Thesis (MSc)--Stellenbosch University, 2012. / ENGLISH ABSTRACT: This study presents results of a detailed geological mapping and structural analysis of auriferous quartz-vein sets of the nine current open-pit operations, of the Siguiri Mining Complex in the northeastern parts of Guinea. The Siguiri Mining Complex is hosted by a low-grade metamorphic, turbiditic succession within the larger Siguiri Basin, which forms part of the Palaeoproterozoic Birimian Supergroup of the Boualé-Mossi domain on the West African Craton. The Siguiri Mining Complex is located in a deeply weathered saprolite profile developed over the monotonous succession of interlayered metapelites and -psammites. In fresh bedrock and core samples, the host succession is mainly made up of quartz-muscovite schists, muscovite-chlorite schists and metagreywackes, with isolated occurrences of intraformational breccias. The main deformation to have affected the metasedimentary succession of the Siguiri Mining Complex can be assigned to a D2 deformational event. D2 structures comprise of north-south trending strike-slip and reverse faults anastomosing around and enveloping open- to tightly folded domains exposed over an area of 12 by 3 km. The geometry, orientation and kinematics of faults and folds suggest that D2 structures formed during progressive deformation in an overall dextral transpressive brittle-ductile shear zone. Structures within the D2 corridor record east-northeast subhorizontal shortening and north-northwest subhorizontal extension. An omnipresent carbonate alteration in form of carbonate-alteration spots testifies to the pervasive, syn-D2 hydrothermal fluid-flow within the sediments. A structurally- and fracture-controlled fluid-flow is evidenced by the abundance of auriferous quartz veins throughout the Siguiri Mining Complex. These quartz veins host the bulk of the gold mineralization. One main and, at least, three minor sets of auriferous quartz veins can be distinguished. The main quartz-vein set shows very consistent easterly to northeasterly trends and steep southerly dips throughout the Siguiri Mining Complex. This orientation is consistent with the dextral transpressive kinematics and strain within the D2 host structure and illustrates the significance of D2 strains for the mineralization. The volumetrically minor vein sets can be shown to be related to different stages of F2 folding and fold amplification. Zones of economic-grade mineralization occur in areas where competent, psammitic units are developed in structural sites of increased dilatancy. Areas of dilatancy are represented by either dilational jog geometries within the overall transpressive structure or zones of pronounced shear-zone subparallel stretch. Jog geometries could be identified in the larger Bidini-Toubani-Sanu Tinti Complex having formed as a result of the anastomosing geometry of the bounding D2 shear zones. In the large Kami Complex, F2 axial culminations and depressions correspond to zones of increased stretch within the D2 transpression zone, delineated by closer vein spacing and the formation of D2 normal faults parallel to the main vein set and normal to F2 fold hinges. The size and extent of the Siguiri Mining Complex suggests that the host D2 transpressive corridor must be assumed to have a significantly larger along-strike continuation, being part of a larger shear zone system related to the accretionary history of Palaeoproterozoic basins and arcs onto the Archaean Man Shield in West Africa. / AFRIKAANSE OPSOMMING: Hierdie studie lewer die resultate voor van 'n gedetailleerde geologiese kartering en strukturele analise van die gouddraende kwarts-aar stelle in die huidige nege oop-groef operasies van die Siguiri Myn Kompleks, in die noordoostelike deel van Guinea. Die Siguiri Myn Kompleks is geherberg deur 'n lae metamorfiese graad turbidiet suksessie in die groter Siguiri Kom, wat deel form van die Paleo-Proterosoïkum Birimian Supergroep van die Boualé-Mossi streek op die Wes Afrika Kraton. Die Siguiri Myn Kompleks is geleë in die diep veweerde saproliet profiel, wat onwikkel het oor die eentonige suksessie van metapeliete en -psammiete. In vars bodemrots en kern monsters is die herberg-gesteente opgemaak uit kwarts-muskoviet skiste, muskoviet-chloriet skiste en metagrouwakte, as ook afgesonderde voorvalle van intraformasie breksies. Die hoof deformasie fase wat die metasedimentêre suksessie van die Siguiri Myn Kompleks geaffekteer het, kan toegeken word aan 'n D2 deformasie gebeurtenis. D2 strukture bestaan uit noord-suid neigende strekkingwaartse verskuiwings en opskuiwings, wat anastomoserend oop- en steil geplooide gebiede omsluit en is oor 'n area van 12 by 3 km ontbloot. Die geometrie, oriëntasie en kinematika van verskuiwings en plooie stel voor dat D2 strukture gevorm het tydens progressiewe deformasie in 'n algemene regse transpressie skuifskeursone, onder brosheid-duktiliteit toestande. Strukture in die D2 gang wys 'n oos-noordoos subhorisontale verkorting en 'n noord-noordwes subhorisontale verlenging. Die alomteenwoordigheid van karbonaat alterasie, in die vorm van karbonaat-alterasie spikkels, getuig van die deurdringende, sin-D2 hidrotermiese vloeistof vloei in die sedimente. Die strukturele- en breuk-beheerde vloeistof vloei is ook duidelik, as gevolg van die oorvloed van gouddraende kwarts-are reg deur die Siguiri Myn Kompleks. Die kwarts-are bevat die grootmaat van die goud mineralisasie. Een hoof, en te minste drie minder belangrike stele van gouddraende kwarts-aar stelle kan uitgeken word. Die hoof kwarts-aar stel wys konstante oostelike to noordoostelike neigings en steil suidelike hellings, reg deur die Siguiri Myn Kompleks. Die oriëntasie is konstant met regse transpressie kinematika en vervorming in die D2 strukture en illustreer die belangrikheid van D2 vervorming vir mineralisasie. Die minder-belangrike aar stelle is verwant aan die verskillende staduims van F2 plooiing en plooi amplifikasie. Sones van ekonomiese graad mineralisasie kom voor in areas waar bevoegde eenhede van psammiete ontwikkel het in strukturele terreine van verhoogde dilatasie. Areas van dilatasie word verteenwoordig deur dilatasie uitwykings in die transpressie strukture of sones van skuifskeur subparalelle verlenging. Uitwykings geometrië kan geidentifiseer word in die groter Bidini-Toubani-Sanu Tinti Kompleks, waar dit gevorm het asgevolg van die anastomoserende geometrie van die D2 skuifskeur sones. In die groter Kami Kompleks kom F2 aksiale kulminerings en depressies voor in sones van verhoogde strekking binne-in die D2 transpressie sone en word uitgebeeld deur nader aar-spasiëring en die formasie van D2 afskuiwings, parallel aan die hoof kwarts-aar stel en normaal met betrekking tot die F2 plooi-skarniere. Die groote en omvang van die Siguiri Myn Kompleks stel voor dat die D2 transpressiewe gang nog n groter voorsetting het, en vorm deel van 'n groter skuifskeur sisteem en is verwant aan die anngroeings geskiedenis van die Paleo-Proterosoïese komme en boë aan die Argeïese Man Skild in Wes Afrika.

