The idea of time series forecasting techniques is that the past has certain information about future. So, the question of how the information is encoded in the past can be interpreted and later used to extrapolate events of future constitute the crux of time series analysis and forecasting. Several methods such as qualitative techniques (e.g., Delphi method), causal techniques (e.g., least squares regression), quantitative techniques (e.g., smoothing method, time series models) have been developed in the past in which the concept lies in establishing a model either theoretically or mathematically from past observations and estimate future from it. Of all the models, time series methods such as autoregressive moving average (ARMA) process have gained popularity because of their simplicity in implementation and accuracy in obtaining forecasts. But, these models were formulated based on certain properties that a time series is assumed to possess. Classical decomposition techniques were developed to supplement the requirements of time series models. These methods try to define a time series in terms of simple patterns called trend, cyclical and seasonal patterns along with noise. So, the idea of decomposing a time series into component patterns, later modeling each component using forecasting processes and finally combining the component forecasts to obtain actual time series predictions yielded superior performance over standard forecasting techniques. All these methods involve basic principle of moving average computation. But, the developed classical decomposition methods are disadvantageous in terms of containing fixed number of components for any time series, data independent decompositions. During moving average computation, edges of time series might not get modeled properly which affects long range forecasting. So, these issues are to be addressed by more efficient and advanced decomposition techniques such as Wavelets and Empirical Mode Decomposition (EMD). Wavelets and EMD are some of the most innovative concepts considered in time series analysis and are focused on processing nonlinear and nonstationary time series. Hence, this research has been undertaken to ascertain the predictability of nonstationary time series using wavelet and Empirical Mode Decomposition (EMD) based ARMA models. The development of wavelets has been made based on concepts of Fourier analysis and Window Fourier Transform. In accordance with this, initially, the necessity of involving the advent of wavelets has been presented. This is followed by the discussion regarding the advantages that are provided by wavelets. Primarily, the wavelets were defined in the sense of continuous time series. Later, in order to match the real world requirements, wavelets analysis has been defined in discrete scenario which is called as Discrete Wavelet Transform (DWT). The current thesis utilized DWT for performing time series decomposition. The detailed discussion regarding the theory behind time series decomposition is presented in the thesis. This is followed by description regarding mathematical viewpoint of time series decomposition using DWT, which involves decomposition algorithm. EMD also comes under same class as wavelets in the consequence of time series decomposition. EMD is developed out of the fact that most of the time series in nature contain multiple frequencies leading to existence of different scales simultaneously. This method, when compared to standard Fourier analysis and wavelet algorithms, has greater scope of adaptation in processing various nonstationary time series. The method involves decomposing any complicated time series into a very small number of finite empirical modes (IMFs-Intrinsic Mode Functions), where each mode contains information of the original time series. The algorithm of time series decomposition using EMD is presented post conceptual elucidation in the current thesis. Later, the proposed time series forecasting algorithm that couples EMD and ARMA model is presented that even considers the number of time steps ahead of which forecasting needs to be performed. In order to test the methodologies of wavelet and EMD based algorithms for prediction of time series with non stationarity, series of streamflow data from USA and rainfall data from India are used in the study. Four non-stationary streamflow sites (USGS data resources) of monthly total volumes and two non-stationary gridded rainfall sites (IMD) of monthly total rainfall are considered for the study. The predictability by the proposed algorithm is checked in two scenarios, first being six months ahead forecast and the second being twelve months ahead forecast. Normalized Root Mean Square Error (NRMSE) and Nash Sutcliffe Efficiency Index (Ef) are considered to evaluate the performance of the proposed techniques. Based on the performance measures, the results indicate that wavelet based analyses generate good variations in the case of six months ahead forecast maintaining harmony with the observed values at most of the sites. Although the methods are observed to capture the minima of the time series effectively both in the case of six and twelve months ahead predictions, better forecasts are obtained with wavelet based method over EMD based method in the case of twelve months ahead predictions. It is therefore inferred that wavelet based method has better prediction capabilities over EMD based method despite some of the limitations of time series methods and the manner in which decomposition takes place. Finally, the study concludes that the wavelet based time series algorithm could be used to model events such as droughts with reasonable accuracy. Also, some modifications that could be made in the model have been suggested which can extend the scope of applicability to other areas in the field of hydrology.