used as naturally contaminated samples. In this approach, the organic compounds, released from contaminated solid samples at different elevated temperatures, were exhaustively extracted with cold fiber SPME over different extraction times. The extraction data were used to obtain desorption and Arrhenius plots. The rate constants of desorption and activation energies of desorption were measured for each contaminant using these plots. The results were comparable to those reported in the literature.
3

Thermal management of 3-D stacked chips using thermoelectric and microfluidic devices

Redmond, Matthew J. 13 January 2014 (has links)
This thesis employs computational and experimental methods to explore hotspot cooling and high heat flux removal from a 3-D stacked chip using thermoelectric and microfluidic devices. Stacked chips are expected to improve microelectronics performance, but present severe thermal management challenges. The thesis provides an assessment of both thermoelectric and microfluidic technologies and provides guidance for their implementation in the 3-D stacked chips. A detailed 3-D thermal model of a stacked electronic package with two dies and four ultrathin integrated TECs is developed to investigate the efficacy of TECs in hotspot cooling for 3-D technology. The numerical analysis suggests that TECs can be used for on demand cooling of hotspots in 3-D stacked chip architecture. A strong vertical coupling is observed between the top and bottom TECs and it is found that the bottom TECs can detrimentally heat the top hotspots. As a result, TECs need to be carefully placed inside the package to avoid such undesired heating. Thermal contact resistances between dies, inside the TEC module, and between the TEC and heat spreader are shown to significantly affect TEC performance. TECs are most effective for cooling localized hotspots, but microchannels are advantageous for cooling large background heat fluxes. In the present work, the results of heat transfer and pressure drop experiments in the microchannels with water as the working fluid are presented and compared to the previous microchannel experiments and CFD simulations. Heat removal rates of greater than 100 W/cm2 are demonstrated with these microchannels, with a pressure drop of 75 kPa or less. A novel empirical correlation modeling method is proposed, which uses finite element modeling to model conduction in the channel walls and substrate, coupled with an empirical correlation to determine the convection coefficient. This empirical correlation modeling method is compared to resistor network and CFD modeling. The proposed modeling method produced more accurate results than resistor network modeling, while solving 60% faster than a conjugate heat transfer model using CFD. The results of this work demonstrate that microchannels have the ability to remove high heat fluxes from microelectronic packages using water as a working fluid. Additionally, TECs can locally cool hotspots, but must be carefully placed to avoid undesired heating. Future work should focus on overcoming practical challenges including fabrication, cost, and reliability which are preventing these technologies from being fully leveraged.
4

Thermal Management and Packaging Techniques for High Performance Electrical Systems

Smarra, Devin 22 June 2020 (has links)
No description available.
5

Computational Study of Transverse Peltier Coolers

Ali, Syed Ashraf 23 August 2013 (has links)
No description available.

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