Thesis (MSc)--Stellenbosch University, 2001. / ENGLISH ABSTRACT: This study focussed on the comparison of accessory mineral chemistry and paragenesis in the S-, I- and A-type granites of the Cape Granite Suite. The objective of the study was to use differences in accessory mineral chemistry and petrography to give insight in the evolution, recycling and formation of continental crust as affected by the Cape Granite Suite. Because of the high partition coefficients of the REE and trace elements into accessory minerals these minerals play an important role to explain granite evolution. The accessory mineral features are used as discriminators between barren and mineralized S-, I- and A-type granites in the suite. The petrography of the suite reflects the allanite-monazite dichtonomy with allanite and titanite occurring in the I -type granites while monazite occurs in S-type granites. Monazite becomes unstable in high Ca melts such as I-type granites. Apatite occurs in all the plutons which reflects its stability over a wide range of geological conditions. Rounded crystal habits of apatite and monazite in S-type granites indicate they are relics of sedimentary source rocks. Concentric growth- and sectoral zoning, as observed with CL and SEM, are common features in minerals that crystallized in barren plutons. The overprinting of magmatic textures reflects secondary processes, such as those that occurred in mineralized plutons, by "patchy" zoning and irregular alteration rims (coronas) in the mineralized plutons' accessory minerals. CL and SEM observations revealed that REE are redistributed into these coronas. Mineral chemistry of the accessory minerals reflects mostly the whole rock chemistry and physical conditions of the magmas. (Al~ Fe) substitution in titanite is controlled by P-T conditions, together with Ca, Mn and Mg substitution which is controlled by whole-rock chemistry, are good discriminators in S- and I-type granites. LREE and Sr content in allanite discriminate between the plutons and reflect the whole-rock chemistry. Apatite, because it occurs in all the plutons, is the most useful accessory mineral for discriminating between the plutons. From previous studies it is known that ASI controls the two main substitutions in apatite: Ca+P~Si+REE and Na+REE~2Ca, Fe and Mn content in apatite (0,1 pfu Mn and 0,05 pfu Fe contents are the cut-off between S-and Itype granites) are controlled by oxidation state of the magma and Sr, REE and Mg reflect whole-rock chemistry. The content of these elements in apatite can be used as discriminators between the plutons as their ASI, oxidation states and whole-rock chemistry differ. REE patterns of monazite and allanite are LREE enriched without exception, while apatite and titanite REE patterns are mostly birdwing profiles with occurrences of LREE or HREE enrichment. These patterns are influenced by crystallization of coexisting REE-bearing phases, fractionation history of the pluton and by crystallization sequence of the accessory minerals. Phase relationships were investigated experimentally for monazite and allanite under magmatic conditions (870 °C, 1,8 kbar) in peraluminous to metaluminous granitic melts. Monazite became unstable when aqueous CaCh solutions of 0.7-7 g CaCh/10cc H20 where added to peraluminous melts (ASI> 1 ). Monazite broke down to Cl-apatite and corona textures were observed. Allanite was tested in peraluminous (ASI> 1) and metaluminous (ASI=1) melts with different P20 5 (0.08 - 0.25 wt%) concentrations. Allanite became unstable at high phosphorus and peraluminous melt conditions and broke down to LREE-P± Al, Ca, K phases. Corona (kelyphitic) textures were observed. It is also clear that phosphorus played an important role, with Al, in the melt structure as can be seen from the absence or presence of crystals in the glasses of the different melts. This is possible because adding of phosphorus to the melt results in a depression of the T of the granitic melts' liquidus. Because of an interaction of phosphorus with Si networks and formation of complexes it also depolymerize aluminosilicate melts. The solubility of monazite was also tested in aqueous solutions under atmospheric conditions and low T (100-350 °C) to investigate low TIP alteration. Solutions ofCaCb +NaCl (1:1) chlorides were very reactive and dissolved the monazite completely, while solutions of CaCb were less reactive and only partly dissolved the monazite. These experiments demonstrate the concentrations required in hydrothermal solutions to destabilize monazite and explain textures found in natural rocks. Accessory minerals are useful discriminators between S-, I- and A-type granites and also their mineralized counterparts. Discrimination does depend on what accessory minerals are present and therefore apatite is the best mineral because it occurs in all the plutons. Petrography of these minerals is an indicator of primary or secondary processes. / AFRIKAANSE OPSOMMING: Die fokus van hierdie studie was om die mineraalchemie en paragenese van bykomstige minerale in S-, 1- en A-tipe graniete van die Kaapse Graniet Suite te vergelyk. Die doelwit van hierdie studie was om die verskille in chemie en petrografie van bykomstige minerale te gebruik as insig in die evolusie, herwinning en ontstaan van kontinentale kors soos geaffekteer deur die Kaapse Graniet Suite. Omdat SAE en spoorelemente hoe partisiekoeffisiente het vir bykomstige minerale speel hierdie minerale 'n belangrike rol om graniet evolusie te verklaar. Genoemde kenmerke van bykomstige minerale is ook gebruik om te onderskei tussen ongemineraliseerde en gemineraliseerde S-, 1- en A-tipe graniete in die suite. Die petrografie van die Kaapse Graniet Suite weerspieel die tweeledigheid van allanietmonasiet deurdat allaniet en titaniet in 1-tipe graniete en monasiet in S-tipe graniete voorkom. Monasiet word dus onstabiel in hoe Ca, 1-tipe, graniete. Apatiet kom in al drie tipes voor wat die mineraal se stabiliteit in verskeie geologiese omgewings weerspieel. Geronde kristalvorme , of reliekteksture, van apatiet en monasiet in S-tipe graniete weerspieel die sedimentere oorsprong van hierdie graniete. Konsentriese groei - en sektorale sonering kom algemeen voor in bykomstige minerale in ongemineraliseerde plutone. Sekondere veranderings rande (koronas) en onreelmatige sonering in gemineraliseerde plutone se bykomstige minerale is 'n aanduiding dat primere teksture gedeeltelik vemietig is deur sekondere prosesse. Katodeluminisensie en skandeerelektron mikroskopie ondersoeke het bewys dat SAE gehermobiliseer word na die koronas. Heelrotschemie en fisiese toestande van die magma word weerspieel in die mineraalchemie van bykomstige minerale. (Al~Fe) substitusie in titaniet word beheer deur P-T toestande en is, saam met Ca, Mn en Mg inhoud wat heelrotschemie weerspieel, goeie diskriminators in S- en 1-tipe graniete. LSAE en Sr inhoud in allaniet onderskei goed tussen plutone omdat hierdie elemente die heelrotschemie weerspieel. Omdat apatiet in al die plutone voorkom is dit die bruikbaarste mineraal om as diskriminant te gebruik. V anuit vorige werk is dit bekend dat die aluminium versadigings indeks die twee hoofsubstitusies: Ca+P~Si+SAE en Na+SAE~2Ca beheer, Fe en Mn inhoud in apatiet (0,1 pfu Mn en 0,05 pfu Fe is die afsnypunt tussen S- en 1-tipe graniete) weerspieel die oksidasietoestand van die magma en Sr, SAE en Mg weerspieel heelrotschemie. Saam kan hierdie elemente dus gebruik word as diskriminatore tussen die verskillende plutone. SAE patrone van allaniet en monasiet is sonder uitsondering verryk in die LSAE, terwyl apatiet en titaniet meestal "birdwing" profiele wys, maar kan ook verryk wees in LSAE of SSAE. Hierdie patrone word beinvloed deur kristallisasie van ander SAE-draende minerale, fraksionering van minerale uit die magma en die kristallisasie volgorde van die mineral e. Faseverwantskappe is eksperimenteel getoets tussen monasiet en allaniet in magmatiese toestande (780 °C en 1,8 kbar). Monasiet word onstabiel in 'n peralumineuse smelt (Aluminium versadigingsindeks >1) as waterig oplossings met konsentrasies van 0.7-7 g CaCh/1 0 cc H20 bygevoeg word. Cl-apatiet vorm as veranderingsproduk om die rande (koronas ). Allaniet is getoets in peralumineuse (Aluminium versadigingsindeks > 1) en metalumineuse smelte (Aluminium versadigingsindeks =1) met wisselende konsentrasies P20s (0.08 - 0.25 wt%). Allaniet het onstabiel geraak in peralumineuse smelte en hoe fosfor konsentrasies en het afgebreek na fases van LSAE+P± Ca, Al, K. Korona (kelifitiese) teksture is waargeneem. Hierdie eksperimente bewys dat fosfor, saam met Al, 'n belangrike rol speel in smeltstruktuur. Dit kan gesien word in die teenwoordig- of afwesigheid van kristalle in die glas. Dit is moontlik deurdat die byvoeging van fosfor 'n verlaging in die graniet likwidus temperatuur veroorsaak. Fosfor depolimeriseer ook aluminiumsilikaat smelte deur interaksie en kompleksvorming tussen fosfor en silika netwerke. Die oplosbaarheid van monasiet is ook getoets in waterige oplossings onder atmosferiese toestande en lae T (100-350 °C) om lae PIT veranderinge te ondersoek. 'n Versadigde oplossing van CaCh en NaCl (1:1) chloried het monasiet heeltemal opgelos terwyl 'n versadigde oplossing van CaCh monasiet net gedeeltelik opgelos het. Hierdie eksperimente dui op die konsentrasies nodig vir hidrotermale vloeistowwe waar bykomstige minerale onstabiel raak en verklaar teksture in natuurlike rotse. Bykomstige minerale kan dus gebruik word as diskriminators tussen ongemineraliseerde en gemineraliseerde plutone en ook tussen S-, I- en A-tipe graniete. Hulle kan egter net gebruik word as hulle teenwoordig is en daarom is apatiet die beste omdat dit in al die plutone aanwesig is. Petrografie is 'n aanduiding van magmatiese of sekondere prosesse.

Thesis (MSc.)--Stellenbosch University, 1994. / ENGLISH ABSTRACT: The NAD deposit forms part of the A-Mine Complex in the Rooiberg tin field in the north-western Transvaal. Mining started in 1986 and the mine was closed recently following a decline of tin prices and metallurgical problems with ore recovery. The deposit is hosted by the Boschoffsberg Quartzite Member of the Pretoria Group sediments and is structurally controlled within the so-called Tin Zone. Extensive alteration of the original host rocks occurred during the mineralisation event. Potassic remobilisation and redistribution appear to have taken place pervasively. The nature of the original host rock was altered to such an extent that it cannot be classified correctly. Previous workers refer to the host rock as an arkose because of its feldspathic nature. Wall rock alteration in the hanging- and foot wall of the different ore lodes (fractures) is generally similar. Very little change is observed in whole rock chemistry away from the lodes. The mineral chemistry of the ore lode minerals is indicative of fluid composition and mineralising conditions in the NAD deposit. The FeO/(FeO + MgO) ratio of tourmalines indicates deposition at a distance from the source of the mineralising fluids. Pyrite trace element chemistry differs from that of the Leeuwpoort deposit, indicating changing fluid chemistry. Contrary to previous assumptions that the carbonate present is ankerite, abundant siderite occurrences were found. Pyrite may co-precipitate with siderite under specific physico-chemical conditions. Cassiterite is generally trace element poor and relatively enriched in Fe. Hydraulic brecciation of the fractures as well as the tourmaline chemistry are strong indicators of a hydrothermal origin for the NAD deposit. However, the origin of the hydrothermal fluids is still uncertain. / AFRIKAANSE OPSOMMING: Die NAD- tinafsetting vorm dee/ van die A-Myn-kompleks in die Rooiberg tinveld in die noord-wes Transvaal. Die myn is in 1986 geopen en is onlangs gesluit weens swak tinpryse en metallurgiese ertsherwinningsprobleme. Die tinafsetting kom voor in die Boschoffsberg Kwartsiet lid van die Pretoria Groep sedimente. Dit is strukturee/ gekontroleer binne die sogenaamde Tin Sone. Vorige navorsers het na die waardgesteente as 'n arkose verwys op grand van die hoe veldspaat-inhoud. lntensiewe en uitgebreide verandering van die oorspronklike waardgesteentes het plaasgevind tydens mineralisasie. Deurdringende kalium-hermobilisering en -herverspreiding het plaasgevind. Die aard van die oorspronklike waardgesteente is egter tot so 'n mate verander, dat dit chemies nie korrek gek/assifiseer kan word nie. Wandrotsverandering van die verskil/ende ertsskeute in beide die voet- en dakgesteentes is baie soortge/yk. Die heelrotsgeochemie van die wandgesteentes verskil baie min weg van die ertsskeute af. Die mineraalchemie van die ertsskeut-minerale is aanduidend van die v/oeistofsamestelling en mineralisasietoestande van die NAD-tinafsetting. Die FeO/(FeO + MgO) verhouding van toermalyne dui daarop dat afsetting op 'n afstand vanaf die bron van die mineralisasie-vloeistowwe plaasgevind het. Die spoor-elementchemie van die NAD-piriete verskil van die piriete van die Leeuwpoort tinafsetting, wat verandering in vloeistofsamestelling aandui. In teenstelling met vorige aannames dat die karbonate in die Rooiberg tinafsettings as ankeriet bekend staan, is daar volop sideriet gevind. Piriet kristalliseer dikwels saam met sideriet onder spesifieke fisiese en chemiese toestande. Kassiteriet is meestal arm aan spoor-elemente, maar is relatief verryk in Fe. Hidroliese breksiering van die skeute en die toermalyn-chemie dui sterk op 'n hidrotermale oorsprong vir die NAD afsetting. Die bron van die vloeistowwe is nog nie definitief vasgestel nie. / Digitized at 300 dpi Colour PDF format (OCR), using ,KODAK i 1220 PLUS scanner. Digitised, Ricardo Davids on request from IBL 10 September 2013

Thesis (MSc)--Stellenbosch University, 2013. / ENGLISH ABSTRACT: The Northern Cape Province of South Africa has played host to numerous mining activities for over a century. To date, most of the mining activity has ceased, leaving the area laden with derelict mine sites and unlined tailings dumps. One such site is the Spektakel mine situated to the west of the town of Springbok. The unlined copper and sulphide rich tailings at the site have the potential to leach elevated concentrations of copper and acidic water into the Buffels River downslope of the site. This poses a threat to the surrounding communities that rely mainly on the river to supply water for drinking, livestock and irrigation. The soil surrounding the tailings dumps was characterised in terms of its mineralogical and chemical properties. The results indicate that the soil contains elevated concentrations of Cu2+, which is bound in the soil in the form of the secondary copper hydroxy mineral atacamite (Cu2(OH)3Cl). No other secondary copper minerals were identified at the site. Analysis of the solution present on the surface of the tailings dumps indicate that the tailings are the main source of the high Cu2+, Mg2+ and SO42- concentrations observed in the surrounding soils. As this solution migrates through the tailings dumps, into the soil, it accumulates Cl- through halite dissolution. The resulting acidic Cu2+, Mg2+, SO42- and Cl- solution reacts with the calcite in the soil, replacing it with atacamite. To determine why only a copper chloride mineral formed in the sulphate rich environment a synthetic solution with the composition of a solution in equilibrium with the soil was evaporated, both in the presence and absence of calcite. The results indicate that when the solution comes into contact with calcite, atacamite immediately precipitated, removing the Cu2+ from the solution. In the absence of calcite Cu2+ remains conservative, accumulating in the solution without precipitating a copper sulphate mineral. This establishes that the elevated Mg2+ concentration of the solution induces the formation MgSO4 aqueous complexes that reduce the activity of free sulphate, thus restricting copper sulphate mineral formation. The results from the soil characterization indicate that the atacamite stabilization mechanisms (circumneutral pH, high Cl- concentration and calcite) in the soil are diminishing. During sporadic rain events the acidic tailings solutions dissolve the calcite and temporarily reduce the Cl- concentration of the soil. To determine how these decreases will influence Cu2+ mobility in the soil, the stability of atacamite was tested by reducing the pH both in the presence and the absence of chloride. The results indicate that an elevated Cl- concentration and a pH > 6 stabilizes atacamite. A decrease in either of these parameters destabilizes atacamite and favours its dissolution. The study concludes that the current chemical conditions in the soil at Spektakel favour the stability of atacamite. However, continued sporadic rain events will reduce the Cl- concentration in the soil by increasing the SO42- concentration. This acidic solution will dissolve the calcite in the soil, thus reducing the buffering capacity of the soil, leading to the instability of atacamite, resulting in the leaching of large quantities of Cu2+ into the surrounding water bodies. / AFRIKAANSE OPSOMMING: Die mynbou bedryf was die ekonomiese dryfkrag van die Noord-Kaap Provinsie van Suid-Afrika vir meer as ‘n eeu. Die area was die gasheer vir ‘n verskeidenheid mynbou aktiwiteite tot die mynmaatskappye besluit het om mynproduksie te staak en die gebied te verlaat. Die mynmaatskappye het geen rehabilitasie aan die myne en mynhope verrig nie. Die verlate myne lê verspreid in die area met oop mynhope wat koper en ander swaar metale in die grond, sowel as in die water, na omliggende areas kan versprei. Een van dié verlate myne is die Spektakel myn 40 km wes van Springbok. Die mynhope by Spektakel kan moontlik koper en ander swaar metale in die Buffelsrivier, wat langs die myn verby loop, loog. Dit dien as ‘n bedreiging vir die omliggende gemeenskappe wat staatmaak op die water vir drinkwater en besproeiing. Die grond rondom die mynhope was ge-analiseer om te bepaal hoe erg ‘n bedreiging die mynhope vir die omgewing is. Die resultate dui daarop dat die grond hoë konsentrasies Cu2+ bevat wat vasgebind is in die sekondêre koper mineral atakamiet (Cu2(OH)3Cl). Geen ander sekondêre koper minerale is in die grond geïdentifiseer. Die analise van die oplossing wat bo-op die mynhoop aangetref is dui aan dat dié oplossing suur en gekonsentreerd is t.o.v. Cu2+, Mg2+ en SO42-. Terwyl die oplossing deur die mynhoop migreer los dit haliet in die grond op wat Cl- tot die oplossing byvoeg. Wanneer hierdie suur en Cu2+, Mg2+, SO42- en Cl- ryke oplossing met die kalsiet in die grond reageer word die kalsiet vervang met atakamiet (Garrels en Stine, 1948). Om vas te stel waarom slegs 'n koperchloried mineraal vorm in die sulfaat ryke grond was ‘n oplossing, met ‘n samestelling soortgelyk aan 'n oplossing in ewewig met die grond, verdamp in beide die teenwoordigheid en afwesigheid van kalsiet. Die resultate van die eksperiment dui daarop dat wanneer die oplossing in kontak kom met kalsiet atakamiet onmiddellik neerslaan en Cu2+ uit die oplossing verwyder. In die afwesigheid van kalsiet bly Cu2+ konserwatief in die oplossing; die Cu2+ hoop op in die oplossing en slaan nooit neer nie. Daar is vasgestel dat die verhoogde Mg2+ in die grondoplossing MgSO4 water komplekse vorm wat die aktiwiteit van SO42- verlaag en verhoed dat kopersulfaat minerale kan vorm. Verdere navorsing dui aan dat die chemiese meganismes wat atakamiet in die grond stabiliseer besig is om te kwyn. Gedurende sporadiese reën buie word die kalsiet in die grond opgelos deur die suur mynhoop oplossings wat die pH van die grond verlaag. Die mynhoop oplossing verryk ook die grond t.o.v SO42- wat die Cl- konsentrasie verlaag. Om te bepaal hoe hierdie afname in Cl- konsentrasie en pH die migrasie van Cu2+ beïnvloed was atakamiet oplossbaarheid bepaal. Atakamiet was onderskeidelik geplaas in ‘n suiwer water en chloried oplossing tewyl die pH verlaag was om te bepaal hoe atakamiet oplos in elk van die oplossings. Die resultate dui aan dat 'n verhoogde Cl- konsentrasie en pH > 6 atakamiet stabiliseer. Die afname van beide hierdie veranderlikes het veroorsaak dat atakamiet makliker ontbind en Cu2+ vrystel. Die gevolgtrekking van die studie is dat die huidige chemiese toestande in die grond by Spektakel gunstig is vir die stabiliteit van atakamiet. Met sporadiese reën buie neem die Cl- konsentrasie in die grond af en los kalsiet op. Hierdie afname in pH en Cl- konsentrasie maak atakamiet meer onstabiel wat gevolglik Cu2+ in die grond en water rondom Spektakel vrystel.

Thesis (MSc)--Stellenbosch University, 2013. / ENGLISH ABSTRACT: Vaalputs radioactive waste disposal facility is situated in an arid region of Bushmanland currently with evapotranspiration potential that far exceeds precipitation. Dominant soil features in Vaalputs are palimpsests of climates under which they formed. Particle sizes vary drastically between horizons which suggest different modes of sediment transport. Petrographic analyses revealed euhedral habits of primary mineral feldspar within the soils of Vaalputs. This suggests a proximal source of sediments and minimal primary mineral weathering under an arid climate where euhedral grains of feldspar are maintained. The surface horizon of the soils is covered by an equigranular coarse sand of residual aeolian origin. The transition from the surface horizon to the subsurface horizons is widely marked by a pebble sized stone-line. The pebble sized material of the stone-line suggests residual accumulation during the weathering of a previously surface exposed horizon. Since deposition of subsurface sediments (15 Ma) pedogenic alteration has been active in Vaalputs. This has resulted to a complex soil system which displays varied forms of thick dorbank horizons including massive polygonal peds and platy horizons. The polygonal peds are defined by desiccation cracks where vertical and horizontal laminations are hosted. Slaking tests as well as bulk chemistry confirmed that the laminations are composed largely of secondary calcite, however elemental mapping revealed numerous illite bands alternating with calcite layers. It is proposed that calcite layers represent solution features rather than cutanic features. Signs of hydromorphy are commonly observed within the dorbank horizons, since an arid climate currently prevails in Vaalputs such hydromorphic features may indicate formation under past climates. The occurrences of palygorskite, sepiolite and dorbank horizons in Vaalputs require high soil pH (generated by high concentrations of Na) for their formation. Vaalputs soils, however, measured circumneutral pH and relatively low Na concentrations which suggests that palygorskite, sepiolite and dorbank horizons are relic features. Salt casts of lenticular texture occur between polygonal peds of massive dorbank horizons and their enveloping vertical and horizontal laminations. Scanning Electron Microscope analyses indicate high concentrations of Mg, Al, Si and O which suggests sepiolite and palygorskite accumulation through a replacement of gypsum. Elemental maps in conjunction with x-ray tomography and bulk chemical analyses revealed that high concentrations of secondary barite occur along the contact surfaces between dorbank horizons and the laminations. The solution chemistry of all horizons show supersaturation with respect to barite suggesting that the Ba accumulation adjacent to the laminations is likely to have taken place at lower sulphate conditions than those present in the soils today. Evidence shows that Vaalputs soils have experienced at least one climate shift. The preserved soil mottles are indicative of soil environments that remain wet for an extended period. A fine textured platy dorbank horizon is an extensive feature in Vaalputs. The presence of this horizon indicates that the sediments were deposited from a low energy fluvial system. The large polygonal ped units in the lower dorbank units as well as the barite enrichments in pore spaces suggests a climate shift from wet to dry began after the sediments were deposited. / AFRIKAANSE OPSOMMING: Vaalputs radioaktiewe afval fasiliteit is geleë in 'n ariede streek van Namakwaland met evapotranspirasie potensiaal wat neerslag tans ver oorskry. Dominante grond funksies in Vaalputs sluit in 'palimpsests‘ klimaat kondisies waaronder dit gevorm het. Deeltjies groottes wissel drasties tussen horisonne wat op verskillende vorme van sediment vervoer dui. Die oppervlak in Vaalputs word gedek deur 'n gelyke korrelagtige growwe sand van residuele eoliese oorsprong. Die oorgang vanaf die oppervlak horison na die ondergrondse horisonne word algemeen gekenmerk deur 'n spoelsteen grootte kliplyn. Die spoelsteen grootte materiaal van die kliplyn dui op residuele opbou gedurende die verwering van 'n voormalige oppervlak blootgestelde horison. Sedert afsetting van die ondergrondse sedimente (15 Mj) is pedogenetiese veranderinge reeds aktief in Vaalputs. Dit het gelei tot 'n komplekse grond stelsel wat verskillende vorme van dik dorbank horisonne insluitend massiewe veelhoekige pedons en plaatagtige horisonne vertoon. Die veelhoekige pedons word gedefinieer deur uitgedroogde krake waar die vertikale en horisontale lamellering aangetref word. Ontbindingstoetse sowel as heelrots chemiese analiese bevestig dat die lamellering grootliks bestaan uit 'n sekondêre kalsiet. Elementele kartering het egter talle illiet bande afgewissel met kalsiet lae openbaar. Daar word voorgestel dat kalsiet lae verteenwoordigend van oplossingskenmerke is eerder as kuntanise kenmerke. Tekens van hidromorfie word algemeen binne die dorbank horisonne waargeneem, aangesien droë klimaat tans in Vaalputs heers kan sulke hidromorfiese kenmerke dui op die vorming onder vorige klimate. Die groot voorkomste van paligorskiet, sepioliet en dorbank horisonne in Vaalputs vereis hoë grond pH (wat gegenereer word deur hoë konsentrasies van Na) vir hul vorming. Vaalputs grond het egter relatief neutrale pH gemeet en relatief lae Na konsentrasies wat daarop dui dat paligorskiet, sepioliet en dorbank horisonne oorblyfsel kenmerke is. Sout gietforme met lentikulare texture kom voor tussen veelhoekige pedons van massieve dorbank horisonne en hul omhullende vertikale en horisontale lamellerings. SEM analiese toon hoe konsentrasies Mg, Al, Si en O aan wat opbou van sepioliet en paligorskiet deur verplasing van gips voorstel. Petrografiese analiese het euhedraal geaardheid van primere veldspaat mineraal getoon binne die grond van Vaalputs. Dit stel 'n bron van sediment voor en minimale pedogenese in dorre klimaat waar euhedraal korrels veldspate bewaar bly. Elementele kartering tesame met x-straal tomografie en heelrots chemiese analiese het getoon dat hoe konsetrasies sekondere bariet langs die kontak oppervlakke tussen dorbank horisonne en lamellerings voorkom. Die oplossingschemie van alle horisonne toon superversadiging met betrekking tot bariet wat voorstel dat die opbou van Ba langs die lamellerings waarskynlik plaasgevind het by laer sulfaat kondisies eerder as die kondisies wat heedendaags in grond voorkom. Bewyse toon dat Vaalputs grond ten minste een klimaatsverandering ondergaan het. Die gepreserveerde grond vlekke is kenmerkend aan grond omgewings wat vogtig gebly het vir 'n geruime tyd. 'n Fyn getekstuurde plaatagtige dorbank horison is 'n uitgebreide verskynsel in Vaalputs. Die teenwoordiheid van hierdie dorbank toon aan dat sedimente vanuit 'n lae energie fluviale sisteem afgeset het. Die groot veelhoekige pedon eenhede in die laer dorbank eenhede sowel as die bariet verryking in porie spasies stel voor dat 'n klimaatsverandering vanaf vogtig na droog begin het nadat die sediment afgeset het.

Thesis (MSc)--Stellenbosch University, 2013. / ENGLISH ABSTRACT: The source of the K2O in the K2O-rich ~3.45 Ga felsic intrusive rocks of the H6 unit in the Hooggenoeg Formation of the Onverwacht Group in the Barberton Granite Greenstone Terrain (BGGT) is examined in this study. This is of particular research interest because the Paleoarchaean rock record is considered to lack K2O-rich magmatic rocks. Previous studies on the felsic igneous rocks of the H6 unit have proposed that these rhyolites are K-metasomatised eruptive equivalents of the sodium-rich ~3.45 Ga TTGs of the BGGT and that the K-feldspar crystals in the rocks formed as a consequence of subsolidus replacement of plagioclase by K-feldspar. Furthermore, the timing of K-metasomatism has previously been related to the formation of the Buck Ridge Chert (BRC), which overlies the H6 unit. However, it has recently been demonstrated from granitic clasts in the conglomerate layer at the base of the Moodies sucession that K2O-rich magmatic rocks formed concurrently with TTG magmas during each of three episodes of TTG magmatism observed in the BGGT. Consequently, the hypothesis of a metasomatic origin for the K2O-rich character of the felsic rocks of the H6 unit requires further examination. Previous studies of the chemistsry of felsic volcanic rocks within the H6 unit were based on relatively low numbers of samples. This study has examined a substantial set of the freshest material available. Two varieties of felsic volcanic rocks were identified; K2O-rich, CaO-poor, Na2O-poor rhyolites and Na2O-rich, CaO-poor, K2O-poor Na-rhyolites. The K2O- rich rhyolite variety is dominant. Consequently, it is possible that the K2O-rich character of these rocks represents a primary magmatic signature. However, this judgment is complicated by the presence of a greenschist-facies metamorphic overprint at 3.2 Ga, which has resulted in complete replacement of micrystalline groundmass and partial replacement of the phenocryst assemblages by greenschist- and sub-greenschist-facies mineral assemblages, which undoubtedly allowed possible shifts in chemical compositions In this thesis, I test the source of K2O in these rocks by using the porphyritic textures of the rocks as an indication of the primary composition of the magmas they were formed from. These textures are typically defined by K-feldspar or albite and quartz phenocrysts within a microcrystalline groundmass. The rocks containing albite are Na-rich (Na-rhyolites) whereas the rocks defined by K-feldspar phenocrysts are rhyolites. XRD study of the structural state of the K-feldspar phenocrysts in the rhyolites indicates that these crystals are orthoclase and intermediate microcline, i.e. medium temperature K-feldspar polymorphs. The modal proportions of K-feldspar, quartz and microcrystalline groundmass in the rhyolites were calculated by using image analysis software. The compositions of the feldspar minerals were determined by electron beam analysis. Minimum bulk rock K2O content of the rhyolites were calculated from the proportions of K-feldspar crystals and their compositions. Even where the proportion of K-feldspar phenocrysts is relatively low (~ 30%), the calculated minimum bulk-rock K2O content is still above 5 wt%. The HREE slope (GdN/LuN) of the felsic porphyritic rocks of the H6 rhyolites is similar to that of ~3.45 Ga TTG plutons and steeper than that of granitic clasts of identical age contained in the basal conglomerate of the Moodies Group. Hence this study has illustrated that the rhyolites of the H6 unit were primary K-feldspar-rich, K2O-rich magmas that formed contemporarily with the ~3.45 Ga TTGs. This implicitly means that rhyolitic volcanism was more wide spread than previously thought in the Paleoarchaean and that it occurred together with the intrusion of the ~3.45 Ga TTGs in the BGGT. / AFRIKAANSE OPSOMMING: Die bron van die K2O in die K2O-ryk ~ 3,45 Ga felsiese vulkaniese rotse van die H6-eenheid in die Hooggenoeg formasie van die Onverwacht Groep in die Barberton Graniet Groensteen Terrein (BGGT) is in hierdie studie ondersoek. Dit is van besondere navorsingsbelang omdat die Paleoargeïse gesteenterekord beskou word as vry van magmatiese K2O ryke gesteentes. Vorige studies oor die felsiese vulkaniese rotse van die H6 eenheid het voorgestel dat hierdie rioliete K-gemetasomatiese eruptiewe ekwivalente van die natrium-ryke ~ 3,45 Ga TTGs van die BGGT is en dat die K-veldspaat kristalle in die gesteentes gevorm is as gevolg van subsolidus vervanging van plagioklaas deur K-veldspaat. Verder is die tydsberekening van K-metasomatisme voorheen gekoppel aan die vorming van die Buck Ridge Chert (BRC) wat die felsiese H6 eenheid bedek. Dit is egter onlangs aangetoon dat K2O-ryke magmatiese rotse gelyktydig met TTG magmas gevorm is tydens elk van drie episodes van TTG magmatisme waargeneem in die BGGT. Gevolglik vereis die hipotese van 'n metasomatiese oorsprong vir die K2O-ryke karakter van die felsiese gesteentes van die H6 eenheid verdere ondersoek. Vorige studies van die felsiese vulkaniese gesteentechemie in die H6 eenheid is gebaseer op 'n relatief klein getal monsters. Hierdie studie het 'n aansienlike stel van die varsste materiaal beskikbaar vir analise ondersoek. Twee variëteite van peralumineuse felsiese vulkaniese gesteentes naamlik 'n K2O-ryk, CaO-arm, Na2O-arm rioliet en Na2O-ryk, CaO-arm, K2O-arm Na-rioliet. Die K2O-ryke rioliet variëteit is meer oorheersend as die Na-rioliete. Dit is dus moontlik dat die K2O-ryk karakter van hierdie rotse 'n primêre magmatiese kenmerke verteenwoordig. Hierdie uitspraak is egter bemoeilik deur die teenwoordigheid van 'n groenskisfasies metamorfe oorprint op 3,2 Ga, wat gelei het tot die volledige vervanging van mikrokrisstalyne grondmassa en gedeeltelike vervanging van fenokrist samestellings deur groenskis en sub-groenskisfasies minerale samestellings en wat ongetwyfeld toegelaat het vir 'n moontlike verskuiwing in chemiese samestelling. In hierdie tesis toets ek die bron van K2O in hierdie gesteentes deur gebruik te maak van die vulkaniese teksture van die gesteentes as 'n aanduiding van die primêre samestelling van die magmas waaruit hulle gevorm het. Hierdie teksture word gewoonlik gedefinieer deur K-veldspaat of albiet en kwarts fenokriste binne 'n grondmassa van wat vroeërglasoorblyfsels was. Die rotse wat albiet bevat is Na-ryk (Na-rioliete) terwyl die rotse gedefinieer deur K-veldspaat fenokriste rioliete is. XRD studie van die strukturele toestand van die K-veldspaat fenokriste in die rioliete dui aan dat hierdie kristalle ortoklaas en intermediêre mikroklien is, dit wil sê die hoër temperatuur K-veldspaat polimorfe. Die modale proporsies van K-veldspaat, kwarts en glasoorblyfsels in die rioliete is akkuraat bereken deur gebruik te maak van beeld analise sagteware. Verder is die samestellings van die veldspaat minerale bepaal deur die elektronstraal analise. Minimum grootmaat rots K2O inhoud van die rioliet is berekén vanaf die fase verhouding van K-veldspaat en hul komposisies. Resultate dui daarop dat selfs waar die verhouding van K-veldspaat phenocrysts is relatief laag (~ 30%), die berekende minimum K2O grootmaat rots samestelling is nog steeds bo 5 wt%. Die REE-helling (GDN / Lun) van felsiese porphyritic rotse van die H6 is soortgelyke relatief tot die REE helling van ~ 3,45 Ga TTGs en steiler REE helling relatief tot granitiese klaste vervat in die basale konglomeraat van die Moodies-groep. Dus het hierdie studie getoon dat die rioliete van die H6-eenheid primêre K-veldspaat-ryke, K2O-ryke en peralumineuse magmas was wat gevorm is terselfdertyd met die ~3,45 Ga TTGs. Dit beteken implisiet dat riolitiese vulkanisme meer wyd verspreid was as wat voorheen gedink is in die Paleoargeïkum en dat dit tesame met die indringing van die ~ 3,45 Ga TTGs in die BGGT plaasgevind het.

Thesis (MSc)--Stellenbosch University, 2013. / This study presents a facies outcrop characterization and petrographical analysis of Unit B of the Permian Laingsburg Formation. Unit B is interpreted as a base-ofslope system, which represents a strikingly sand-rich succession. The base-of-slope system is defined by a channel-levee complex. The study provides systematically a clear understanding and description on reservoir heterogeneities, in terms of facies distribution, physical processes and architectural elements. The dataset included detailed sedimentary logs, photomosaic interpretations, supplemented by a petrographical study to determine the textural and compositional attributes of the studied sandstones. Seven lithofacies was recognised within Unit B, based on detail observation and description on grain size and sedimentary structures. They mainly consist of 1) thick to massive bedded ‘structureless’ sandstone, 2) horizontal and ripple cross-laminated thin-medium bedded sandstone, 3) silty sandstone, 4) structureless siltstone, 5) hemipelagic mudstone, 6) muddy slump, and 7) sandy slump. Palaeocurrent analysis indicates that the mean sediment transport direction of Unit B was to the E and NE. Lithofacies 1 comprises thickly to massive bedded, frequently amalgamated, mostly very-fined grained sand, mixed grading, irregular to sharp upper contacts, structured upper bedding planes, large floating mudstone clasts and granules, rare groove and flute casts. Also, scour and fill features have been documented. Lithofacies 1 has been interpreted to result from channelized sandy debris flow currents. Lithofacies 2 composes of thin-medium bedded, very fine-grained sand, ungraded, sharp upper contacts, discrete units with traction bed forms, horizontal and cross-lamination, mud-draped ripples, internal erosional surfaces and preserved crests. Lithofacies 2 shows diagnostic sedimentary features for a deep-water bottom reworking current. Lithofacies 5 composes of very fine–grained mud, ‘structureless’ to finely horizontally laminated, fissile mudstone. Deposition resulted from suspension settling of mud fractions out of a low-energy buoyant plume. Lithofacies 6 composes of contorted and convoluted bedding, steeply dipping layers and irregular upper contacts. Deposition occurred via slumping on an unstable slope. Lithofacies 7 composes of fine–grained ‘structureless’ sandstone, amalgamated units, with dark floating mudstone granules. Lithofacies 7 has been interpreted to form from channelized flows evolving into slump deposition on an unstable slope. The petrographic data reveals that the reservoir quality of the sandstones is strongly controlled by depositional processes and diagenetic products. The sediments of the Karoo Basin appear to be diagenetically controlled as a function of burial depth. The major diagenetic products controlling the reservoir quality of the sandstones, includes compaction (mechanical and chemical), and authigenic porefilling constituents (quartz cement, feldspar dissolution and partial to complete replacement, calcite cement, chlorite and illite). Compaction played a major role in the evolution of the sediment, as compared to the effect of quartz cementation, and is considered here to have caused irreversible destruction of depositional porosity and permeability. The sediment has undergone intense mechanical compaction during early-stage diagenesis, low temperature and shallow depth of burial (probably the first 2 km). The high burial palaeotemperature (250 ± 500C) or more specifically the high geothermal gradient of the Karoo Basin consequently increased the number of diagenetic reactions. The high burial temperatures may have increased pressure dissolution and quartz cementation. With compaction been limited, quartz cementation and the authigenesis of chlorite and illite at deeper depths may have had a profound effect on the permeability distribution of the studied sandstones. After the completion of diagenesis, the pore systems of these sandstones were completely destroyed by low-grade regional burial metamorphism.

Thesis (MSc)--Stellenbosch University, 2014. / ENGLISH ABSTRACT: Iron is an essential micronutrient for all phytoplankton and is found in seawater at picomolar-level concentrations. For the first time in South Africa, a technique that utilizes a flow injection analyser (FIA) coupled with a chemiluminescence reaction has been developed for the analysis of Fe in seawater samples. The developed method is an improvement on similar available methods and uses commercially available resin (IDA) as opposed to the one that requires synthesis in the laboratory. Furthermore, the method requires reduced reagent concentrations thereby providing better results in a cost-efficient and easy manner. The improvements resulted in better precision while eliminating the loss of resin through bleeding, a common problem when using 8-HQ resin as per prior methods. Method validation was performed using internationally calibrated reference material provided by GEOTRACES and the values obtained were within the error limits of certified range. An inter-laboratory calibration was also conducted as part of the verification of the system. Surface samples from the SANAE 51 cruise were analysed for dFe and TdFe. Subsequently, the method was implemented on the SANAE 53 voyage on board the SA Agulhas II, to assess trace metal sampling protocol for any contamination issues, as well as for the analyses of collected samples. Current results suggest some contamination during collection stages, but this is still to be verified by complementary data on macronutrients and chlorophyll. The method was successfully developed and implemented in a land based clean laboratory, as well as on board a vessel. / AFRIKAANSE OPSOMMING: Yster is „n noodsaaklike mikrovoedsel vir fitoplankton en word in seewater in pikomolêre konsentrasies gevind. Hierdie lae konsentrasies en potensiële besoedeling gedurende monsteropname vanaf „n skip se platform maak akkurate Fe-analise moeilik. Vir die eerste keer in Suid-Afrika is „n tegniek ontwikkel wat gebruik maak van „n vloei- inspuitinganaliseerder (VIA), met „n geassosieerde chemiluminessensiereaksie, om die analise van Fe in seewatermonsters uit te voer. In teenstelling met soortgelyke bestaande metodes wat labratorium-gesintetiseerde hars vereis, is die nuut-ontwikkelde metode „n verbetering wat gebruik maak van „n kommersieel-beskikbare hars (IDA). Verder vereis die metode verminderde reagenskonsentrasies wat sodoende beter resultate lewer op 'n koste-effektiewe en eenvoudiger wyse. Die verbeteringe het gelei tot verhoogde akkuraatheid en uitskakeling van die verlies van hars deur dreinering – „n algemene probleem wat ondervind is met die gebruik van 8-HQ hars in vorige metodes. Geldigheidsbepaling van die metode is met internasionaal-gekalibreerde verwysingsmateriaal, verskaf deur GEOTRACES, uitgevoer. Die waardes wat verkry is, was binne die foutgrense van die gesertifiseerde skaal. „n Interlaboratorium-kalibrasie is ook uitgevoer as deel van die verifikasie van die stelsel. Daarna is die metode geïmplementeer gedurende die SANAE 53 reis op die SA Agulhas II, om die spoormetaal-monsternemingprotokol vir enige besoedelingskwessies te evalueer, asook vir die ontleding van versamelde monsters. Huidige resultate dui op „n mate van besoedeling tydens die versamelingstadiums, maar dit moet nog geverifieer word deur aanvullende data van die totale oplosbare Fe, makrovoedingstowwe en chlorofil.

Thesis (PhD)--Stellenbosch University, 2012. / ENGLISH ABSTRACT: The discovery of lucrative diamond deposits along the west coast of Southern Africa about 1200 kilometres from the Kimberley region during the period 1908 to 1927, gave rise to a number of different theories with respect to their possible provenance. These included the transportation of diamonds from unknown sources in southern Namibia by south-flowing rivers, hidden on- and off-shore kimberlites along the coast, and transportation by west-bound rivers from the hinterland. Subsequent research has shown that the latter is the only plausible theory. The discovery of marine and coastal diamond deposits as far south as the Olifants River estuary showed that the Vaal-Orange drainage in its current form could not have been the only conduit for diamonds to the coast, and the drainage evolution of southern Africa was interpreted as comprising essentially the following two main palaeo-fluvial systems active in the formation of the world's only known diamond mega-placer deposit:  The Karoo River with its headwaters similar to those of the modern Orange and Vaal Rivers and entering the Atlantic Ocean via the present-day Olifants River;  The Kalahari River that drained southern Botswana and followed the route of the modern-day Molopo River, entering the Atlantic Ocean in the vicinity of the present Orange River mouth. An important shortcoming of the above model is that it could not account for the fact that diamond distribution along the west coast shows a marked increase in grade and average stone size at the estuaries of all the major rivers draining from the escarpment to the Atlantic between the Olifants and the Orange Rivers. The presence of fluvial diamond deposits along the courses of the Buffels, Swartlintjies, Spoeg, Horees and Groen Rivers confirms that the increased grade and diamond size at their estuaries is not a function of large bays and rougher bottom topography associated with the rivers, although these could have contributed to this phenomenon. This proves that the catchments of the rivers between the Olifants and Orange Rivers also had access to diamondiferous debris, although they were not in contact with these two major drainages. A number of researchers proposed that diamonds liberated from pre-Karoo kimberlites were moved from their primary hosts to the south-western parts of the subcontinent by Dwyka glacials. From the above it is clear that nearly a century after the discovery of diamonds along the west coast of southern Africa consensus regarding their origin had not been reached. The aim of this study was therefore to establish a model explaining the most likely sources and distribution history of the more important alluvial diamond deposits in southern Africa. The methodology comprised a study of 1878 diamonds collected from 25 alluvial and two kimberlitic sources for comparison with known similar data from 12 kimberlitic populations in southern Africa. The diamond study was supplemented by a study of sedimentary clasts from bulk gravel samples taken along the Middle and Lower Orange River as well as Scanning Electron-microscope (SEM) Analyses of garnet grains and zircon geochronology. The evidence from the study does not support the postulated existence of a former Karoo River. The surface features of diamonds, notably brown spots indicating – in the context of southern Africa - liberation from pre-Karoo kimberlites, as well as the results of Fourier Transform Infrared analyses revealed that the populations at Kwaggaskop along the Sout River, previously considered an erosion remnant of the Lower Karoo River and those occurring south of Brandvlei and Van Wyksvlei in the valley of the Sak River, previously considered to have been reworked from the Middle Karoo River, differ profoundly from each other. In addition, the surface feature studies and Fourier Transform Infrared Analyses clearly show major distinctions between the diamond populations from the Sout River-Olifants River estuary and those from the Kimberley kimberlite province which was said to have supplied diamonds in large quantities to the Olifants River estuary via the postulated Karoo River. Furthermore the idea of a palaeo-Gamoep River playing a significant role in the transportation of diamonds to the west coast is favoured by the presence of brown-spotted diamonds and diamonds with Platelet Preservation Indices revealing severe platelet destruction that could be traced through Bosluispan in the Koa River valley, the Buffels River valley, the Buffels River estuary and to the shallow marine environment north of the Buffels River. Zircon geochronology confirmed the role of the Orange River in the denudation of the sub-continent. With respect to the drainage evolution and diamond distribution in southern Africa the results of this study indicate a complex diamond dispersal model that differs in some respects from prevailing theories. It shows that diamonds liberated from pre- Karoo kimberlites in the north-eastern part of the sub-continent were initially moved in a south-westerly direction by pre-Karoo drainages, then by Dwyka glaciers and ice sheets. Ultimately, after liberation from exhumed glacial and fluvial deposits and together with diamonds subsequently liberated from Jurassic and Cretaceous kimberlites, Cretaceous and younger drainages provided the transport toward the Atlantic Ocean where the diamonds were concentrated along shorelines and in bedrock trap sites. Significant quantities did not reach the coast, but were locked up in fluvial sediments in erosion remnants like terraces, karstic depressions and other segments of palaeo-channels along the way. The presence of diamonds with FTIR characteristics reminiscent of those from Orapa and Jwaneng in the Orange River deposits as well as in a raised marine terrace in southern Namaqualand and in marine deposits north of Concession 12A, also negates the possible existence of a palaeo-Kalahari River, unless it was a very young system that did not interrupt the south-bound dispersal of Botswana diamonds during the Late Oligocene-Early Miocene. The study also included microscopic examination of a parcel of diamonds from the enigmatic Skeleton Coast deposits, north-western Namibia. These results confirmed the conclusion based on geological and geomorphic grounds that these diamonds cannot be linked to the Oranjemund deposits, while their surface features showed that pre-Karoo sources comprise the most likely provenance for the Skeleton Coast diamonds. Thus the combination of FTIR analyses and surface feature studies of diamonds, zircon geochronology and SEM analyses of garnets allowed the formulation of a revised model for the distribution of alluvial diamonds and the drainage history of the sub-continent since the Middle Cretaceous, while the study of sedimentary clasts confirmed the repeated occurrence of high energy fluvial conditions – especially evident in the palaeo-Orange River sediments – that contributed to the high percentage of gem stones in the surviving alluvial diamond populations due to the destruction of poor quality diamonds. / AFRIKAANSE OPSOMMING: Die ontdekking van ryk alluviale diamantafsettings aan die suider-Afrikaanse weskus, meer as 1200 kilometer van die Kimberley-omgewing af tussen 1908 en 1927, het 'n aantal teorieë omtrent moontlike provenansgebiede vir hierdie afsettings tot gevolg gehad. Dit het gewissel van die suidwaartse vervoer van diamante vanaf bronne in suidelike Namibië, diamantdraende kimberliete in die kusvlaktes of op die vastelandstoep onder huidige seevlak, tot die vervoer van diamante deur weswaarts-vloeiende riviere vanuit die binneland. Geen ontdekkings wat eersgenoemde teorie kon ondersteun is in Namibië gemaak nie. Verder, namate meer gevorderde navorsingsresultate aan die lig gekom het, het dit duidelik geword dat kimberliete wat weg van 'n antieke kraton geleë is, grootliks sonder diamante is, en gevolglik het die idee van nabygeleë diamantdraende kimberliete in die kusvlakte of op die seebodem as bron, onaanvaarbaar geword. Grootskaalse wes- tot suidweswaartse vervoer van diamante het gevolglik die enigste aanvaarbare alternatief gebied. Die ontdekkiing van aan- en aflandige mariene afsettings tot so ver as suid van die Olifantrsrivier het getoon dat die Vaal-Oranjestelsel in sy huidige vorm nie die enigste vervoerkanaal vir diamante na die weskus kon wees nie. Die dreineringsgeskiedenis van suidelike Afrika was gevolglik vertolk aan die hand van twee voorgestelde groot oer-rivierstelsels, naamlik: - Die Karoorivier met sy bolope naastenby soortgelyk aan dié van die moderne Oranje- en Vaalriviere, en wat langs die huidige Olifantsrivier uitgemond het; - Die Kalaharirivier wat die suide van Botswana gedreineer het, en min of meer die roete van die huidige Moloporivier gevolg het, met sy monding baie naby aan dié van die moderne Oranjerivier. 'n Belangrike tekortkoming in bogenoemde model is die feit dat dit nie 'n verduideliking bied vir die volgende feit nie: Diamant-produksiedata van die Suid-Afrikaanse weskus toon 'n skielike toename in graad (karaat per 100 ton) en gemiddelde steengrootte van diamante by die monding van al die belangrike riviere tussen die Olifants- en Oranjeriviere, wat vanaf die platorand na die Atlantiese Oseaan dreineer. Die feit dat fluviale diamantvoorkomste in die valleie van die Bufffels-, Swartlintjies-, Spoeg-, Horees- en Groenriviere aangetref word, bevestig dat hierdie verskynsel nie net aan die teenwoordigheid van kus-inhamme en ruwer vloertopografie wat met die riviermondings geassosiëer is, toegeskryf kan word nie, alhoewel dit wel „n bydrae tot hierdie waarneming kon maak. Dit bevestig dat hierdie riviere wel in hul opvang-gebiede ook toegang tot diamanthoudende puin gehad het, sonder enige kontak met die Olifants- of Oranjeriviere. 'n Aantal navorsers het die gedagte geopper dat diamante wat uit voor-Karoo kimberliete vrygestel was, deur bewegende ysplate en/of gletsers vanaf hul provenansgebiede na die suidweste van die subkontinent vervoer is. Uit die voorafgaande paragrawe is dit duidelik dat, ongeveer ʼn eeu ná die ontdekking van diamante langs die suider-Afrikaanse weskus, daar nog nie eenstemmigheid bereik is oor die oorsprong van hierdie diamante nie. Die doel van hierdie studie was gevolglik die daarstelling van „n model wat „n aanvaarbare verduideliking bied vir die verspreiding en afsetting van sommige voorkomste van spoeldiamante in suidelike Afrika soos tans waargeneem. Vir hierdie doel is 1878 diamante afkomstig vanuit 25 alluviale en twee kimberlietvoorkomste ondersoek. Die resultate is vergelyk met soortgelyke inligting wat bekend is vir diamantpopulasies vanuit 12 suider-Afrikaanse kimberliete. Die diamantstudie is aangevul met die ondersoek van spoelklippe vanuit gruismonsters wat langs die Middel- en Benede Oranjerivier versamel is asook Skanderings-elektron Mikroskoop-analises (SEM) van granaatkorrels en sirkoon-geokronologie. Die resultate van hierdie studie ondersteun nie die hipotese van „n eertydse Karoorivier nie. Die teenwoordigheid van bruin spikkels op diamante wat – in die konteks van die geologiese geskiedenis van suidelike Afrika – vrystelling vanuit vóór- Karoo kimberliete impliseer, asook die resultate van FTIR-analises dui op „n komplekse model wat „n alternatief bied vir bestaande sienswyses. Dit toon dat die diamantpopulasies by Kwaggaskop langs die Soutrivier wat veronderstel was om die Benede Karoorivier te verteenwoordig, en dié wat suid van Brandvlei en Van Wyksvlei in die vallei van die Sakrivier aangetref word en veronderstel was om afkomstig te wees uit die Middel Karoorivier, drasties van mekaar verskil. Dit openbaar ook beduidende verskille tussen die diamantpopulasies van die Olifantsriviermonding en dié van die Kimberley-omgewing waarvandaan die veronderstelde Karoorivier groot hoeveelhede diamante aan die Sout-Olifantsrivier sou gelewer het. Verder verskaf die teenwoordigheid van diamante met bruin spikkels en diamante met eienskappe wat toon dat hul stikstofplaatjies vernietig is, „n skakel tussen Bosluispan in die vallei van die Koarivier en die seegebied noord van die Buffelsrivier, via die Buffelsriviervallei en die Buffelsriviermonding, en hierdie feite ondersteun gevolglik eerder die voorstel dat groot hoeveelhede diamante deur die paleo-Gamoeprivier na die weskus vervoer is. Die teenwoordigheid van diamante met FTIR-kenmerke soortgelyk aan dié van Orapa en Jwaneng in die Mid-Oranje afsettings, 'n mariene terras in die suide van Namakwaland en in mariene konsessies noord van Seegebied 12A, opponeer ook die gedagte van 'n paleo-Kalaharirivier, tensy laasgenoemde 'n baie jong stelsel was wat nie die suidwaartse beweging van Botswana-diamante gedurende die Laat Oligoseen tot Vroeg Mioseen verhinder het nie. Die resultate van die sirkoon-geokronologie het die rol van die Oranjerivier in die afplatting van die subkontinent bevestig. Die volgende model tree uit bogenoemde waarnemings na vore: diamante wat in die noordooste van die subkontinent uit kimberliete met „n voor-Karoo inplasingsouderdom vrygestel is, is aanvanklik suidweswaarts vervoer deur voor-Karoo riviere. Daarna is die diamante deur gletsers en ysplate gedurende die Dwyka-tydperk, en uiteindelik ná vrystelling vanuit ontblote glasiale en paleo-fluviale afsettings tesame met diamante wat intussen vanuit Jura- en Krytouderom kimberliete vrygestel is, deur die dreineringstelsels in die Kryt-tydperk en later, verder suidweswaarts vervoer. Sommige het onderweg in fluviale sedimente (terrasse, karstholtes en ander reste van paleokanale) agtergebly, terwyl „n beduidende hoeveelheid tot in die Atlantiese Oseaan vervoer is waar hulle deur mariene prosesse in ou strandlyne en bodemrots opvangstrukture gekonsentreer is. Die studie het ook die mikroskopiese ondersoek van 'n pakkie diamante afkomstig vanuit die enigmatiese afsettings aan die noordelike Skedelkus van Namibië ingesluit. Op grond van geologiese en geomorfologiese getuienis word die afleiding gemaak dat die Skedelkusdiamante nie met die Oranjemund-afsettings verbind kan word nie, terwyl die mikroskopiese oppervlakteksture toon dat bronne met 'n voor-Karoo inplasingsouderdom die mees waarskynlike provenans vir hierdie diamante is. Die kombinasie van FTIR-analises en oppervlaktekstuur-studies van diamante, sirkoongeokronologie en SEM-analises van granate het die formulering van „n hersiene model vir die subkontinent se dreineringsgeskiedenis sedert die Middel-Kryttydperk en diamantverspreiding moontlik gemaak terwyl die studie van sedimentêre klaste getoon het dat hoë-energietoestande, waardeur diamante van swak gehalte vernietig sou word, herhaaldelik voorgekom het, veral in die paleo-Oranjerivier. Die afleiding word gemaak dat hierdie aspek „n bydrae gelewer het tot die hoë persentasie juweelstene in die oorblywende alluviale diamantpopulasies.

Thesis (MSc)--University of Stellenbosch, 2004 / ENGLISH ABSTRACT: The Sandveld, a potato growing area of the Western Cape is subject to significant groundwater abstraction for both municipal and agriculture purposes. The climate is arid and sensitive and important ecosystems in the area are showing varying degrees of impact. Management measures are needed to ensure ongoing sustainable development of the area. In this study, different interpolation techniques were evaluated to calculate values for unsampled variables rainfall and groundwater elevation. Local deterministic techniques as well as geostatistical techniques were used. It was found that geostatistical techniques, especially with collateral information, such as topography, provided a more accurate result. For environmental studies of this nature, Kriging is recommended as interpolation technique. The underlying data will determine the selection of the particular type of Kriging. Data was extracted from a customized relational database, geoMon, used for data capture, retrieval, processing and reporting. Ease of data extraction facilitated analysis. The interpolated grids were applied in two scenarios: Recharge calculations and quantification as well as a new classification approach according to Resource Directed Measures (RDM). Management classes were defined based on GIS-derived data. / AFRIKAANSE OPSOMMING: Die Sandveld, ‘n aartappelverbouingsgebied in die Wes-Kaap, ondergaan aansienlike grondwateronttrekking vir beide munisipale sowel as landbou doeleindes. Die klimaat is dor en droog en sensitiewe en belangrike ekosisteme in die area ondervind wisselende impakvlakke. Bestuursmaatreëls word benodig om volhoubare ontwikkeling van die area te verseker. In hierdie studie is verskillende interpolasie tegnieke om onbekende waardes vir veranderlikes gebruik in grondwater evaluasie te bereken, evalueer. Lokale deterministiese tegnieke sowel as geostatistiese tegnieke is gebruik. Geostatistiese tegnieke, veral gebruik saam met addisionele inligting soos topografie, bereken meer akkurate resultate. Vir omgewingsstudies van hierdie aard, word Kriging aanbeveel as interpolasie tegniek. Eienskappe van die onderliggende data word gebruik om die tipe Kriging aan te dui. Data is onttrek uit ‘n gebruikersaangepaste databasis, geoMon, wat gebruik is vir datavaslegging, onttrekking, prosessering en verslaggewing. Die gemak waarmee data onttrek kon word het analise vergemaklik. Geïnterpoleerde data is gebruik vir grondwateraanvullingsberekeninge en -kwantifisering sowel as ‘n nuwe benadering tot klassifikasie volgens hulpbron gerigte maatreëls. Bestuursklasse gebaseer op GIS-afgeleide data, is gedefinieer.